Synthesis of New Furan Compounds: A Study towards Pyrrole Ring
Corresponding Author(s) : Aydin Demircan
ademircan@nigde.edu.tr
Asian Journal of Chemistry,
Vol. 18 No. 1 (2006): Vol 18 Issue 1
Abstract
Synthesis towards the precursor 1 for radicalic reaction has been studied. 3-Methyl-5-(5-methylfuran-2-yl)-4,5-dihydro-isoxazole, (7) was obtained from vinyl furan. 2-(4-Iodo-pent-4-enyl)-4-methyl-6-(5-methyl-furan-2-yl)-[1,3]oxazinane (13) was generated using the amino alcohol 8 and corresponding aldehyde (11). Selective protection on the amino alcohol was achieved. Steric hindrance of amino group behaved obstructive to a condensation reaction.
Keywords
Synthesis
Furan
Intra-
Intermolecular
Hetero
Radicalic cyclization
(1)
Karaarslan, M.; Demircan, A. Synthesis of New Furan Compounds: A Study towards Pyrrole Ring. ajc 2010, 18, 645-649.
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