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Potential Commercial Applications of Nano-Surfactant in Enhanced Oil: Ni0.5Mn0.5Fe2O4-Chitosan Nanoparticles
Corresponding Author(s) : X.F. Zheng
Asian Journal of Chemistry,
Vol. 26 No. 18 (2014): Vol 26 Issue 18
Abstract
Chitosan nanoparticles with magnetic properties can be potentially used as separation materials in adsorption of oil for enhanced oil recovery. Different from the traditional surfactants, the novel magnetic Ni0.5Mn0.5Fe2O4-chitosan nanoparticles has the advantage of excellent biodegradation and a high level of controllability. The Ni0.5Mn0.5Fe2O4-chitosan nanoparticles with core-shell structure was prepared successfully. The image of transmission electron microscope and the scanning electron microscopy showed that the cubic-shape magnetic Ni0.5Mn0.5Fe2O4 particles were encapsulated by the spherical chitosan nanoparticles. The size of the Ni0.5Mn0.5Fe2O4-chitosan nanoparticles were all below 100 nm. The saturated magnetization of the Ni0.5Mn0.5Fe2O4-chitosan nanoparticles could reach 80 emu/g and showed the characteristics of superparamagnetism at the same time. The evaluation on the interfacial properties of the product showed that the interfacial tension between crude oil and water could be reduce to ultra-low values as low as 10-3 mN/m when the magnetic Ni0.5Mn0.5Fe2O4-chitosan nanoparticle was used in several blocks in Shengli Oilfield without other additives. Meanwhile, the magnetic Ni0.5Mn0.5Fe2O4-chitosan nanoparticles possessed good salt-resisting capacity.
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A. Singh, J.D. Van Hamme and O.P. Ward, Biotechnol. Adv., 25, 99 (2007); doi:10.1016/j.biotechadv.2006.10.004.
J.D. Desai and I.M. Banat, Microbiol. Mol. Biol. Rev., 61, 47 (1997).
E. Carrero, N.V. Queipo, S. Pintos and L.E. Zerpa, J. Petrol. Sci. Eng., 58, 30 (2007); doi:10.1016/j.petrol.2006.11.007.
M. Nitschke, S.G.V.A.O. Costa and J. Contiero, Biotechnol. Prog., 21, 1593 (2005); doi:10.1021/bp050239p.
S. Mukherjee, P. Das and R. Sen, Trends Biotechnol., 24, 509 (2006); doi:10.1016/j.tibtech.2006.09.005.
J.D. Van Hamme, A. Singh and O.P. Ward, Biotechnol. Adv., 24, 604 (2006); doi:10.1016/j.biotechadv.2006.08.001.
R.S. Makkar, S.S. Cameotra and I.M. Banat, AMB Express, 1, 5 (2011); doi:10.1186/2191-0855-1-5.
H.-P. Meyer, Org. Process Res. Dev., 15, 180 (2011); doi:10.1021/op100206p.
S.L. Fox and G.A. Bala, Bioresour. Technol., 75, 235 (2000); doi:10.1016/S0960-8524(00)00059-6.
L.R. Rodrigues, J.A. Teixeira and R. Oliveira, Biochem. Eng. J., 32, 135 (2006); doi:10.1016/j.bej.2006.09.012.
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H.W. Gu, K.M. Xu, C.J. Xu and B. Xu, Chem. Commun., 941 (2006); doi:10.1039/B514130C.
P. Wunderbaldinger, L. Josephson and R. Weissleder, Bioconjug. Chem., 13, 264 (2002); doi:10.1021/bc015563u.
W. Wang, L. Deng, Z.H. Peng and X. Xiao, Enzyme Microb. Technol., 40, 255 (2007); doi:10.1016/j.enzmictec.2006.04.020.
W.S.W. Ngah, S. Ab Ghani and A. Kamari, Bioresour. Technol., 96, 443 (2005); doi:10.1016/j.biortech.2004.05.022.
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Y.C. Chang and D.H. Chen, J. Colloid Interf. Sci., 283, 446 (2005); doi:10.1016/j.jcis.2004.09.010.
C. Shen, H. Chen, S. Wu, Y. Wen, L. Li, Z. Jiang, M. Li and W. Liu, J. Hazard. Mater., 244-245, 689 (2013); doi:10.1016/j.jhazmat.2012.10.061.
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L. Josephson, US Patent, 4,672,040 (1987).