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Vol. 32 No. 1 (2020): Vol 32 Issue 1

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Interactions of Cetyltrimethylammonium Bromide with 1,3-Dioxolane in Water: A Study of Viscosity and Volumetric Properties

https://doi.org/10.14233/ajchem.2020.22248
Dayananda Sarangi
Department of Chemistry, KIIT University, Bhubaneswar-751024, India
A.C. Samantaray
P.G. Department of Chemistry, Vikram Deb Autonomous College, Jeypore-764001, India
Rojalin Sahu
Department of Chemistry, KIIT University, Bhubaneswar-751024, India
https://orcid.org/0000-0003-1086-6193
Braja B. Nanda
P.G. Department of Chemistry, Vikram Deb Autonomous College, Jeypore-764001, India
https://orcid.org/0000-0001-8028-2447

Corresponding Author(s) : Rojalin Sahu

rojalinsahu.chem@gmail.com

Asian Journal of Chemistry, Vol. 32 No. 1 (2020): Vol 32 Issue 1

Abstract

Densities and viscosities of ternary mixtures containing cetyltrimethyl ammonium bromide (CTAB) in aqueous solution of 1,3-dioxolane have been measured at 5 K intervals from 298.15 to 313.15 K and at atmospheric pressure. The experimental results of viscosity and density have been analyzed by using Jones-Dole equation and Masson equation. The values of constants A and B of Jones-Dole equation have been interpreted in terms of solute-solute and solute-solvent interactions. The standard partial molar volume,Vf0 at infinite dilution were determined from Masson equations. The structure making/breaking capacity of solute is interpreted with the help of Helper equation. The positive value of Helper′s constant (∂2Vf0/∂T2)p and the negative value of dB/dT shows that CTAB in studied organic solvent predominantly acts as a structure-maker.

Keywords

1,3-Dioxolane Cetyltrimethylammonium bromide Ion-solvent interactions Jones-Dole equation
Sarangi, D., Samantaray, A., Sahu, R., & Nanda, B. B. (2019). Interactions of Cetyltrimethylammonium Bromide with 1,3-Dioxolane in Water: A Study of Viscosity and Volumetric Properties. Asian Journal of Chemistry, 32(1), 53–58. https://doi.org/10.14233/ajchem.2020.22248
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