Synthesis and Quantum Chemistry of Two Novel Copper(II) Complexes
Corresponding Author(s) : SHU-SHENG ZHANG
shushzhang@126.com
Asian Journal of Chemistry,
Vol. 19 No. 2 (2007): Vol 19 Issue 2
Abstract
The reaction of Cu(NO3)2 with N'-[(2-hydroxyphenyl) methylidene]-2-(4-methyl)acetohydrazide (sal-mphah) led to the formation of a one-dimensional coordination polymer with the empirical formula of [Cu(sal-mphah)·H2O]n (1·H2O). While, the reaction of Cu(NO3)2 with salicylidene-[1-(t-buty)-5-methyl-1H-pyrazole]-formhydrazine (sal-pfh) gave a dinuclear Cu(II) compound [Cu(sal-pfh)2·(μ-NO3)2] (2). The electronic studies of the ligands and their copper(I) complexes have been calculated with density functional theory (DFT/B3LYP) and the coordination character was further discussed.
Keywords
Copper compounds
Quantum chemistry
Density functional theory (DFT/B3LYP)
(1)
WEI, Q.-L.; ZHANG, S.-S.; GAO, J.; LI, X.-M. Synthesis and Quantum Chemistry of Two Novel Copper(II) Complexes. ajc 2010, 19, 1461-1467.
Download Citation
Endnote/Zotero/Mendeley (RIS)BibTeX