Copyright (c) 2014 AJC
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Spectrophotometric Determination of Monosaccharide Composition of Wood (Pinus brutia Ten.) Using Artificial Neural Network Modelling
Corresponding Author(s) : Samim Yasar
Asian Journal of Chemistry,
Vol. 26 No. 18 (2014): Vol 26 Issue 18
Abstract
Spectrophotometric data were used to estimate monosaccharide content in Pinus brutia Ten. (brutian pine) wood using artificial neural network (ANN) modelling. The monosaccharide composition of P. brutia Ten. samples ranged for glucose from 42.33 to 54.67 %, for mannose from 8.55 to 11.95 %, for xylose from 7.15 to 9.83 %, for galactose from 1.72 to 2.49 % and for arabinose from 1.19 to 1.65 %, based on extractive free dry wood. Three layered artificial neural network model with six hidden neurons gave in general better results with correlation R2 values between 0.9987 and 0.9916 in training and between 0.9984 and 0.9902 in testing. In validation, this model was scored with a small average relative error (1.2 %) fairly good.
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References
D. Fengel and G. Wegener, Wood-Chemistry, Ultrastructure Reaction, Walter de Gruyter, Berlin (1984).
J. Lee, J. Biotechnol., 56, 1 (1997); doi:10.1016/S0168-1656(97)00073-4.
B.K. Ahring, D. Licht, A.S. Schmidt, P. Sommer and A.B. Thomsen, Bioresour. Technol., 68, 3 (1999); doi:10.1016/S0960-8524(98)00077-7.
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J. Robinson, J.D. Keating, S.D. Mansfield and J.N. Saddler, Enzyme Microb. Technol., 33, 757 (2003); doi:10.1016/S0141-0229(03)00192-3.
J. Söderström, L. Pilcher, M. Galbe and G. Zacchi, Biomass Bioenergy, 24, 475 (2003); doi:10.1016/S0961-9534(02)00148-4.
A. Sues, R. Millati, L. Edebo and M.J. Taherzadeh, FEMS Yeast Res., 5, 669 (2005); doi:10.1016/j.femsyr.2004.10.013.
W. Blaschek, in eds.: G. Franz, Polysaccharide, Springer Verlag, Berlin-Heidelberg-New York, Chap. 2, pp. 17-47 (1992).
R. Li, J.J. Volenec, B.C. Joern and S.M. Cunningham, Crop Sci., 36, 617 (1996); doi:10.2135/cropsci1996.0011183X003600030016x.
J. Moreno, C. Vargas-Garcia, M.J. Lopez and G. Sanchez-Serrano, J. Appl. Microbiol., 86, 439 (1999); doi:10.1046/j.1365-2672.1999.00680.x.
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F.L. Consoli and S.B. Vinson, Comp. Biochem. Physiol. B, 132, 711 (2002); doi:10.1016/S1096-4959(02)00087-8.
A.K.K. Achakzai, S.A. Kayani, M. Yaqoob and A. Nabi, J. Biol. Sci., 3, 882 (2003); doi:10.3923/jbs.2003.882.891.
A. Oren and L. Mana, FEMS Microbiol. Lett., 223, 83 (2003); doi:10.1016/S0378-1097(03)00345-8.
G.D. Manrique and F.M. Lajolo, Postharvest Biol. Technol., 33, 11 (2004); doi:10.1016/j.postharvbio.2004.01.007.
L. Zhang, Z. Lu, Z. Yu and X. Gao, Food Contr., 16, 279 (2005); doi:10.1016/j.foodcont.2004.03.007.
R. Meder, S. Gallagher, K.L. Mackie, H. Bohler and R.R. Meglen, Holzforschung, 53, 261 (1999); doi:10.1515/HF.1999.044.
J. Rodrigues, J. Puls, O. Faix and H. Pereira, Holzforschung, 55, 265 (2001); doi:10.1515/HF.2001.044.
S. Yasar, Acta Chim. Slov., 52, 435 (2005).
J. Zupan and J. Gasteiger, Anal. Chim. Acta, 248, 1 (1991); doi:10.1016/S0003-2670(00)80865-X.
J. Zupan and J. Gasteiger, Neural Networks for Chemists-An Introduction, VCH, Weinheim (1993).
J. Zupan, Acta Chim. Slov., 41, 327 (1994).
S. Agatonovic-Kustrin, M. Zecevic and Lj. Zivanovic, J. Pharm. Biomed. Anal., 21, 95 (1999); doi:10.1016/S0731-7085(99)00133-8.
H.M. Henrique, E.L. Lima and D.E. Seborg, Chem. Eng. Sci., 55, 5457 (2000); doi:10.1016/S0009-2509(00)00170-6.
Z. Ramadan, X.-H. Song, P.K. Hopke, M.J. Johnson and K.M. Scow, Anal. Chim. Acta, 446, 231 (2001); doi:10.1016/S0003-2670(01)00999-0.
R.B. Boozarjomehry and W.Y. Svrcek, Comput. Chem. Eng., 25, 1075 (2001); doi:10.1016/S0098-1354(01)00680-9.
M.S. Chun, J.J. Yi and Y.H. Moon, J. Mater. Process. Technol., 111, 146 (2001); doi:10.1016/S0924-0136(01)00499-X.
M. Fullana, F. Trabelsi and F. Recasens, Chem. Eng. Sci., 55, 79 (2000); doi:10.1016/S0009-2509(99)00182-7.
X. Yao, X. Zhang, R. Zhang, M. Liu, Z. Hu and B. Fan, Talanta, 57, 297 (2002); doi:10.1016/S0039-9140(02)00031-0.
R.C. Pettersen, V.H. Schwandt and M.J. Effland, J. Chromatogr. Sci., 22, 478 (1984); doi:10.1093/chromsci/22.11.478.
B. Cao, U. Tschirner, S. Ramaswamy and A. Webb, Tappi J., 80, 193 (1997).