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Synthesis and Characterization of Four New Complexes of Cu(I), Cu(II), Ir(III) and Pd(II) Formed by CS2 Insertion in L2MXn (L = PPh3 and Imidazole, X = Cl, n = 2,3)
Corresponding Author(s) : Pradip K. Gogoi
Asian Journal of Chemistry,
Vol. 30 No. 10 (2018): Vol 30 Issue 10, 2018
Abstract
Four new complexes [L2Cu(S2COC2H5)] {L=PPh3 (A), C3H4N2 (B)}, [L2IrCl2(S2COC2H5)] (L=PPh3) (C) and [L2Pd(S2COC2H5)] (L=PPh3) (D) have been synthesized by the insertion of CS2 in L2CuCl2, L3IrCl3 and L2PdCl2, respectively in mixed solvent of dichloromethane and ethanol at room temperature. The complexes have been characterized by FTIR, UV-visible and ESR spectroscopy. All the complexes have been found to be air-stable. Complexes (A), (B) and (D) are distorted square planar while complex (C) is of distorted octahedral geometry.
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- I.K. Bezougli, A. Bashall, M. McPartlin and D.M.P. Mingos, J. Chem. Soc., Dalton Trans., 2671 (1998); https://doi.org/10.1039/a802681e.
- M.R. Torres, A. Perales and J. Ros, Organometallics, 7, 1223 (1988); https://doi.org/10.1021/om00095a033.
- P.K. Gogoi, D.K. Bhuyan and N. Gogoi, Asian J. Chem., 29, 657 (2017); https://doi.org/10.14233/ajchem.2017.20295.
- P.K. Gogoi, G. Borah, N. Bharali and D. Saikia, Indian J. Chem., 46A, 1113 (2007).
- Z. Dong, L. Guanliang, Z. Liang and Z. Chuanjan, Indian J. Chem., 42A, 1102 (2004).
- K. Shalini, P.K. Sharma and N. Kumar, Der Chem. Sinica, 1, 36 (2010).
- B. Buriez, D.J. Cook, K.J. Harlow, A.F. Hill, T. Welton, A.J.P. White, D.J. Williams and J.D.E.T. Wilton-Ely, J. Organomet. Chem., 578, 264 (1999); https://doi.org/10.1016/S0022-328X(98)01130-9.
- E. Lindner, R. Grimmer and H. Weber, Angew. Chem., 82, 639 (1970); https://doi.org/10.1002/ange.19700821517.
- B.J. McCormick, R.I. Kaplan and B.P. Stormer, Can. J. Chem., 49, 699 (1971); https://doi.org/10.1139/v71-117.
- M.C. Baird and G. Wilkinson, J. Chem. Soc. A, 865 (1967); https://doi.org/10.1039/j19670000865.
- M. Baird, G. Hartwell Jr., R. Mason, A.I.M. Rae and G. Wilkinson, Chem. Commun., 92 (1967); https://doi.org/10.1039/c19670000092.
- M.C. Baird, G. Hartwell and G. Wilkinson, J. Chem. Soc. A, 2037 (1967); https://doi.org/10.1039/j19670002037.
- A.C. Lane, C.L. Barnes, M.V. Vollmer and J. R. Walensky, Inorganics, 2, 540 (2014); https://doi.org/10.3390/inorganics2040540.
- O.P. Lam, L. Castro, B. Kosog, F.W. Heinemann, L. Maron and K. Meyer, Inorg. Chem., 51, 781 (2012); https://doi.org/10.1021/ic202535e.
- A.B.P. Lever, Inorganic Electronic Spectroscopy, Elsevier Science Publishing Company Inc., edn 2, p. 341 and 547 (1986).
- A.F. Hill, ed.: E.W. Abel, Co-Ligands in Organotransition Metal Chemistry, In: Organotransition Metal Chemistry, The Royal Society of Chemistry, pp. 22-41 (2002).
References
I.K. Bezougli, A. Bashall, M. McPartlin and D.M.P. Mingos, J. Chem. Soc., Dalton Trans., 2671 (1998); https://doi.org/10.1039/a802681e.
M.R. Torres, A. Perales and J. Ros, Organometallics, 7, 1223 (1988); https://doi.org/10.1021/om00095a033.
P.K. Gogoi, D.K. Bhuyan and N. Gogoi, Asian J. Chem., 29, 657 (2017); https://doi.org/10.14233/ajchem.2017.20295.
P.K. Gogoi, G. Borah, N. Bharali and D. Saikia, Indian J. Chem., 46A, 1113 (2007).
Z. Dong, L. Guanliang, Z. Liang and Z. Chuanjan, Indian J. Chem., 42A, 1102 (2004).
K. Shalini, P.K. Sharma and N. Kumar, Der Chem. Sinica, 1, 36 (2010).
B. Buriez, D.J. Cook, K.J. Harlow, A.F. Hill, T. Welton, A.J.P. White, D.J. Williams and J.D.E.T. Wilton-Ely, J. Organomet. Chem., 578, 264 (1999); https://doi.org/10.1016/S0022-328X(98)01130-9.
E. Lindner, R. Grimmer and H. Weber, Angew. Chem., 82, 639 (1970); https://doi.org/10.1002/ange.19700821517.
B.J. McCormick, R.I. Kaplan and B.P. Stormer, Can. J. Chem., 49, 699 (1971); https://doi.org/10.1139/v71-117.
M.C. Baird and G. Wilkinson, J. Chem. Soc. A, 865 (1967); https://doi.org/10.1039/j19670000865.
M. Baird, G. Hartwell Jr., R. Mason, A.I.M. Rae and G. Wilkinson, Chem. Commun., 92 (1967); https://doi.org/10.1039/c19670000092.
M.C. Baird, G. Hartwell and G. Wilkinson, J. Chem. Soc. A, 2037 (1967); https://doi.org/10.1039/j19670002037.
A.C. Lane, C.L. Barnes, M.V. Vollmer and J. R. Walensky, Inorganics, 2, 540 (2014); https://doi.org/10.3390/inorganics2040540.
O.P. Lam, L. Castro, B. Kosog, F.W. Heinemann, L. Maron and K. Meyer, Inorg. Chem., 51, 781 (2012); https://doi.org/10.1021/ic202535e.
A.B.P. Lever, Inorganic Electronic Spectroscopy, Elsevier Science Publishing Company Inc., edn 2, p. 341 and 547 (1986).
A.F. Hill, ed.: E.W. Abel, Co-Ligands in Organotransition Metal Chemistry, In: Organotransition Metal Chemistry, The Royal Society of Chemistry, pp. 22-41 (2002).