Synthesis and Characterization of Complexes of vic-Dioxime Derivatives with Transition Metal

Abstract

A novel vic-dioxime compound (H₂L) and their transition metal complexes were synthesized for the first time. This compound, N-[(4-(2,4-dihyroxybenzylideneamino)naphthalen-1-yl)]-N'- hydroxy-2-(hydroxyimino)acetimidamide, have been synthesized by starting metarial of naphthalene. The complexes of nickel(II), copper(II) and cobalt(II) with H₂L were prepared. The ligand and its metal complexes were charecterized FT-IR, UV, ¹H NMR, ¹³C NMR, MS, elemental analysis and conductometric measurements.