Synthesis and Characterization of Zn(II), Cd(II), Hg(II) and Pd(II) Complexes of N″-[(1E,2Z)-2-(hydroxyimino)-1- phenylpropylidene]thiocarbohydrazide
Corresponding Author(s) : R.G. DESHMUKH
ravideshmukh@vsnl.net
Asian Journal of Chemistry,
Vol. 20 No. 3 (2008): Vol 20 Issue 3
Abstract
The ligand, N″-[(1E,2Z)-2-(hydroxyimino)-1-phenylpropylidene] thiocarbohydrazide (HPTCHOPD) has been synthesized by condensation of isonitrosopropiophenone with thiocarbohydrazide in 1:1 molar proportion in presence of ethanol. The complexes of Zn(II), Cd(II), Hg(II) and Pd(II) with ligand HPTCHOPD have been synthesized and characterized. The diamagnetic nature of Zn(II), Cd(II), Hg(II), suggested tetrahedral geometry and square planar geometry for Pd(II) complexes.
Keywords
Isonitrosopropiophenone
Diamagnetic tetra hedral
Thiocarbohydrazide
Square planar
(1)
DESHMUKH, R.; C. SAWANT, D.; G. PINGALE, S. Synthesis and Characterization of Zn(II), Cd(II), Hg(II) and Pd(II) Complexes of N″-[(1E,2Z)-2-(hydroxyimino)-1- phenylpropylidene]thiocarbohydrazide. ajc 2010, 20, 1723-1732.
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