Synthesis and Reactivity of Quadridentate Schiff Base Chelates of Lanthanide(III) Ions
Corresponding Author(s) : V. BALASUBRAMANIAN
Asian Journal of Chemistry,
Vol. 15 No. 1 (2003): Vol 15 Issue 1
Abstract
α-Naphthylisocyanation reactions are first conducted on Schiff
base chelates of lanthanide(III) ion. The results of reaction reactivity
clearly indicate that α-naphthylisocyanate attacks at the coordinated
Schiff base chelates and after prototropic rearrangement forms α-naphthylamido
derivatives. The results are investigated and based
on spectroscopic results. The structures of the chelates are proposed.
Keywords
Lanthanide(III)
Schiff Base
Chelates
Reactivity
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BALASUBRAMANIAN, V.; LOGANAYAGI, A.; NANTHINI, R.; RAVI, A.; KARTHIKEYAN, N.; MUTHUKUMARAN, S. Synthesis and Reactivity of Quadridentate Schiff Base Chelates of Lanthanide(III) Ions . ajc 2010, 15, 139-143.
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