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Vol. 18 No. 1 (2006): Vol 18 Issue 1

Synthesis and Characterization of Alkaline Earth Metal Chelates of Phthiocolmonoxime

D.G. Kanase
Department of Chemistry, Yashwantrao Mohite CollegeBharati Vidyapeeth Deemed University, Pune-411 038, India
S.S. Kadam
Department of Chemistry, Yashwantrao Mohite CollegeBharati Vidyapeeth Deemed University, Pune-411 038, India
S.T. Takale
Department of Chemistry, Yashwantrao Mohite CollegeBharati Vidyapeeth Deemed University, Pune-411 038, India
V.D. Kelkar
Department of Chemistry, Yashwantrao Mohite CollegeBharati Vidyapeeth Deemed University, Pune-411 038, India

Corresponding Author(s) : D.G. Kanase

dgkanase@yahoo.co.in

Asian Journal of Chemistry, Vol. 18 No. 1 (2006): Vol 18 Issue 1

Abstract

Metal chelates of phthiocolmonoxime with beryllium(II), magnesium(II), calcium(II), strontium(II) and barium(II) were synthesized and there chemical identities were established on the basis of elemental analysis. The structural investigations were carried out using infrared spectra and electronic spectra. The molecular composition of all the chelates corresponds to [ML2.(H2O)2] except for beryllium(II) chelate in which it is [ML(OH)]2.2H2O. A dimeric structure for tetrahedrally surrounded metal ion with bridging hydroxo group is proposed for beryllium(II) chelates, while trans-octahedral structure is suggested for all other chelates.

Keywords

Synthesis Spectral studies Chelates Alkaline earth metals Phthiocolmonoxime
Kanase, D., Kadam, S., Takale, S., & Kelkar, V. (2010). Synthesis and Characterization of Alkaline Earth Metal Chelates of Phthiocolmonoxime. Asian Journal of Chemistry, 18(1), 407–412. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/21344
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