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Vol. 32 No. 4 (2020): Vol 32 Issue 4, 2020

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Isotherm, Kinetics and Thermodynamic Study of Adsorption of Phthalocyanine and Azo Dyes by CoCl2 Doped Polyaniline

https://doi.org/10.14233/ajchem.2020.22411
U.D. Lingeswari
P.G. and Research Department of Chemistry, Seethalakshmi Ramaswami College (Affiliated to Bharathidasan University), Tiruchirappalli-620002, India
https://orcid.org/0000-0001-9386-6652
T. Vimala
P.G. and Research Department of Chemistry, Seethalakshmi Ramaswami College (Affiliated to Bharathidasan University), Tiruchirappalli-620002, India
https://orcid.org/0000-0003-2006-3175

Corresponding Author(s) : U.D. Lingeswari

vimalsrc@gmail.com

Asian Journal of Chemistry, Vol. 32 No. 4 (2020): Vol 32 Issue 4, 2020

Abstract

In this work, CoCl2 doped polyaniline was prepared using chemical oxidation method and used as an effective adsorbent for the removal of industrial dyes reactive blue 21 and reactive red 180. The adsorption experiments were performed with the variation of initial concentrations of dyes, pH of the solution, weight of adsorbent, temperature and agitation speed. Isotherm analysis, evaluating the correlation coefficients by ANOVA technique, kinetic study and calculation of thermodynamic parameters are carried out. Furthermore, the adsorption density of dyes onto PANI-CoCl2 adsorbent is characterized by SEM and FTIR. This study is compared with other previous works to establish that PANI-CoCl2 is an efficient adsorbent to remove dye from aqueous solution.

Keywords

Industrial dye Polyaniline SEM Adsorption Degradation
Lingeswari, U., & Vimala, T. (2020). Isotherm, Kinetics and Thermodynamic Study of Adsorption of Phthalocyanine and Azo Dyes by CoCl2 Doped Polyaniline. Asian Journal of Chemistry, 32(4), 746–752. https://doi.org/10.14233/ajchem.2020.22411
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References
  1. Y. Al-Degs, M.A.M. Khraisheh, S.J. Allen and M.N. Ahmad, Water Res., 34, 927 (2000); https://doi.org/10.1016/S0043-1354(99)00200-6
  2. Y. Yu, Y.Y. Zhuang, Z.-H. Wang and M.-Q. Qiu, Chemosphere, 54, 425 (2004); https://doi.org/10.1016/S0045-6535(03)00654-4
  3. V. Katheresan, J. Kansedo and S.Y. Lau, J. Environ. Chem. Eng., 6, 4676 (2018); https://doi.org/10.1016/j.jece.2018.06.060
  4. E. Forgacs, T. Cserháti and G. Oros, Environ. Int., 30, 953 (2004); https://doi.org/10.1016/j.envint.2004.02.001
  5. S.J. Allen and B. Koumanova, J. Univ. Chem. Technol. Metall., 40, 175 (2005).
  6. M.T. Yagub, T.K. Sen, S. Afroze and H.M. Ang, Adv. Colloid Interface Sci., 209, 172 (2014); https://doi.org/10.1016/j.cis.2014.04.002
  7. Z. Ghazali, R. Othaman, Md. P. Abdullah, Adv. Nat. Appl. Sci., 6, 1307 (2012).
  8. M. Arami, N.Y. Limaee, N.M. Mahmoodi and N.S. Tabrizi, J. Colloid Interface Sci., 288, 371 (2005); https://doi.org/10.1016/j.jcis.2005.03.020
  9. M.T. Sulak, E. Demirbas and M. Kobya, Bioresour. Technol., 98, 2590 (2007); https://doi.org/10.1016/j.biortech.2006.09.010
  10. W. Shi, H. Shao, H. Li, M. Shao and S. Du, J. Hazard. Mater., 170, 1 (2009); https://doi.org/10.1016/j.jhazmat.2009.04.097
  11. N. Nasuha, B.H. Hameed and A.T.M. Din, J. Hazard. Mater., 175, 126 (2010); https://doi.org/10.1016/j.jhazmat.2009.09.138
  12. A.B. Kaiser, Adv. Mater., 13, 927 (2001); https://doi.org/10.1002/1521-4095(200107)13:1213<927::AIDADMA927>3.0.CO;2-B
  13. K. Gupta, G. Chakraborty, S. Ghatak, P.C. Jana and A.K. Meikap, J. Appl. Polym. Sci., 115, 2911 (2010); https://doi.org/10.1002/app.31380
  14. K. Pielichowski, J. Pielichowski, J. Iqbal and P. Gurtat, Appl. Catal. A Gen., 161, L25 (1997); https://doi.org/10.1016/S0926-860X(97)00145-2
  15. M. Majhi, R.B. Choudhary, A.K. Thakur, F.S. Omar, N. Duraisamy, K. Ramesh and S. Ramesh, Polym. Bull., 75, 1563 (2018); https://doi.org/10.1007/s00289-017-2112-1
  16. A. Gupta and M. Kumar, Indian J. Res., 4, 332 (2015).
  17. Asha, S.L. Goyal and N. Kishore, AIP Conf. Proc., 1731, 140054 (2016); https://doi.org/10.1063/1.4948220.
  18. T. Sismanoglu, Y. Kismir and S. Karakus, J. Hazard. Mater., 184, 164 (2010); https://doi.org/10.1016/j.jhazmat.2010.08.019
  19. A. Vanaamudan, N. Pathan and P. Pamidimukkala, Desalination Water Treat., 52, 1589 (2014); https://doi.org/10.1080/19443994.2013.789405
  20. M. Rachakornkij, S. Ruangchuaya and S. Teachakulwiroj, Songklanakarin J. Sci. Technol., 26(Suppl.1), 13 (2004).
  21. M.T. Sulak and H.C. Yatmaz, Desalination Water Treat., 37, 169 (2012); https://doi.org/10.1080/19443994.2012.661269
  22. D. Pathania, S. Sharma and P. Singh, Arab. J. Chem., 10, S1445 (2017); https://doi.org/10.1016/j.arabjc.2013.04.021
  23. S. Ravulapalli and R. Kunta, Int. J. Environ. Sci. Technol., 8, 7837 (2019); https://doi.org/10.1007/s13762-018-2147-3
  24. R. Kooh, M.K. Dahri and L.B.L. Lim, Cogent Environ. Sci., 2, 1140553 (2017); https://doi.org/10.1080/23311843.2016.1140553s
  25. S. Sawasdee, H. Jankerd and P. Watcharabundit, Energy Procedia, 138, 1159 (2017); https://doi.org/10.1016/j.egypro.2017.10.225
  26. A. Geethakarthi and B.R. Phanikumar, Int. J. Environ. Sci. Technol., 8, 561 (2011); https://doi.org/10.1007/BF03326242
  27. M.A. Ahmad, N.A.A. Puad and O.S. Bello, Water Resour. Ind., 6, 18 (2014); https://doi.org/10.1016/j.wri.2014.06.002
  28. G. Mckay, G. Ramprasad and P. Mowli, Water Res., 21, 375 (1987); https://doi.org/10.1016/0043-1354(87)90218-1
  29. N.R.A. Manap, R. Shamsudin, M.N. Maghpor, A.A.M. Hamid and A. Jalar, J. Environ. Chem. Eng., 6, 970 (2018); https://doi.org/10.1016/j.jece.2017.12.067
  30. A.M. Aljeboree, A.N. Alshirifi and A.F. Alkaim, Arab. J. Chem., 10(Suppl. 2), s3381 (2017); https://doi.org/10.1016/j.arabjc.2014.01.020
  31. A.A. Inyinbor, F.A. Adekola and G.A. Olatunji, Water Resour. Ind., 15, 14 (2016); https://doi.org/10.1016/j.wri.2016.06.001
  32. G. Ciobanu, S. Barna and M. Harja, Arch. Environ. Prot., 42, 3 (2016); https://doi.org/10.1515/aep-2016-0014
  33. J.M. Dos Santos, M.L. Felsner, C.A.P. Almeida and K.C. Justi, Water Air Soil Pollut., 227, 300 (2016); https://doi.org/10.1007/s11270-016-3003-z
  34. F. Berg, J. Wilken, C.A. Helm and S. Block, J. Phys. Chem. B, 119, 25 (2015); https://doi.org/10.1021/jp507659x
  35. M. Ayad, G. El-Hefnawy and S. Zaghlol, Chem. Eng. J., 217, 460 (2013); https://doi.org/10.1016/j.cej.2012.11.099
  36. M.M. Ayad and A.A. El-Nasr, J. Phys. Chem. C, 114, 14377 (2010); https://doi.org/10.1021/jp103780w
  37. M.M. Ayad, A. Abu El-Nasr and J. Stejskal, J. Ind. Eng. Chem., 18, 1964 (2012); https://doi.org/10.1016/j.jiec.2012.05.012
  38. M. Ayad and S. Zaghlol, Chem. Eng. J., 204–206, 79 (2012); https://doi.org/10.1016/j.cej.2012.07.102
  39. V.K. Gupta, D. Pathania, N.C. Kothiyal and G. Sharma, J. Mol. Liq., 190, 139 (2014); https://doi.org/10.1016/j.molliq.2013.10.027
  40. A.N. Chowdhury, S.R. Jesmeen and M.M. Hossain, Polym. Adv. Technol., 15, 633 (2004); https://doi.org/10.1002/pat.521
  41. M. Tanzifi, S.H. Hosseini, A.D. Kiadehi, M. Olazar, K. Karimipour, R. Rezaiemehr and I. Ali, J. Mol. Liq., 244, 189 (2017); https://doi.org/10.1016/j.molliq.2017.08.122
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