Synthesis and Characterization of Zn(II) Complex of a Tripodal Tetradentate (N4) Ligand and a Theoretical Study.
Corresponding Author(s) : Sadegh Salehzadeh
saleh@basu.ac.ir
Asian Journal of Chemistry,
Vol. 18 No. 3 (2006): Vol 18 Issue 3
Abstract
A slightly modified method for synthesis of a previously known tetradentate (N4) tripodal ligand, N(CH2CH2NH2)2(CH2C5H4N) (L22py), is reported. A new zinc (II) complex, [Zn(L22py)](ClO4)2. is prepared from the direct reaction of the latter ligand and ZnCl2 in equimolar ratio followed by addition of excess amount of NaClO4. The resulting complex is characterized by microanalysis, IR, 1H NMR and 13C NMR spectra. The ab initio calculations on [Zn(L22py)]2+ show that all nitrogen donor atoms of the ligand are coordinated to the metal ion.
Keywords
ab initio
Tetradentate ligands
Tripodal complexes
Salehzadeh, S., & Golbegadhi, R. (2010). Synthesis and Characterization of Zn(II) Complex of a Tripodal Tetradentate (N4) Ligand and a Theoretical Study. Asian Journal of Chemistry, 18(3), 2211–2215. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/20976
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