Issue

Vol. 30 No. 12 (2018): Vol 30 Issue 12

Copyright (c) 2018 AJC

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Determination of Various Properties of Ethyl Actetate + n-Butanol Binary Mixture at Different Temperatures

https://doi.org/10.14233/ajchem.2018.21573
Soujanya Kaki
Department of Chemistry, CMR College of Engineering & Technology (Autonomous), Hyderabad-501 401, India
D. Rama Chandran
Department of Chemistry, Acharya Nagarjuna University, Guntur-522 510, India

Corresponding Author(s) : Soujanya Kaki

soujanya.kaki@gmail.com

Asian Journal of Chemistry, Vol. 30 No. 12 (2018): Vol 30 Issue 12

Abstract

The present study deals with the variations of ultrasonic velocity, density, viscosity, various acoustic and thermodynamic parameters such as adiabatic compressibility, intermolecular free length, molar volume, acoustic impedance, free volume, internal pressure, enthalpy and also excess thermodynamic properties for n-butanol with ethyl acetate as function of concentration and temperature. All the excess parameters are fitted into the Redlich-Kister equation. And also to compare the ultrasonic sound velocity in ethyl acetate with n-butanol mixture from various theoretical relations of Nomoto and Van Dael Vangeel . These properties can be effectively utilized as a qualitative study to predict the extent of molecular interactions between the components.

Keywords

Intermolecular forces Ethyl actetate n-Butanol Binary mixture Nomoto Van Dael and Vangeel
Kaki, S., & Chandran, D. R. (2018). Determination of Various Properties of Ethyl Actetate + n-Butanol Binary Mixture at Different Temperatures. Asian Journal of Chemistry, 30(12), 2716–2722. https://doi.org/10.14233/ajchem.2018.21573
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. O. Müller and J. Winkelmann, Phys. Rev. E, 59, 2026 (1999); https://doi.org/10.1103/PhysRevE.59.2026.
  2. A. Bagheri and S.A. Mirbakhshi, Phys. Chem. Liq., 54, 529 (2016); https://doi.org/10.1080/00319104.2015.1121783.
  3. D. Belmonte, C. Gatti, G. Ottonello, P. Richet and M. Vetuschi Zuccolini, J. Phys. Chem. A, 120, 8881 (2016); https://doi.org/10.1021/acs.jpca.6b08676.
  4. Z. Chen, Y. Huo, P. Long, H. Shen and J.M. Lee, Phys. Chem. Chem. Phys., 19, 5389 (2017); https://doi.org/10.1039/c6cp08876g.
  5. P. Prabhu and A.R. Venis, Asian J. Chem., 30, 1759 (2018); https://doi.org/10.14233/ajchem.2018.21292.
  6. R.H. Perry and D.W. Green, Perry's Chemical Engineers' Handbook McGraw-Hill: New York, edn 7, pp. 13-20 (1997).
  7. J.H. Hildebrand and R.L. Scott, Regular Solutions, Prentice-Hall: New York, pp. 104-115 (1962).
  8. G. Scatchard, Chem. Rev., 8, 321 (1931); https://doi.org/10.1021/cr60030a010.
  9. J.H. Hildebrand and C.A. Jenks, J. Am. Chem. Soc., 42, 2080 (1920); https://doi.org/10.1021/ja01455a015.
  10. J.H. Hildebrand, J. Am. Chem. Soc., 51, 66 (1929); https://doi.org/10.1021/ja01376a009.
  11. J.H. Hildebrand, Phys. Rev., 34, 984 (1929); https://doi.org/10.1103/PhysRev.34.984.
  12. J.H. Hildebrand, Proc. Nat. Acad. Sci., 13, 267 (1927); https://doi.org/10.1073/pnas.13.5.267.
  13. O. Redlich and A.T. Kister, Ind. Eng. Chem., 40, 345 (1948); https://doi.org/10.1021/ie50458a036.
  14. M.R. Rao, J. Chem. Phys., 9, 682 (1941); https://doi.org/10.1063/1.1750976.
  15. T. Jacobson, Phys. Rev. Lett., 75, 1260 (1995); https://doi.org/10.1103/PhysRevLett.75.1260.
  16. R. Padmanaban, K. Venkatramanan, S. Girivel, K. Kasthuri, A. Usharani, A. Gayathri and R. Vellaichamy, ed.: J. Ebenezar, Mathematical and Experimental Analysis of Ultrasound Velocity and Refractive Index in Binary Mixtures of Pharmaceutically Important Polymer-PEG 600; In: Recent Trends in Materials Science and Applications, Springer International Publishing: Switzerland, pp: 709-722 (2017).
  17. V.S. Rao, T.V. Krishna, T.M. Mohan and P.M. Rao, J. Solution Chem., 46, 281 (2017); https://doi.org/10.1007/s10953-017-0578-y.
  18. A. Saini, A. Harshvardhan and R. Dey, Indian J. Chem., 51A, 21 (2012).
  19. J.O. Hirschfelder, Hirschfelder, J.O., Molecular Theory of Gases and Liquids, John Wiley, New York, p. 29 & 286 (1959).
  20. J.O. Hirschfelder, J. Chem. Educ., 16, 540 (1939); https://doi.org/10.1021/ed016p540.
  21. A. Schmidt, M. Zad, W.E. Acree Jr. and M.H. Abraham, Phys. Chem. Liq., 54, 313 (2016); https://doi.org/10.1080/00319104.2015.1084882.
  22. R. Sharma, R.C. Thakur and B. Saini, Asian J. Chem., 28, 2331 (2016); https://doi.org/10.14233/ajchem.2016.20010.
  23. I.A. Sedov, T.I. Magsumov, M.A. Stolov and B.N. Solomonov, Thermochim. Acta, 623, 9 (2016); https://doi.org/10.1016/j.tca.2015.11.010.
  24. J.P. Singh and R. Sharma, Int. J. Eng. Res. Dev., 5, 48 (2013).
  25. J. Tong, Y. Qu, K. Li, T.-F. Chen, J. Tong and J.-Z. Yang, J. Chem. Thermodyn., 97, 362 (2016); https://doi.org/10.1016/j.jct.2016.02.001.
  26. Y. Xu, H. Zhu and L. Yang, J. Chem. Eng. Data, 58, 2260 (2013); https://doi.org/10.1021/je400331r.
  27. L. Venkatramana, R.L. Gardas, C.N. Rao, K. Sivakumar and K.D. Reddy, J. Sol. Chem., 44, 327 (2015); https://doi.org/10.1007/s10953-015-0309-1.
  28. R.R. Naik, S.V. Bawankar, P.V. Tekade and O.A. Mahodaya, Russ. J. Phys. Chem. A, 89, 152 (2015); https://doi.org/10.1134/S0036024415010227.
  29. R. Mehra and B.B. Malav, Arabian J. Chem., 10, S1894 (2017); https://doi.org/10.1016/j.arabjc.2013.07.018.
  30. B. Kubíková, M. Boèa, J. Mlynáriková, Z. Netriová and Z. Vasková, J. Thermal Anal. Calorim., 125, 497 (2016); https://doi.org/10.1007/s10973-016-5324-y.
  31. K. Saravanakumar, T.G. Lavanya and T.R. Kubendran, J. Eng. Thermophys., 25, 106 (2016); https://doi.org/10.1134/S1810232816020144.
  32. Y. Wang, Q. Liu, L. Qiu, T. Wang, H. Yuan, J. Lin and S. Luo, Spectrochim. Acta A: Mol. Bimol. Spectrosc., 150, 902 (2015); https://doi.org/10.1016/j.saa.2015.06.027.
  33. F. Chen, Z. Yang, Z. Chen, J. Hu, C. Chen and J. Cai, J. Mol. Liq., 209, 683 (2015); https://doi.org/10.1016/j.molliq.2015.06.041.
  34. R. Padmanaban, K. Venkatramanan, S. Girivel, K. Kasthuri, A. Usharani, A. Gayathri and R. Vellaichamy, Recent Trends Mater. Sci. Appl., 189, 709 (2017); https://doi.org/10.1007/978-3-319-44890-9_57.
Read More
Author biographies is not available.
Download
PDF
Statistic
Read Counter : 2 Download : 0