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Vol. 18 No. 4 (2006): Vol 18 Issue 4

Alkaline Earth Metal Chelates of 3-Halolawsonemonoximes

D.G. Kanase
Department of Chemistry, Yashwantrao Mohite College, Bharati Vidyapeeth,Deemed University, Pune-411 038, India
S.S. Kadam
Department of Chemistry, Yashwantrao Mohite College, Bharati Vidyapeeth,Deemed University, Pune-411 038, India
S.T. Takale
Department of Chemistry, Yashwantrao Mohite College, Bharati Vidyapeeth,Deemed University, Pune-411 038, India
V.D. Kelkar
Department of Chemistry, Yashwantrao Mohite College, Bharati Vidyapeeth,Deemed University, Pune-411 038, India

Corresponding Author(s) : D.G. Kanase

dgkanase@yahoo.co.in

Asian Journal of Chemistry, Vol. 18 No. 4 (2006): Vol 18 Issue 4

Abstract

Metal chelates of 3-halolawsonemonoximes with beryllium (II), magnesium (II), calcium (II), strontium (II) and barium (II) were synthesized. The structural investigations were carried out using infrared spectra and electronic spectra. The molecular composition of all the chelates corresponds to [ML2×(H2O)2] except for beryllium (II) chelate in which it is [ML(OH)]2×2H2O. A dimeric structure for tetrahedrally surrounded metal ion with bridging hydroxo group is proposed for beryllium (II) chelates, while trans-octahedral structure is suggested for all remaining chelates.

Keywords

Synthesis Spectral Chelates Beryllium(II) Magnesium(II) Calcium(II) Strontium(II) Barium(II) 3-Halolawsonemonoximes
Kanase, D., Kadam, S., Takale, S., & Kelkar, V. (2010). Alkaline Earth Metal Chelates of 3-Halolawsonemonoximes. Asian Journal of Chemistry, 18(4), 2725–2731. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/20644
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