Copyright (c) 2014 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Use of Silica Fume as Low-Cost Absorbent Material for Nickel Removal from Aqueous Solutions
Corresponding Author(s) : Ekrem Kalkan
Asian Journal of Chemistry,
Vol. 26 No. 18 (2014): Vol 26 Issue 18
Abstract
The potential of economically low-cost cellulose containing waste materials like silica fume assessed for nickel adsorption from aqueous solutions. In this study, the potential use of silica fume in the remediation of polluted heavy metal water to remove nickel ions is presented. The effects of contact time, initial nickel concentration, pH, temperature, adsorbent dosage on the uptake of nickel were studied in batch process. The experimental investigation results show that activated silica fume has a high level of adsorption capacity for nickel ion. The adsorption data was correlated with the Langmuir and Freundlich isotherm models. It was found that the Langmuir and Freundlich isotherms fitted well to the data. Consequently, it is concluded that nickel is considerably adsorbed on silica fume and silica fume can be successfully used for the removal of the nickel ions from the aqueous solutions with heavy metals.
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- V.K. Gupta and A. Rastogi, J. Hazard. Mater., 154, 347 (2008); doi:10.1016/j.jhazmat.2007.10.032.
- S. Kalyani, P. Srinivasa Rao and A. Krishnaiah, Chemosphere, 57, 1225 (2004); doi:10.1016/j.chemosphere.2004.08.057.
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- F.V. Pereira, L.V.A. Gurgel and L.F. Gil, J. Hazard. Mater., 176, 856 (2010); doi:10.1016/j.jhazmat.2009.11.115.
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- P.M. Choksi and V.Y. Joshi, Desalination, 208, 216 (2007); doi:10.1016/j.desal.2006.04.081.
- E. Kalkan, H. Nadaroglu and N. Demir, Desalination Water Treat., 44, 180 (2012); doi:10.1080/19443994.2012.691704.
- X. Huang, M. Sillanpëë, B. Dou and E.T. Gjessing, Environ. Pollut., 156, 270 (2008); doi:10.1016/j.envpol.2008.02.014.
- T. Aman, A.A. Kazi, M.U. Sabri and Q. Bano, Colloid Surf. B, 63, 116 (2008); doi:10.1016/j.colsurfb.2007.11.013.
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- E. Kalkan, H. Nadaroglu, N. Dikbaş, E. Taşgin, N. Çelebi, Pol. J. Environ. Stud., 22, 105 (2013).
- R.D. Hooton, ACI Mater. J., 90, 143 (1993).
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- A.H. Toutanji and Z. Bayasi, Cement Concr. Res., 29, 497 (1999); doi:10.1016/S0008-8846(98)00197-5.
- E. Kalkan, Eng. Geol., 87, 220 (2006); doi:10.1016/j.enggeo.2006.07.002.
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- B.D. Ozturk, H. Filik, E. Tutem and R. Apak, Talanta, 53, 263 (2000); doi:10.1016/S0039-9140(00)00382-9.
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- B.M.W.P.K. Amarasinghe and R.A. Williams, Chem. Eng. J., 132, 299 (2007); doi:10.1016/j.cej.2007.01.016.
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- V. Bansal, A.P. O’Mullane and S.K. Bhargava, Electrochem. Commun., 11, 1639 (2009); doi:10.1016/j.elecom.2009.06.018.
- R.E. Treybal, Mass Transfer Operations, McGraw Hill, New York, p. 447 (1980).
- V.K. Gupta and I. Ali, Sep. Purif. Technol., 18, 131 (2000); doi:10.1016/S1383-5866(99)00058-1.
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- F.P. Padilha, F.P. de França and A.C.A. da Costa, Bioresour. Technol., 96, 1511 (2005); doi:10.1016/j.biortech.2004.11.009.
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- M.C.S. Reddy, V. Nirmala, C. Ashwini, Arab. J. Chem., (2013) doi:10.1016/j.arabjc.2013.09.029.
- Mahmoodi, R. Salehi, M. Arami and H. Bahrami, Desalination, 267, 64 (2011); doi:10.1016/j.desal.2010.09.007.
- H. Nadaroglu, N. Celebi, E. Kalkan and G. Tozsin, Jokull J., 63, 87 (2013).
References
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D. Bozic, V. Stankovic, M. Gorgievski, G. Bogdanovic and R. Kovacevic, J. Hazard. Mater., 171, 684 (2009); doi:10.1016/j.jhazmat.2009.06.055.
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F.V. Pereira, L.V.A. Gurgel and L.F. Gil, J. Hazard. Mater., 176, 856 (2010); doi:10.1016/j.jhazmat.2009.11.115.
A.B. Albadarin, A.H. Al-Muhtaseb, N.A. Al-laqtah, G.M. Walker, S.J. Allen and M.N.M. Ahmad, Chem. Eng. J., 169, 20 (2011); doi:10.1016/j.cej.2011.02.044.
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I. Villaescusa, N. Fiol, M. Martinez, N. Miralles, J. Poch and J. Serarols, Water Res., 38, 992 (2004); doi:10.1016/j.watres.2003.10.040.
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E. Malkoc and Y. Nuhoglu, J. Hazard. Mater., 127, 120 (2005); doi:10.1016/j.jhazmat.2005.06.030.
B. Tansel, Recent Pat. Chem. Eng., 1, 17 (2008); doi:10.2174/2211334710801010017.
T.A. Kurniawan, G.Y.S. Chan, W.H. Lo and S. Babel, Sci. Total Environ., 366, 409 (2006); doi:10.1016/j.scitotenv.2005.10.001.
A.F. Bertocchi, M. Ghiani, R. Peretti and A. Zucca, J. Hazard. Mater., 134, 112 (2006); doi:10.1016/j.jhazmat.2005.10.043.
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S.V. Dimitrova and D.R. Mehanjiev, Water Res., 34, 1957 (2000); doi:10.1016/S0043-1354(99)00328-0.
E. Kalkan, H. Nadaroglu, N. Dikbaş, E. Taşgin, N. Çelebi, Pol. J. Environ. Stud., 22, 105 (2013).
R.D. Hooton, ACI Mater. J., 90, 143 (1993).
C.D. Atis, F. Ozcan, A. Kilic, O. Karahan, C. Bilim and M.H. Severcan, Build. Environ., 40, 1678 (2005); doi:10.1016/j.buildenv.2004.12.005.
A.H. Toutanji and Z. Bayasi, Cement Concr. Res., 29, 497 (1999); doi:10.1016/S0008-8846(98)00197-5.
E. Kalkan, Eng. Geol., 87, 220 (2006); doi:10.1016/j.enggeo.2006.07.002.
E. Kalkan, Appl. Clay Sci., 52, 345 (2011); doi:10.1016/j.clay.2011.03.014.
E. Kalkan and S. Akbulut, Eng. Geol., 73, 145 (2004); doi:10.1016/j.enggeo.2004.01.001.
E. Kalkan, Appl. Clay Sci., 43, 296 (2009); doi:10.1016/j.clay.2008.09.002.
E. Kalkan, Cold Reg. Sci. Technol., 58, 130 (2009); doi:10.1016/j.coldregions.2009.03.011.
E. Kalkan, Appl. Clay Sci., 80-81, 117 (2013); doi:10.1016/j.clay.2013.06.014.
B.D. Ozturk, H. Filik, E. Tutem and R. Apak, Talanta, 53, 263 (2000); doi:10.1016/S0039-9140(00)00382-9.
J.D. Seader and E.J. Henly, Separation Process Principles, John Wiley & Sons Inc. (2006).
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N. Celebi, H. Nadaroglu and E. Kalkan, Fresenius Environ. Bull., 21, 1982 (2012).
V.K. Gupta, C.K. Jain, I. Ali, M. Sharma and V.K. Saini, Water Res., 37, 4038 (2003); doi:10.1016/S0043-1354(03)00292-6.
P.S. Kumar, K. Ramakrishnan and R. Gayathri, J. Eng. Sci. Technol., 5, 232 (2010).
H.A. Elliott and C.P. Huang, Water Res., 15, 849 (1981); doi:10.1016/0043-1354(81)90139-1.
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B. Bayat, J. Hazard. Mater., 95, 251 (2002); doi:10.1016/S0304-3894(02)00140-1.
M. Imamoglu and O. Tekir, Desalination, 228, 108 (2008); doi:10.1016/j.desal.2007.08.011.
S.S. Shukla, L.J. Yu, K.L. Dorris and A. Shukla, J. Hazard. Mater., 121, 243 (2005); doi:10.1016/j.jhazmat.2004.11.025.
A. Benhammou, A. Yaacoubi, L. Nibou and B. Tanouti, J. Colloid Interf. Sci., 282, 320 (2005); doi:10.1016/j.jcis.2004.08.168.
M.M. Rashad, M.M. Hessien, E.A. Abdel-Aal, K. El-Barawy and R.K. Singh, Powder Technol., 205, 149 (2011); doi:10.1016/j.powtec.2010.09.005.
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J. Das, B.S. Patra, N. Baliarsingh and K.M. Parida, Appl. Clay Sci., 32, 252 (2006); doi:10.1016/j.clay.2006.02.005.
S. Cay, A. Uyanik and A. Ozasik, Sep. Purif. Technol., 38, 273 (2004); doi:10.1016/j.seppur.2003.12.003.
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H. Nadaroglu, E. Kalkan and N. Demir, Desalination, 251, 90 (2010); doi:10.1016/j.desal.2009.09.138.
V. Bansal, A.P. O’Mullane and S.K. Bhargava, Electrochem. Commun., 11, 1639 (2009); doi:10.1016/j.elecom.2009.06.018.
R.E. Treybal, Mass Transfer Operations, McGraw Hill, New York, p. 447 (1980).
V.K. Gupta and I. Ali, Sep. Purif. Technol., 18, 131 (2000); doi:10.1016/S1383-5866(99)00058-1.
R. Shawabkeh, A. Al-Harahsheh and A. Al-Otoom, Sep. Purif. Technol., 40, 251 (2004); doi:10.1016/j.seppur.2004.03.006.
M. Minamisawa, H. Minamisawa, S. Yoshida and N. Takai, J. Agric. Food Chem., 52, 5606 (2004); doi:10.1021/jf0496402.
S.K. Srivastava, G. Bhattacharjee, R. Tyagi, N. Pant and N. Pal, Environ. Technol. Lett., 9, 1173 (1988); doi:10.1080/09593338809384679.
M. Ajmal, A. Hussain Khan, S. Ahmad and A. Ahmad, Water Res., 32, 3085 (1998); doi:10.1016/S0043-1354(98)00067-0.
F.P. Padilha, F.P. de França and A.C.A. da Costa, Bioresour. Technol., 96, 1511 (2005); doi:10.1016/j.biortech.2004.11.009.
M. Rao, A.V. Parwate and A.G. Bhole, Waste Manage., 22, 821 (2002); doi:10.1016/S0956-053X(02)00011-9.
V. Padmavathy, P. Vasudevan and S.C. Dhingra, Process Biochem., 38, 1389 (2003); doi:10.1016/S0032-9592(02)00168-1.
F.A.A. Al-Rub, M. Kandah and N. Al-Dabaybeh, Eng. Life Sci., 2, 111 (2002); doi:10.1002/1618-2863(200204)2:4<111::AID-ELSC111>3.0.CO;2-Q.
Y.S. Ho, D.A. John Wase and C.F. Forster, Water Res., 29, 1327 (1995); doi:10.1016/0043-1354(94)00236-Z.
R. Gundogan, B. Acemioglu and M.H. Alma, J. Colloid Interf. Sci., 269, 303 (2004); doi:10.1016/S0021-9797(03)00762-8.
E.G. Pradas, M.V. Sanchez, E.C. Cruz, M.S. Viciana and M.E. Perez, J. Chem. Technol. Biotechnol., 59, 289 (1994); doi:10.1002/jctb.280590312.
G. McKay, Use of Adsorbents for the Removal of Pollutants from Waste Water, CRC Press, Bocca Baton, FL (1985).
M. Arami, N. Limaee and N. Mahmoodi, Chem. Eng. J., 139, 2 (2008); doi:10.1016/j.cej.2007.07.060.
M.C.S. Reddy, V. Nirmala, C. Ashwini, Arab. J. Chem., (2013) doi:10.1016/j.arabjc.2013.09.029.
Mahmoodi, R. Salehi, M. Arami and H. Bahrami, Desalination, 267, 64 (2011); doi:10.1016/j.desal.2010.09.007.
H. Nadaroglu, N. Celebi, E. Kalkan and G. Tozsin, Jokull J., 63, 87 (2013).