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Preparation and Characterization of Poly Metal Complexes Derived from 5,5'-Methylenebis(2-Hydroxy Benzaldehyde) and 6,6'-Methylenebis(2-hydroxy naphthaldehyde) with Hydrazine and 4-Amino Phenyl Ether
Corresponding Author(s) : Ambreen Shah
Asian Journal of Chemistry,
Vol. 26 No. 18 (2014): Vol 26 Issue 18
Abstract
Some new Schiff base polymers were prepared by polycondensation of 5,5'-methylenebis(2- hydroxy benzaldehyde) and 6,6'-methylenebis(2-hydroxy naphthaldehyde) with 4-aminophenyl ether and hydrazine in acidic media. After polymerization, Schiff base polymers were treated with Cu and Ni acetate to prepare poly metal chelates by solution technique. The poly metal chelates were characterized by elemental micro-analysis, IR, UV-visible and spectroscopic techniques. The solutions of poly metal chelates were prepared in THF at 30 °C, to investigate viscometric study by dilute solution viscometry (DSV) method. The intrinsic viscosities of these poly metal complexes were ranged within 0.393-0.5201 dL/g as compared to 0.174-0.249 dL/g for Schiff base polymers in THF. Thermoanalytical studies of poly metal complexes were examined and compared.
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- C.-C. Kwok, S.-C. Yu, I.H.T. Sham and C.-M. Che, Chem. Commun, 2758 (2004); doi:10.1039/b412762e.
- M.A.A. Akl, I.M.M. Kenawy and R.R. Lasheen, Microchem. J., 78, 143 (2004); doi:10.1016/j.microc.2004.03.019.
- Z.H. Xie, F.Z. Xie, L.Q. Guo, X.C. Lin and G.N. Chen, J. Sep. Sci., 28, 462 (2005); doi:10.1002/jssc.200401928.
- E.A. Moawed, M.A.A. Zaid and M.F. El-Shahat, Acta Chromatogr., 15, 220 (2005).
- M.A. Hamed, K.S. Abou- El-Sherbini and H. R. Lotfy, J. Chin. Chem. Soc., 53, 605 (2006); doi:10.1002/jccs.200600079.
- S. Çavuş and G. Gürdag, Polym. Adv. Technol., 19, 1209 (2008); doi:10.1002/pat.1113.
- C. Noureddine, A. Lekhmici, Q. Ali, M. Ruba, M. Zalloum and S. Mubarak, J. Macromol. Sci. Part A, 47, 177 (2010); doi:10.1080/10601320903458796.
- M.Y. Khuhawar, A. Shah and M.A. Mughal, Chin. J. Polym. Sci., 25, 399 (2007); doi:10.1142/S0256767907002278.
- M. Tunçel, A. Özbülbül and S. Serin, React. Funct. Polym., 68, 292 (2008); doi:10.1016/j.reactfunctpolym.2007.08.012.
- Z. Rezvani, K. Nejati, E. Alizadeh and R. Sammimi, J. Mol. Cryst. Liq., 533, 16 (2010); doi:10.1080/15421406.2010.526554.
- G. Aysegul, T. Mehmet, D. Havva and R. Alan Wheatley, Inorg. Chim. Acta, 358, 1785 (2005); doi:10.1016/j.ica.2004.11.026.
- M.Y. Khuhawar and A.H. Channar, J. Macromol. Sci. A, 32, 523 (1995); doi:10.1080/10601329508019197.
- M.Y. Khuhawar, M.A. Mughal and A.H. Channar, Eur. Polym. J., 40, 805 (2004); doi:10.1016/j.eurpolymj.2003.11.020.
- A. Shah and A.A. Shah, Asian J. Chem., 25, 4215 (2013); doi:10.14233/ajchem.2013.13906.
- Ö. Saatçilar, N. Şatiroglu, S. Bektaş, Ö. Genç and A. Denizli, React. Funct. Polym., 50, 41 (2002); doi:10.1016/S1381-5148(01)00088-8.
- V.N.R. Pillai and A. Mohan, in ed.: K.S.V. Srinivasan, Macromolecules New Frontiers, Allied Publishers Ltd., vol. II, p. 433 (1998).
- H. Mart and A.R. Vilayetoğlu, Polym. Degrad. Stab., 83, 255 (2004); doi:10.1016/S0141-3910(03)00270-2.
- M.E. El-Sayed Mansour, A. A. Kaseem, H. Nourel-Din and A. A. El-Toukhy, Macromol. Rep., 28, 103 (1991).
- A. Shah and A.A. Shah, Asian J. Chem., 25, 7513 (2013); doi:10.14233/ajchem.2013.14958.
References
C.-C. Kwok, S.-C. Yu, I.H.T. Sham and C.-M. Che, Chem. Commun, 2758 (2004); doi:10.1039/b412762e.
M.A.A. Akl, I.M.M. Kenawy and R.R. Lasheen, Microchem. J., 78, 143 (2004); doi:10.1016/j.microc.2004.03.019.
Z.H. Xie, F.Z. Xie, L.Q. Guo, X.C. Lin and G.N. Chen, J. Sep. Sci., 28, 462 (2005); doi:10.1002/jssc.200401928.
E.A. Moawed, M.A.A. Zaid and M.F. El-Shahat, Acta Chromatogr., 15, 220 (2005).
M.A. Hamed, K.S. Abou- El-Sherbini and H. R. Lotfy, J. Chin. Chem. Soc., 53, 605 (2006); doi:10.1002/jccs.200600079.
S. Çavuş and G. Gürdag, Polym. Adv. Technol., 19, 1209 (2008); doi:10.1002/pat.1113.
C. Noureddine, A. Lekhmici, Q. Ali, M. Ruba, M. Zalloum and S. Mubarak, J. Macromol. Sci. Part A, 47, 177 (2010); doi:10.1080/10601320903458796.
M.Y. Khuhawar, A. Shah and M.A. Mughal, Chin. J. Polym. Sci., 25, 399 (2007); doi:10.1142/S0256767907002278.
M. Tunçel, A. Özbülbül and S. Serin, React. Funct. Polym., 68, 292 (2008); doi:10.1016/j.reactfunctpolym.2007.08.012.
Z. Rezvani, K. Nejati, E. Alizadeh and R. Sammimi, J. Mol. Cryst. Liq., 533, 16 (2010); doi:10.1080/15421406.2010.526554.
G. Aysegul, T. Mehmet, D. Havva and R. Alan Wheatley, Inorg. Chim. Acta, 358, 1785 (2005); doi:10.1016/j.ica.2004.11.026.
M.Y. Khuhawar and A.H. Channar, J. Macromol. Sci. A, 32, 523 (1995); doi:10.1080/10601329508019197.
M.Y. Khuhawar, M.A. Mughal and A.H. Channar, Eur. Polym. J., 40, 805 (2004); doi:10.1016/j.eurpolymj.2003.11.020.
A. Shah and A.A. Shah, Asian J. Chem., 25, 4215 (2013); doi:10.14233/ajchem.2013.13906.
Ö. Saatçilar, N. Şatiroglu, S. Bektaş, Ö. Genç and A. Denizli, React. Funct. Polym., 50, 41 (2002); doi:10.1016/S1381-5148(01)00088-8.
V.N.R. Pillai and A. Mohan, in ed.: K.S.V. Srinivasan, Macromolecules New Frontiers, Allied Publishers Ltd., vol. II, p. 433 (1998).
H. Mart and A.R. Vilayetoğlu, Polym. Degrad. Stab., 83, 255 (2004); doi:10.1016/S0141-3910(03)00270-2.
M.E. El-Sayed Mansour, A. A. Kaseem, H. Nourel-Din and A. A. El-Toukhy, Macromol. Rep., 28, 103 (1991).
A. Shah and A.A. Shah, Asian J. Chem., 25, 7513 (2013); doi:10.14233/ajchem.2013.14958.