Copyright (c) 2014 AJC
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Physico-Chemical Properties of Organic Nonlinear Optical Crystal for Frequency Doubling: Morpholinium Hydrogen Tartrate
Corresponding Author(s) : R. Kesavasamy
Asian Journal of Chemistry,
Vol. 26 No. 18 (2014): Vol 26 Issue 18
Abstract
Nonlinear optical crystal of morpholinium hydrogen tartrate have been synthesized and grown in aqueous solution by slow evaporation technique. The cell parameters of the grown crystal is identified by single crystal X-ray diffraction analysis which confirms that the morpholinium hydrogen tartrate crystallizes in orthorhombic system with noncentro symmetric space group. The powder X-ray diffraction pattern of the grown crystal has been indexed. FT-IR spectrum was recorded to identify the various functional groups of morpholinium hydrogen tartrate. The various kinds of protons and carbons of morpholinium hydrogen tartrate have been identified using 1H and 13C NMR spectral analyses. The range of optical absorption was ascertained by recording UV-visible NIR spectral studies. The TG/DTA studies of the grown crystal has been revealed. The mechanical property of the grown crystal was analyzed using Vickers microhardness studies. The nonlinear optical crystal activity of the crystal is confirmed by Kurtz-Perry powder technique.
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References
D.S. Chemla and J. Zyss, Nonlinear Optical Properties of Organic molecules and Crystals, vol. 1, Academic Press, London, (1987).
J. Badan, R. Hierle, A. Perigand and J. Zyss, In: Williams (Ed), Nonlinear Optical Properties of Organic molecules and Polymeric Materials, Am. Chem. Soc., Washington, DC, Vol. 233, p. D5 (1993).
D. Xu, M. Jiang and Z. Tan, Acta Chim. Sin., 41, 570 (1983).
A. Parkin, I.D.H. Oswald and S. Parsons, Acta Crystallogr. B, 60, 219 (2004); doi:10.1107/S0108768104003672.
Z. Dega-Szafran, I. Gaszczyk, D. Maciejewska, M. Szafran, E. Tykarska and I. Wawer, J. Mol. Struct., 560, 261 (2001); doi:10.1016/S0022-2860(00)00754-7.
I. Majerz, E. Kwiatkowska and A. Koll, J. Mol. Struct., 831, 106 (2007); doi:10.1016/j.molstruc.2006.07.029.
H. Ratajczak, J. Baran, J. Barycki, S. Debrus, M. May, A. Pietraszko, H.M. Ratajczak, A. Tramer and J. Venturini, J. Mol. Struct., 555, 149 (2000); doi:10.1016/S0022-2860(00)00596-2.
C.B. Aakeroy, P.B. Hitchcock and K.R. Seddon, J. Chem. Soc. Chem. Commun., 7, 553 (1992); doi:10.1039/c39920000553.
C.B. Aakeroy and K.R. Seddon, Chem. Soc. Rev., 22, 397 (1997); doi:10.1039/cs9932200397.
C.B. Aakeroy, Acta Crystallogr. B, 53, 569 (1997); doi:10.1107/S0108768197008446.
U. Rychlewska and R. Warzajtis, Acta Crystallogr. B, 56, 833 (2000); doi:10.1107/S0108768100004274.
K. Rajagopal, M. Subha Nandhini, R.V. Krishnakumar and S. Natarajan, Acta Crystallogr. Sect. E Struct. Rep. Online, 58, o1306 (2002); doi:10.1107/S1600536802019414.
S.A.M. Britto Dhas and S. Natarajan, Cryst. Res. Technol., 42, 471 (2007); doi:10.1002/crat.200610850.
M.K. Marchewka, J. Baran, A. Pietraszko, A. Haznar, S. Debrus and H. Ratajczak, Solid State Sci., 5, 509 (2003); doi:10.1016/S1293-2558(03)00029-3.
M.K. Marchewka, H. Ratajczak and S. Debrus, Opt. Phys., 12, 113 (2003); doi:10.1142/S0218863503001274.
J. Shen, J. Zheng, Y. Che and B. Xi, J. Cryst. Growth, 257, 136 (2003); doi:10.1016/S0022-0248(03)01408-8.
V. Subhashini, S. Ponnusamy and C. Muthamizhchelvan, Spectrochim. Acta A, 87, 265 (2012); doi:10.1016/j.saa.2011.11.050.
M.-L. Liu, Acta Crystallogr. Sect. E Struct. Rep. Online, 68, o289 (2012); doi:10.1107/S1600536811055759.
R. Sankar, C.M. Raghavan, M. Balaji, R.M. Kumar and R. Jayavel, Cryst. Growth Des., 7, 348 (2007); doi:10.1021/cg060566k.
A. Ashour, N. El-Kadry and S.A. Mahmoud, Thin Solid Films, 269, 117 (1995); doi:10.1016/0040-6090(95)06868-6.
G. Peramaiyan, P. Pandi, B.M. Sornamurthy, G. Bhagavannarayana and R. Mohan Kumar, Spectrochim. Acta A, 95, 310 (2012); doi:10.1016/j.saa.2012.03.082.
P. Pandi, G. Peramaiyan, S. Sudhahar, G. Chakkaravarthi, R. Mohan Kumar, G. Bhagavannarayana and R. Jayavel, Spectrochim. Acta A, 98, 7 (2012); doi:10.1016/j.saa.2012.08.018.
S. Gowri, T. Uma Devi, D. Sajan, A. Chandramohan and N. Lawrence, Optik, 124, 2393 (2013); doi:10.1016/j.ijleo.2012.07.049.
K. Boopathi, P. Rajesh and P. Ramasamy, Mater. Res. Bull., 47, 2299 (2012); doi:10.1016/j.materresbull.2012.05.041.
G. Anandha Babu, G. Bhagavannarayana and P. Ramasamy, J. Cryst. Growth, 310, 2820 (2008); doi:10.1016/j.jcrysgro.2008.02.008.
J.M. Linet and S.J. Das, Physica B, 405, 3955 (2010); doi:10.1016/j.physb.2010.06.037.
K. Sangwal, M. Hordyjewicz and B. Surowska, J. Optoelectron. Adv. Mater., 4, 875 (2002).
K. Sangwal, A. Kothari and S.K. Arora, Surf. Sci., 600, 1475 (2006); doi:10.1016/j.susc.2006.01.044.
E. Meyer and Z. Ver, Dtsch. Ing., 52, 645 (1908).
E.M. Onitsch, Mikroskopie, 95, 12 (1950).
S.K. Kurtz and T.T. Perry, J. Appl. Phys., 39, 3798 (1968); doi:10.1063/1.1656857.