Kinetic Studies on Thermal Decomposition of Mixed Ligand Complexes of Lanthanide(III) Ions
Corresponding Author(s) : G. RAJENDRAN
Asian Journal of Chemistry,
Vol. 19 No. 1 (2007): Vol 19 Issue 1
Abstract
Some mixed ligand complexes of lanthanide(III) ions with 4-hydroxy-3',4-dimethoxy diphenyl azomethine (HDDA) and diphenyl sulfoxide (DPSO) and various coordinating anions such as nitrate, perchlorate and thiocyanate have been synthesized and their kinetics on thermal decomposition were studied. The activation energies for the decomposition stages were calculated by Coats-Redfern and Madhusoodhanan-Krishan-Ninan equations. The tentative mechanism for the thermal decomposition has been proposed.
Keywords
Kinetic
Thermal
Decomposition
Lanthanide
Complexes
RAJENDRAN , G., & USHA DEVI, K. (2010). Kinetic Studies on Thermal Decomposition of Mixed Ligand Complexes of Lanthanide(III) Ions. Asian Journal of Chemistry, 19(1), 209–212. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/20443
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