Copyright (c) 2014 AJC
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Synthesis and Characterization of Non-Toxic Thermal Stabilizers of PVC Based on Layered Double Hydroxides
Corresponding Author(s) : Hyung Wook Park
Asian Journal of Chemistry,
Vol. 26 No. 17 (2014): Vol 26 Issue 17
Abstract
Hydrotalcite-like compounds are expressed by the general formula [M(2+)1xM(3+)x(OH)2]x+1An-x/ n·mH2O, where M(2+) and M(3+) are divalent and trivalent cations, respectively. Mg1-xAlx(OH)2COn-x/ n·mH2O structures, non-toxic thermal stabilizers of poly(vinyl chloride), were manufactured by various coprecipitation methods to optimize the manufacturing process of non-toxic thermal stabilizers of poly(vinyl chloride). These hydrotalcite-like compounds were characterized by field-emission-scanning electron microscopy, X-ray diffraction, thermal analysis and transmittance spectra. Samples were fabricated using different steps and a base reactant produced the most stable sample. The cell parameter c is related to the thickness of the brucite-like layer and the interlayer distance was 23.21 Å.
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- E.J. Park, S.D. Park, I.C. Bang, Y.-B. Park and H.W. Park, Mater.Lett.,81, 193 (2012); doi:10.1016/j.matlet.2012.04.101.
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References
Y. Kuang, L. Zhao, S. Zhang, F. Zhang, M. Dong and S. Xu, Materials, 3, 5220 (2010); doi:10.3390/ma3125220.
K.-H. Goh, T.-T. Lim and Z. Dong, Water Res., 42, 1343 (2008); doi:10.1016/j.watres.2007.10.043.
T. Kameda, T. Yoshioka, F. Yabuuchi, M. Uchida and A. Okuwaki, J. Mater. Sci., 42, 2194 (2007); doi:10.1007/s10853-007-1543-8.
R. Allmann and B. Section, Struct. Crystallogr. Crystal Chem., 24, 972 (1968); doi:10.1107/S0567740868003511.
E.J. Park, S.D. Park, I.C. Bang, Y.-B. Park and H.W. Park, Mater.Lett.,81, 193 (2012); doi:10.1016/j.matlet.2012.04.101.
H. Wang, H. Yi, P. Ning, X. Tang, L. Yu, D. He and S. Zhao, Chem. Eng. J., 166, 99 (2011); doi:10.1016/j.cej.2010.10.025.
H.-Y. Zeng, X. Deng, Y.-J. Wang and K.-B. Liao, AIChE J., 55, 1229 (2009); doi:10.1002/aic.11722.
J. Chandradass and M. Balasubramanian, Mater. Manuf. Process., 23, 158 (2008); doi:10.1080/10426910701774635.
P. Benito, I. Guinea, F.M. Labajos and V. Rives, J. Solid State Chem., 181, 987 (2008); doi:10.1016/j.jssc.2008.02.003.
G. Fetter, F. Hernández, A.M. Maubert, V.H. Lara and P. Bosch, J. Porous Mater., 4, 27 (1997); doi:10.1023/A:1009619005529.