Copyright (c) 2014 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Enhanced Control on the Electro Deposition Through Magnetic Field Using Reverse Microemulsion as Template
Corresponding Author(s) : Tajamal Hussain
Asian Journal of Chemistry,
Vol. 26 No. 18 (2014): Vol 26 Issue 18
Abstract
Reverse micro emulsion is often used for the synthesis of metal nanoparticles. Such prepared metallic nanoparticles may be used as catalyst for oxidation of methanol occurring in fuel cell. Nickel electrodes were modified by electro chemical deposition of the nickel nanoparticles. In-continuous deposition was occurred on using reverse micro emulsion. This problem was addressed on having the same in the presence of magnetic field. In fact, Lorentz force started playing role in terms of large mass transfer rate when magnetic field perpendicular to the direction of current was applied. Surface analysis of the both types of the modified electrode was done with the help scanning electron microscopy. Electro chemical and catalytic studies of both modified electrodes were done. Results of these studies encouraged the employment of the magnetic field during the electro chemical deposition of the metals.
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- T. Hellweg, Curr. Opin. Colloid Interface Sci., 7, 50 (2002); doi:10.1016/S1359-0294(02)00004-3.
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- R.A. Mackay, Colloids Surf. A, 82, 1 (1994); doi:10.1016/0927-7757(93)02610-Q.
- A.W. Adamson, Physical Chemistry of Surfaces, John Wiley & Sons, New York (1976).
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- V. Ganesh and V. Lakshminarayanan, Electrochim. Acta, 49, 3561 (2004); doi:10.1016/j.electacta.2004.03.024.
- I.J. Brown and S. Sotiropoulos, Electrochim. Acta, 46, 2711 (2001); doi:10.1016/S0013-4686(01)00481-9.
- I.J. Brown and S. Sotiropoulos, J. Appl. Electrochem., 30, 107 (2000); doi:10.1023/A:1003888402752.
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References
T. Hellweg, Curr. Opin. Colloid Interface Sci., 7, 50 (2002); doi:10.1016/S1359-0294(02)00004-3.
R.A. Mackay and J. Texter, Electrochemistry in Colloids and Dispersions, VCH, New York (1992).
J.F. Rusling, Acc. Chem. Res., 24, 75 (1991); doi:10.1021/ar00003a003.
R.A. Mackay, Colloids Surf. A, 82, 1 (1994); doi:10.1016/0927-7757(93)02610-Q.
A.W. Adamson, Physical Chemistry of Surfaces, John Wiley & Sons, New York (1976).
C. Fu, H. Zhou, H. Wu, J. Chen and Y. Kuang, Colloid Polym. Sci., 286, 1499 (2008); doi:10.1007/s00396-008-1921-z.
C.H. Lu, H.H. Chang, C. Yen and J. Tamkang, Sci. Eng., 7, 199 (2004).
H. Li, J. Liu, S. Xie, M. Qiao, W. Dai and H. Li, J. Catal., 259, 104 (2008); doi:10.1016/j.jcat.2008.07.015.
T.C. Franklin, S. Mathew and K.L. Mittal, Surfactant in Solutions, Plenum, New York (1989).
J.H. Fendler, Membrane Mimetic Chemistry, Wiley-Interscience, New York (1982).
E. Pelizzetti and E. Pramauro, Anal. Chim. Acta, 169, 1 (1985); doi:10.1016/S0003-2670(00)86203-0.
P.L. Luisi, M. Giomini, M.P. Pileni and B.H. Robinson, Biochim. Biophys. Acta, 947, 209 (1988); doi:10.1016/0304-4157(88)90025-1.
K. Shinoda and B. Lindman, Langmuir, 3, 135 (1987); doi:10.1021/la00074a001.
A. Manna, T. Imae, T. Yogo, K. Aoi and M. Okazaki, J. Colloid Interf. Sci., 256, 297 (2002); doi:10.1006/jcis.2002.8691.
M.P. Pileni, Nat. Mater., 2, 145 (2003); doi:10.1038/nmat817.
H. Zhou, C. Peng, S. Jiao, W. Zeng, J. Chen and Y. Kuang, Electrochem. Commun., 8, 1142 (2006); doi:10.1016/j.elecom.2006.05.015.
C. Destrée, J. Ghijsen and J. B.Nagy, Langmuir, 23, 1965 (2007); doi:10.1021/la0534726.
L. Xiong and A. Manthiram, Solid State Ion., 176, 385 (2005); doi:10.1016/j.ssi.2004.08.005.
X. Zhang and K.Y. Chan, Chem. Mater., 15, 451 (2003); doi:10.1021/cm0203868.
R. Campbell, M.G. Bakker, C. Treiner and J. Chevalet, J. Porous Mater., 11, 63 (2004); doi:10.1023/B:JOPO.0000027361.04282.f6.
R. Campbell, M.G. Bakker, G. Havrilla, V. Montoya, E. Kenik and M. Shamsuzzoha, Micropor. Mesopor. Mater., 97, 114 (2006); doi:10.1016/j.micromeso.2006.08.011.
A. Seghiouer, J. Chevalet, A. Barhoun and F. Lantelme, J. Electroanal. Chem., 442, 113 (1998); doi:10.1016/S0022-0728(97)00498-1.
J.P. Hsu and A. Nacu, J. Colloid Interf. Sci., 259, 374 (2003); doi:10.1016/S0021-9797(02)00207-2.
W. Zhang, X. Qiao and J. Chen, Colloids Surf. A, 299, 22 (2007); doi:10.1016/j.colsurfa.2006.11.012.
W. Zhang, X. Qiao and J. Chen, Chem. Phys., 330, 495 (2006); doi:10.1016/j.chemphys.2006.09.029.
L. Huang, H. Wang, Z. Wang, A. Mitra, K.N. Bozhilov and Y.S. Yan, Adv. Mater., 14, 61 (2002); doi:10.1002/1521-4095(20020104)14:1<61::AID-ADMA61>3.0.CO;2-Y.
Y.X. Pang and X. Bao, J. Mater. Chem., 12, 3699 (2002); doi:10.1039/b206501k.
C. Fu, H. Zhou, D. Xie, L. Sun, Y. Yin, J. Chen and Y. Kuang, Colloid Polym. Sci., 288, 1097 (2010); doi:10.1007/s00396-010-2238-2.
H. Zhou, C. Peng, C. Fu, J. An, H. Zou, Y. Wang, Y. Xu and Y. Kuang, J. Cent. South Univ. Technol., 17, 40 (2010); doi:10.1007/s11771-010-0008-4.
H. Zhou, C. Peng, S. Jiao, W. Zeng, J. Chen and Y. Kuang, Electrochem. Commun., 8, 1142 (2006); doi:10.1016/j.elecom.2006.05.015.
V. Ganesh and V. Lakshminarayanan, J. Colloid Interf. Sci., 349, 300 (2010); doi:10.1016/j.jcis.2010.05.014.
A. Bund, A. Ispas and G. Mutschke, Sci. Technol. Adv. Mater., 9, 024208 (2008); doi:10.1088/1468-6996/9/2/024208.
M. Ebadi, W.J. Basirun and Y. Alias, J. Chem. Sci., 122, 279 (2010); doi:10.1007/s12039-010-0032-9.
M. Ebadi, W.J. Basirun, Y. Alias and M. Mahmoudian, Chem. Cent. J., 4, 14 (2010); doi:10.1186/1752-153X-4-14.
V. Ganesh and V. Lakshminarayanan, Electrochim. Acta, 49, 3561 (2004); doi:10.1016/j.electacta.2004.03.024.
I.J. Brown and S. Sotiropoulos, Electrochim. Acta, 46, 2711 (2001); doi:10.1016/S0013-4686(01)00481-9.
I.J. Brown and S. Sotiropoulos, J. Appl. Electrochem., 30, 107 (2000); doi:10.1023/A:1003888402752.
V. Ganesh and V. Lakshminarayanan, J. Colloid Interf. Sci., 349, 300 (2010); doi:10.1016/j.jcis.2010.05.014.
A.T. Shah, M.I. Din, U. Farooq, M.T.Z. Butt, M. Athar, M.A. Chaudhary, M.N. Ahmad and M.L. Mirza, Colloids Surf. A, 405, 19 (2012); doi:10.1016/j.colsurfa.2012.04.022.