Reactions of Cyclic Oxalyl Compounds, Synthesis of Functionalized Hydrazono-2H-imidazol-4,5(1H, 3H)dione: Experimental Data and AM1 Calculations
Corresponding Author(s) : Emin Saripinar
emin@erciyes.edu.tr
Asian Journal of Chemistry,
Vol. 17 No. 1 (2005): Vol 17 Issue 1
Abstract
The reaction of the 4-benzoyl-5-phenylfuran-2,3-dione (1) with guanylhydrazones (2a-d) gives hydrazono-2H-imidazol-4.5-(1H,3H)-dione derivatives (4a-d) (yield ca. 30-40%). The structure of these compounds were determined by spectroscopic methods. Quantum chemical calculations were carried out for 2a-d and 4a-d by AM1 method.
Keywords
Guanylhydrazones
Imidazol
Semiempirical calculations
Furan-2,3-dione
(1)
Saripinar, E.; Akcamur, Y.; Kollenz, G. Reactions of Cyclic Oxalyl Compounds, Synthesis of Functionalized Hydrazono-2H-Imidazol-4,5(1H, 3H)dione: Experimental Data and AM1 Calculations. ajc 2016, 17, 395-403.
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