A New Two-Dimensional Silver Coordination Polymer Constructed by 1,3-Bis(4-pyridyl)propane and 2,6-Dichlorophenylacetic Acid: Synthesis, Structure, Luminescence and Thermal Stable Properties

Xiao-Min Hao; Gang Chen; Chang-Sheng Gu

doi:10.14233/ajchem.2014.18208

Issue

Vol. 26 No. 17 (2014): Vol 26 Issue 17

Issue Published : August 27, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

A New Two-Dimensional Silver Coordination Polymer Constructed by 1,3-Bis(4-pyridyl)propane and 2,6-Dichlorophenylacetic Acid: Synthesis, Structure, Luminescence and Thermal Stable Properties

https://doi.org/10.14233/ajchem.2014.18208

Xiao-Min Hao

Department of Chemistry, Harbin Institute of Technology, Harbin, P.R. China ; Department of Applied Chemistry, Guangdong Ocean University, Zhanjiang, P.R. China

Gang Chen

Department of Chemistry, Harbin Institute of Technology, Harbin, P.R. China

Chang-Sheng Gu

Department of Applied Chemistry, Guangdong Ocean University, Zhanjiang, P.R. China

Corresponding Author(s) : Gang Chen

gchen@hit.edu.cn

Asian Journal of Chemistry, Vol. 26 No. 17 (2014): Vol 26 Issue 17
Article Published : August 12, 2014

Abstract

A novel complex 1 of {[Ag(bpp)(dcpa)] H₂O}_n [Hdcpa: 2,6-dichlorophenylacetic acid; bpp: 1,3-bis(4-pyridyl)propane] was synthesized and characterized by elemental analysis, IR, TGA, X-ray single crystal diffraction. The carboxylate oxygens of the Hdcpa ligands connect one Ag(I) ion in bidentate chelating mode to form mononuclear silver building blocks, which are into a 1D infinite chain through trans-bpp ligands. A two-dimensional network consist of adjacent Ag-bpp chain through Ag-Ag interaction. Furthermore, the luminescent property of complex 1 was investigated at room temperature. CCDC: 996495.

Keywords

Ag(I) coordinated polymer Crystal structure Luminesce

Hao, X.-M., Chen, G., & Gu, C.-S. (2014). A New Two-Dimensional Silver Coordination Polymer Constructed by 1,3-Bis(4-pyridyl)propane and 2,6-Dichlorophenylacetic Acid: Synthesis, Structure, Luminescence and Thermal Stable Properties. Asian Journal of Chemistry, 26(17), 5805–5808. https://doi.org/10.14233/ajchem.2014.18208

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J.J. Perry IV, J.A. Perman and M.J. Zaworotko, Chem. Soc. Rev., 38, 1400 (2009); doi:10.1039/b807086p.

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L.Q. Fan, J.H. Wu, J.M. Lin and Y.F. Huang, Chin. J. Struct. Chem., 24, 1489 (2010).

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M.V. Marinho, M.I. Yoshida, K.J. Guedes, K. Krambrock, A.J. Bortoluzzi, M. Hörner, F.C. Machado and W.M. Teles, Inorg. Chem., 43, 1539 (2004); doi:10.1021/ic035251y.

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Q.Y. Liu and L. Xu, Cryst. Eng. Commun., 7, 87 (2005); doi:10.1039/b418341j.

S. Kitagawa, R. Kitaura and S. Noro, Angew. Chem. Int. Ed., 43, 2334 (2004); doi:10.1002/anie.200300610.

Issue

Vol. 26 No. 17 (2014): Vol 26 Issue 17

A New Two-Dimensional Silver Coordination Polymer Constructed by 1,3-Bis(4-pyridyl)propane and 2,6-Dichlorophenylacetic Acid: Synthesis, Structure, Luminescence and Thermal Stable Properties

Corresponding Author(s) : Gang Chen

Abstract

Keywords

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