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Synthesis and Characterization of Molecularly Imprinted Polymer with Dimethylamylamine as Template
Corresponding Author(s) : S. Amin
Asian Journal of Chemistry,
Vol. 30 No. 12 (2018): Vol 30 Issue 12
Abstract
Molecular imprinted polymer (MIP) is a selective polymer that has the ability to bind target molecules so that they can be used as sorbents in the process of separation. Molecular imprinted polymer is made with a ratio of 1:4:20 between dimethylamylamine, methacrylic acid, and ethylene glycol dimethacrylate. The synthesis of molecular imprinted polymer was performed using bulk method with direct heating at 60 °C for 7 h. By using Fourier transform infrared, there is a functional group difference between the FTIR spectrum of molecular imprinted polymer, non-imprinted polymer and molecular imprinted polymer without dimethylamylamine. Scanning electron microscopy (SEM) shows that molecular imprinted polymer has an irregular and hollow morphological structure, unlike non-imprinted polymer that tends to be irregular compared to molecular imprinted polymer and have no cavities. While molecular imprinted polymer without dimethylamylamine has irregular and hollow morphological structure of equal size more than molecular imprinted polymer. The resulting molecular imprinted polymer has a selectivity to adsorb dimethylamylamine 209 % higher than non-imprinted polymer. The percentage of concentration of molecular imprinted polymer with chloroform solvent was 203 % more dissected than the percentage of molecular imprinted polymer with methanol solvent.
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References
J. Savulescu, B. Foddy and M. Clayton, Br. J. Sport Med., 38, 666 (2004); https://doi.org/10.1136/bjsm.2003.005249.
http://www.wada-ama.org, The 2017 Prohibited list international standard, the world anti-doping agency code.
A.B. Cadwallader, Aegis Sciences Corporation All Rights Reserved (2014).
http://www.wada-ama.org, 2015 Anti-Doping Testing Figures.
http://www.dailymail.co.uk,Girl Who Died in Marathon Took Energy Drug That is Now Banned After Being Linked to Deaths of Two U.S. Soldiers.
M.J. Eliason, A. Eichner, A. Cancio, L. Bestervelt, B.D. Adams and P.A. Deuster, Mil. Med., 177, 1455 (2012); https://doi.org/10.7205/MILMED-D-12-00265.
V. Lopez-Avila and M. Zorio, Forensic Sci. Int., 231, 113 (2013); https://doi.org/10.1016/j.forsciint.2013.04.029.
R. Le, J.E. Young, J.J. Pesek and M.T. Matyska, J. Sep. Sci., 36, 2578 (2013); https://doi.org/10.1002/jssc.201300325.
L. Chen, X. Wang, W. Lu, X. Wu and J. Li, Chem. Soc. Rev., 45, 2137 (2016); https://doi.org/10.1039/C6CS00061D.
R. Osman, N. Saim, N.M. Anuar and S.N.M. Subari, The Open Conf. Proc. J., 4, (Suppl-2, M25), 111 (2013); https://doi.org/10.2174/2210289201304020111.
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S. Qiao, H. Sun, H. Yan and H.K. Row, Chromatographia, 64, 625 (2006); https://doi.org/10.1365/s10337-006-0097-2.
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P. Cheah, C.N. Bhikha, J.H. O’Haver and A.E. Smith, Int. J. Polym. Sci., Article ID 6308603 (2017); https://doi.org/10.1155/2017/6308603.
S. Srivastava, Desig. Monomers Polym., 12, 1 (2009); https://doi.org/10.1163/156855508X391103.
S. Nesrinne and A. Djamel, Arabian J. Chem., 10, 539 (2017); https://doi.org/10.1016/j.arabjc.2013.11.027.
M. Shekarchi, M. Pourfarzib, B. Akbari-Adergani, A. Mehramizi, M. Javanbakht and R. Dinarvand, J. Chromatogr. B Analyt. Technol. Biomed. Life Sci., 931, 50 (2013); https://doi.org/10.1016/j.jchromb.2013.04.041.
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F.R. Harisman and D. Sugiarso, J. Sainsdan Seni. Pomits, 3, 2337 (2014).
R.J. Umpleby, S.C. Baxter, Y. Chen, R.N. Shah and K.D. Shimizu, Anal. Chem., 73, 4584 (2001); https://doi.org/10.1021/ac0105686.
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N.A. Othman, R. Daik, F.B.M. Suah and F.S. Mehamod, Int. J. Appl. Chem., 12, 661 (2016).