Preparation of Cellulose Graft Copolymer Based on Combination of Ionic Liquids and Microwave Heating

Dan-Hui Liu; Wei Luo; Yu-Zhen Wei; Chun-Xiang Lin; Chao-Yang Du; Ming-Hua Liu

doi:10.14233/ajchem.2014.18489

Issue

Vol. 26 No. 18 (2014): Vol 26 Issue 18

Issue Published : September 1, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Preparation of Cellulose Graft Copolymer Based on Combination of Ionic Liquids and Microwave Heating

https://doi.org/10.14233/ajchem.2014.18489

Dan-Hui Liu

College of Environment & Resources, Fuzhou University, Fuzhou 350002, P.R. China

Wei Luo

College of Environment & Resources, Fuzhou University, Fuzhou 350002, P.R. China

Yu-Zhen Wei

Fujian Gaoke Environmental Protection Research Institute Co. Ltd, Fuzhou 350002, P.R. China

Chun-Xiang Lin

College of Environment & Resources, Fuzhou University, Fuzhou 350002, P.R. China ; Fujian Provincial Technology Exploitation Base of Biomass Resources, Fuzhou 350002, P.R. China

Chao-Yang Du

Fujian Southeast Century Environmental Protection Co. Ltd, Fuzhou 350002, P.R. China

Ming-Hua Liu

College of Environment & Resources, Fuzhou University, Fuzhou 350002, P.R. China ; Fujian Provincial Technology Exploitation Base of Biomass Resources, Fuzhou 350002, P.R. China

Corresponding Author(s) : Chun-Xiang Lin

linchunxiang2002@163.com

Asian Journal of Chemistry, Vol. 26 No. 18 (2014): Vol 26 Issue 18
Article Published : September 3, 2014

Abstract

Cellulose is a promising raw materials available and can be modified through a variety of chemical modifications to obtain functional materials. Cellulose-g-acrylamide copolymer was prepared in a homogeneous medium by using N,N’-methylenebisacrylamide as crosslinker without any radical initiator under microwave radiation. 1-Butyl-3-methylinidazolium chloride an ([Bmim]Cl) ionic liquid is an environment friendly and effective reaction medium, was chosen to dissolve cellulose and the homogeneous graft polymerization of acrylamide onto cellulose. Due to the effect of microwave heating, the reaction time was significantly shorten: 1 min microwave heating was adequate, compared with 0.5-5.0 h, as conventional heating was used. The influences of monomer concentration, crosslilnker dosage, microwave power and reaction time were investigated the obtained cellulose graft copolymer was characterized by IR spectrum, TGA and SEM. A feasible reaction mechanism of grafting based on microwave heating was put forward.

Keywords

Homogeneous Ionic liquid Graft polymerization Cellulose Microwave Acrylamide

Liu, D.-H., Luo, W., Wei, Y.-Z., Lin, C.-X., Du, C.-Y., & Liu, M.-H. (2014). Preparation of Cellulose Graft Copolymer Based on Combination of Ionic Liquids and Microwave Heating. Asian Journal of Chemistry, 26(18), 6295–6298. https://doi.org/10.14233/ajchem.2014.18489

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References

A.K. Jain and A. Suhane, Adv. Eng. Appl. Sci., 1, 23 (2012).

K. Littunen, U. Hippi, L.S. Johansson, M. Österberg, T. Tammelin, J. Laine and J. Seppälä, Carbo-hydr. Polym., 84, 1039 (2011); doi:10.1016/j.carbpol.2010.12.064.

E. Lam, K.B. Male, J.H. Chong, A.C.W. Leung and J.H.T. Luong, Trends Biotechnol., 30, 283 (2012); doi:10.1016/j.tibtech.2012.02.001.

D. Marquardt, C. Vollmer, R. Thomann, P. Steurer, R. Mülhaupt, E. Redel and C. Janiak, Carbon, 49, 1326 (2011); doi:10.1016/j.carbon.2010.09.066.

Z. Cao, H. Ge and S. Lai, Eur. Polym. J., 37, 2141 (2001); doi:10.1016/S0014-3057(01)00070-2.

A. Santhana Krishna Kumar, C. Uday Kumar, V. Rajesh and N. Rajesh, Int. J. Biol. Macromol., 66, 135 (2014); doi:10.1016/j.ijbiomac.2014.02.007 .

J. Wu, G. Meng, Z. Liu et al., Technol. Rev., 30, 39 (2012).

J. Shu, X.J. Li and D.B. Zhao, Adv. Mater. Res., 148-149, 799 (2011).

K. Bhunia, S.S. Sablani, J. Tang and B. Rasco, Comp. Rev. Food Sci. Food Safety, 12, 523 (2013); doi:10.1111/1541-4337.12028.

C. Abrusci, J.L. Pablos, T. Corrales, J. López-Marín, I. Marín and F. Catalina, Int. Biodeterior. Biodegrad., 65, 451 (2011); doi:10.1016/j.ibiod.2010.10.012.

M. Petkovic, K.R. Seddon, L.P.N. Rebelo and C. Silva Pereira, Chem. Soc. Rev., 40, 1383 (2011); doi:10.1039/c004968a.

S. Mallakpour and Z. Rafiee, Prog. Polym. Sci., 36, 1754 (2011); doi:10.1016/j.progpolymsci.2011.03.001.

Issue

Vol. 26 No. 18 (2014): Vol 26 Issue 18

Preparation of Cellulose Graft Copolymer Based on Combination of Ionic Liquids and Microwave Heating

Corresponding Author(s) : Chun-Xiang Lin

Abstract

Keywords

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