Synthesis, Structure of Me6[14]N4diene+(ClO4)2 and the Cyclic Voltammetry Measurement of its Copper(II) Complex
Asian Journal of Chemistry,
Vol. 20 No. 6 (2008): Vol 20 Issue 6
Abstract
The Me6[14]N4diene·(ClO4)2 (5,5,7,12,12,14-hexamethyl- 1,4,8,11-tetraazacyclotetradeca-4,11-diene·2ClO4) has been synthesized and determined by X-ray diffraction. The crystal is orthorhombic, space group P2(1)/c with unit cell parameters: a = 14.9753(6)Å, b = 9.2169(4)Å, c = 16.4902(9)Å, α = 90º, β = 90º, γ = 90º, V = 2276.07(18)Å3, Z = 8, Dc = 1.411 g/cm3, μ = 0.334 mm-1, T = 293(2) K, Mr = 241.69, F(000) = 1032, R = 0.0626 and wR = 0.1745. The cyclic voltammograms of its copper(II) complex has been investigated.
Keywords
Tetraaza-macrocycle
Crystal structure
Cyclic voltammetry
Bi, J.-H., Chen, Y., Huang, Z.-X., Cui, M., & Hu, N.-L. (2010). Synthesis, Structure of Me6[14]N4diene+(ClO4)2 and the Cyclic Voltammetry Measurement of its Copper(II) Complex. Asian Journal of Chemistry, 20(6), 4887–4890. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/19110
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