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Influence of Structural, Thermoelectric Power and Catalytic Efficiency of Nd-Doped Mn3O4

https://doi.org/10.14233/ajchem.2020.22378
V.T. Geetha
Department of Chemistry, Hindustan Institute of Technology and Science, No. 1, Rajiv Gandhi Salai (OMR), Padur, Chennai-603103, India; Department of Chemistry, Sri Sairam Engineering College, Sai Leo Nagar, West Tambaram, Chennai-600044, India
G. Puthilibai
Department of Chemistry, Hindustan Institute of Technology and Science, No. 1, Rajiv Gandhi Salai (OMR), Padur, Chennai-603103, India; Department of Chemistry, Sri Sairam Engineering College, Sai Leo Nagar, West Tambaram, Chennai-600044, India
S. Induja
Department of Chemistry, Hindustan Institute of Technology and Science, No. 1, Rajiv Gandhi Salai (OMR), Padur, Chennai-603103, India

Corresponding Author(s) : V.T. Geetha

geethavt@yahoo.com

Asian Journal of Chemistry, Vol. 32 No. 1 (2020): Vol 32 Issue 1

Abstract

Hexagonal shape Nd doped Mn3O4 samples were prepared via microwave route using urea as reducing agent. Nd doped Mn3O4 magnetic, structural, optical and morphological properties of the synthesized hexagonal like particles were examined by diffused reflectance spectroscopy (DRS) and photoluminescence (PL), XRD, SEM, TEM and vibrating sample measurements (VSM) studies. Morphological results showed the hexagonal shape morphology and uniform size dispersal. The crystallite size and the particle size calculated and the TEM monographs designate the correlation of the data obtained from both measurements. It could be noted that saturation magnetization (Ms) and remanence (Mr) values reduce by maximizing neodymium replacement.

Keywords

Combustion method Magnetic properties Neodymium Mn3O4
Geetha, V., Puthilibai, G., & Induja, S. (2019). Influence of Structural, Thermoelectric Power and Catalytic Efficiency of Nd-Doped Mn3O4. Asian Journal of Chemistry, 32(1), 147–152. https://doi.org/10.14233/ajchem.2020.22378
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References
  1. D.-C. Liang, Q. An, P. Jin, X.-K. Li, H. Wei, J. Wu and Z.-G. Wang, Chin. Phys. B, 20, 108503 (2011); https://doi.org/10.1088/1674-1056/20/10/108503.
  2. K.E. Sickafus, J.M. Wills and N.W. Grimes, J. Am. Ceram. Soc., 82, 3279 (1999); https://doi.org/10.1111/j.1151-2916.1999.tb02241.x.
  3. D. Bahadur and S. Rajakumar, J. Chem. Sci., 118, 15 (2006); https://doi.org/10.1007/BF02708761.
  4. F. Gözüak, Y. Köseoglu, A. Baykal and H. Kavas, J. Magn. Magn. Mater., 321, 2170 (2009); https://doi.org/10.1016/j.jmmm.2009.01.008.
  5. Y. Koseoglu, F. Alan, M. Tan, R. Yilgin and M. Ozturk, Ceram. Int., 38, 3625 (2012); https://doi.org/10.1016/j.ceramint.2012.01.001.
  6. Y. Chen, L. Yang, C. Feng and L.-P. Wen, Biochem. Biophys. Res. Commun., 337, 52 (2005); https://doi.org/10.1016/j.bbrc.2005.09.018.
  7. I. Kostova, R. Kostova, G. Momekov, N. Trendafilova and M. Karaivanova, J. Trace Elem. Med. Biol., 18, 219 (2005); https://doi.org/10.1016/j.jtemb.2005.01.002.
  8. H. Yang, L. Guo, W. Yan and H. Liu J. Power Sources, 159 1305 (2006); https://doi.org/10.1016/j.jpowsour.2005.11.106.
  9. C. Ragupathi, S. Narayanan, M.P. Pachamuthu, N.M. Basith, R Kannapiran and G. Ramalingam, Adv. Sci. Eng. Med., 10, 882 (2018); https://doi.org/10.1166/asem.2018.2188.
  10. W. Qin, L. Xu, J. Song, R. Xing and H. Song, Sens. Actuators B Chem., 185, 231 (2013); https://doi.org/10.1016/j.snb.2013.05.001.
  11. P. Gunawan, L. Mei, J. Teo, J. Ma, J. Highfield, Q. Li and Z. Zhong, Langmuir, 28, 14090 (2012); https://doi.org/10.1021/la302590g.
  12. C. Ragupathi, J.J. Vijaya, R.T. Kumar and L.J. Kennedy, J. Mol. Struct., 1079, 182 (2015); https://doi.org/10.1016/j.molstruc.2014.09.045.
  13. X. Fu, L.A. Clark, Q. Yang and M.A. Anderson, Environ. Sci. Technol., 30, 647 (1996); https://doi.org/10.1021/es950391v.
  14. F. Cheng, Z. Peng, C. Liao, Z. Xu, S. Gao, C. Yan, D. Wang and J. Wang, Solid State Commun., 107, 471 (1998); https://doi.org/10.1016/S0038-1098(98)00265-8.
  15. M. Sajjia, M. Oubaha, M. Hasanuzzaman and A.G. Olabi, Ceram. Int., 40, 1147 (2014); https://doi.org/10.1016/j.ceramint.2013.06.116.
  16. M. Sales, C. Valentín and J. Alarcón, J. Eur. Ceram. Soc., 17, 41 (1997); https://doi.org/10.1016/S0955-2219(96)00069-6.
  17. M.H. Mahmoud, A.M. Elshahawy, S.A. Makhlouf and H.H. Hamdeh, J. Magn. Magn. Mater., 343, 21 (2013); https://doi.org/10.1016/j.jmmm.2013.04.064.
  18. I. Khan, S. Khan, H. Ahmed and R. Nongjai, AIP Conf. Proc., 1536, 241 (2013); https://doi.org/10.1063/1.4810190.
  19. G. Williamson and R. Smallman, Philos. Mag., 1, 34 (1956); https://doi.org/10.1080/14786435608238074.
  20. L. Li, C. Xiang, X. Liang and B. Hao, Synth. Met., 160, 28 (2010); https://doi.org/10.1016/j.synthmet.2009.09.026.
  21. C.H. Ong and H. Gong, Thin Solid Films, 445, 299 (2003); https://doi.org/10.1016/S0040-6090(03)01175-1.
  22. Y.C. Ng and M. Shamsuddin, J. Iran. Chem. Soc., 8(S1), S28 (2011); https://doi.org/10.1007/BF03254279.
  23. C. Ragupathi, J.J. Vijaya, L.J. Kennedy and M. Bououdina, Ceram. Int., 40, 13067 (2014); https://doi.org/10.1016/j.ceramint.2014.05.003.
  24. C. Ragupathi, J.J. Vijaya and L.J. Kennedy, Mater. Sci. Eng. B, 184, 18 (2014); https://doi.org/10.1016/j.mseb.2014.01.010.
  25. C. Ragupathi, J.J. Vijaya, L.J. Kennedy and M. Bououdina, Mater. Sci. Semicond. Process., 24, 146 (2014); https://doi.org/10.1016/j.mssp.2014.03.026.
  26. Y. Ichiyanagi, Y. Kimishima and S. Yamada, J. Magn. Magn. Mater., 272–276, E1245 (2004); https://doi.org/10.1016/j.jmmm.2003.12.377.
  27. A.S. Bhatt, D.K. Bhat, C. Tai and M.S. Santosh, Mater. Chem. Phys., 125, 347 (2011); https://doi.org/10.1016/j.matchemphys.2010.11.003.
  28. S.K. Nataraj, B.H. Kim, J.H. Yun, D.H. Lee, T.M. Aminabhavi and K.S. Yang, Mater. Sci. Eng. B, 162, 75 (2009); https://doi.org/10.1016/j.mseb.2009.03.008.
  29. T. Selvamani, A. Sinhamahapatra, D. Bhattacharjya and I. Mukhopadhyay, Mater. Chem. Phys., 129, 853 (2011); https://doi.org/10.1016/j.matchemphys.2011.05.055.
  30. J.P. Muñoz Mendoza, O.E. Ayala Valenzuela, V. Corral Flores, J. Matutes Aquino and S.D. De la Torre, J. Alloys Compd., 369, 144 (2005); https://doi.org/10.1016/j.jallcom.2003.09.075.
  31. N. Yamazoe and N. Miura, Chemical Sensor Technology, 4th edition, Elsevier, Amsterdam, edn 4, p. 19 (1992).
  32. L. Promsong and M. Sriyudthsak, Sens. Actuators B Chem., 25, 504 (1995); https://doi.org/10.1016/0925-4005(95)85108-9.
  33. M.R. Islam, N. Kumazawa and M. Takeuchi, Appl. Surf. Sci., 142, 262 (1999); https://doi.org/10.1016/S0169-4332(98)00712-0.
  34. P. Song, J. Hu, H. Qin, L. Zhang and K. An, Mater. Lett., 58, 2610 (2004); https://doi.org/10.1016/j.matlet.2004.03.028.
  35. S. Komarneni, R. Roy and Q.H. Li, Mater. Res. Bull., 27, 1393 (1992); https://doi.org/10.1016/0025-5408(92)90004-J.
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