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Some Novel Phases in Binary System of PbO-Sb2O3
Corresponding Author(s) : H. Guzin Aslan
Asian Journal of Chemistry,
Vol. 26 No. 18 (2014): Vol 26 Issue 18
Abstract
In this study, we have investigated the PbO-Sb2O3 binary system. PbO and Sb2O3 are reacted using different stoichiometric ratios at 650 °C in an air using a gold and a platinum reaction vessel by heating for 24 h. PbSb2O6, Pb9Sb8O21, Pb4Sb2O8, Pb9Sb8O17, Pb6Sb2O11, Pb5Sb2O9, Pb7Sb2O11, Pb8Sb2O12, Pb9Sb2O13, phases are synthesized and these phases 0.5, 0.692, 0.8, 0.818, 0.857, 0.87, 0.875, 0.88, 0.9 mole fractions, respectively. Reaction products are characterized by the X-ray powder diffraction and by DTA/TG analysis methods.
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References
R.J. Hill, J. Solid State Chem., 71, 12 (1987); doi:10.1016/0022-4596(87)90136-8.
S.S. Lopatin, E.S. Medvedev and I.P. Raevskii, Russ. J. Inorg. Chem., 30, 867 (1985).
A.A. Bush and Y.N. Venetsev, Russ. J. Inorg. Chem., 31, 769 (1986).
F. Raymande, Spectroscopie Moleculaire, (Acad. Sci. Press, Paris) p. 274 (1972).
A. Magneli, Arkiu för Khimii, Minerolojioch Geoloji Band, 15B No:3.
A.V. Astafev, A.N. Bush, S.Y. Stefanovich and Y.N. Venetsev, Neorgan. Meter. Izv. Akad. Nauk SSSR [Khim], 645 (1984).
G. Burchard and W Z. Rudorrf, Z. Anorgan. Allgem. Chem., 447, 149 (1978); doi:10.1002/zaac.19784470116.
V.G. Kuznetsov and R.A. Koz'min, Zh. Neorg. Khim, 10, 2361 (1958).
D.C. Gelach, R.W. Hennig and D.A. Pawlek, Metallography, 2215 (1968).
J. Hu, T.W. Odom and C.M. Lieber, Acc. Chem. Res., 32, 435 (1999); doi:10.1021/ar9700365.
Y.N. Xia, P.D. Yang, Y.G. Sun, Y.Y. Wu, B. Mayers, B. Gates, Y.D. Yin, F. Kim and H.Q. Yan, Adv. Mater., 15, 353 (2003); doi:10.1002/adma.200390087.
A.E. Whitten, B. Dittrich, M.A. Spackman, P. Turner and T.C. Brown, Dalton Trans., 23 (2004); doi:10.1039/b312550e.
R.D. Bernett, A. Mitchell and T.C. Brown, J. Mater. Sci., 39, 1075 (2004); doi:10.1023/B:JMSC.0000012947.67817.17.
J. Spengler, F. Anderle, E. Bosch, R.K. Grasselli, B. Pillep, P. Behrens, O.B. Lapina, A.A. Shubin, H.-J. Eberle and H. Knözinger, J. Phys. Chem. B, 105, 10772 (2001); doi:10.1021/jp012228u.
K. Terashima, T. Hashimoto, T. Uchino, S.-H. Kim and T. Yoko, Ceram. Soc. Japan, 104, 1008 (1996); doi:10.2109/jcersj.104.1008.
S.A. Nedil'ko and A.M. Sych, Neorgan. Mater., 12, 2014 (1976).
A. Tairi, J.C. Champarnaud-Mesjard, D. Mercurio and B. Frit, Rev. Chim. Miner., 22, 699 (1985).