Propyltriphenylphosphonium Chlorotrioxochromate(VI): A Mild and Efficient Oxidant for Oxidation of Organic Substrates
Corresponding Author(s) : SHAHRIARE GHAMMAMY
shghamami@ikiu.ac.ir; shghamamy@yahoo.com
Asian Journal of Chemistry,
Vol. 20 No. 3 (2008): Vol 20 Issue 3
Abstract
The new mild chromium(VI) oxidizing agent, propyltriphenylphosphonium chlorochromate(VI), (PTriPPCC), was prepared and characterized. This new compound is effective in the oxidation of organic substrates specially alcohols to corresponding carbonyl compounds. The facile oxidation of triphenylphosphine to triphenylphosphine oxide by this reagent in CH3CN provides a clear cut indicating for oxygen atom transfer mechanism.
Keywords
Oxidation
Alcohols
Propyltriphenylphosphonium chlorotrioxochromate
Organic substrate
Chromium(VI)
JAVANSHIR, Z., GHAMMAMY, S., MEHRANI, K., MALEKI, S., & SIAVOSHI, F. (2010). Propyltriphenylphosphonium Chlorotrioxochromate(VI): A Mild and Efficient Oxidant for Oxidation of Organic Substrates. Asian Journal of Chemistry, 20(3), 1791–1794. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/19155
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