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Vol. 32 No. 8 (2020): Vol 32 Issue 8, 2020

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Effect of Doping Nano Samarium(III) Oxide in PVA+Na3C6H5O7 Films for Battery Applications

https://doi.org/10.14233/ajchem.2020.22673
J. Ramesh Babu
Department of Physics, Koneru Lakshmaiah Education Foundation, Vaddeswaram-522502, India
https://orcid.org/0000-0002-4776-5161
K. Ravindhranath
Department of Chemistry, Koneru Lakshmaiah Education Foundation, Vaddeswaram-522502, India
https://orcid.org/0000-0003-3500-0767
K.Vijaya Kumar
Department of Physics, Dayananda Sagar University, Bengaluru-560068, India
https://orcid.org/0000-0002-5045-3767

Corresponding Author(s) : J. Ramesh Babu

jallirameshura@gmail.com

Asian Journal of Chemistry, Vol. 32 No. 8 (2020): Vol 32 Issue 8, 2020

Abstract

The effect of doping nano Sm2O3 particles in PVA + Na3C6H5O7 (90:10% w/w) polymer composite films on the structural, thermal, electrical properties and battery parameters are  investigated. The PVA + Na3C6H5O7 + nano Sm2O3 (90:10:1- 4% w/w) films were synthesized and characterized. A 2% w/w Sm2O3 film was relatively homogeneous with high amorphous  in nature enabled the movement of nanoparticles in the matrix of polymer under potential gradient. The maximum conductivity was 2.09 × 10-3 S cm-1 for 2% w/w nano Sm2O3 film and it  is 7 orders more than polyvinyl alcohol. The films were adopted in batteries with configuration: Anode (Mg+MgSO4)/[{PVA:Na3C6H5O7 (90:10% w/w)} + nano Sm2O3 (1-4% w/w)]/cathode (iodine + carbon + pieces of electrolyte) and battery parameters were assessed. The discharge time is 174 h with the cell having 2.0% w/w nano Sm2O3 film. These nano Sm2O3 doped films are  successfully adopted in the fabrication of batteries and also the proposed cells are simple, effective, eco-friendly and economical.

Keywords

Polymer Electrolytes Polyvinyl alcohol Nano Sm2O3 Battery applications
Babu, J. R. ., Ravindhranath, K. ., & Kumar, K. (2020). Effect of Doping Nano Samarium(III) Oxide in PVA+Na3C6H5O7 Films for Battery Applications. Asian Journal of Chemistry, 32(8), 1947–1954. https://doi.org/10.14233/ajchem.2020.22673
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