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Vol. 30 No. 9 (2018): Vol 30 Issue 9

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Spinel Organic-Framework Wrapped Polymer Electrodes for Super Capacitors

https://doi.org/10.14233/ajchem.2018.21500
Gunjana Chaudhary
Thin Film Laboratory, Department of Materials Science & Nanotechnology, Deenbandhu Chhotu Ram University of Science & Technology, Murthal-131 039, India
Ashok K. Sharma
Thin Film Laboratory, Department of Materials Science & Nanotechnology, Deenbandhu Chhotu Ram University of Science & Technology, Murthal-131 039, India
Indu Kaushal
Thin Film Laboratory, Department of Materials Science & Nanotechnology, Deenbandhu Chhotu Ram University of Science & Technology, Murthal-131 039, India
Priya Saharan
Thin Film Laboratory, Department of Materials Science & Nanotechnology, Deenbandhu Chhotu Ram University of Science & Technology, Murthal-131 039, India

Corresponding Author(s) : Ashok K. Sharma

aksharma210@gmail.com

Asian Journal of Chemistry, Vol. 30 No. 9 (2018): Vol 30 Issue 9

Abstract

This work presents the blueprint for design and fabrication of novel electrode material by facile thin layer deposition of poly(aniline) (PANI) on highly conductive Mn-doped cobalt ferrite grown on the surface of carbon nanofibers to achieve high specific capacitance for application in energy storage and conversion devices. The crystalline growth of metal oxide over carbon nanofibers uniquely served as a highly conductive template with redox active sites. Physical and chemical aspects of fabricated composites were characterized by FTIR spectroscopy, UV spectroscopy, XRD, FESEM, EDS, HRTEM technique and selected area electron diffraction characterization studies. The electrochemical proficiency of synthesized electrode materials was tested by application of three-electrode system for cyclic voltammetry, galvanostatic charge-discharge and electrochemical impedance spectroscopy. The uppermost specific capacitance of 1866 F g-1 at a scanning rate of 5 mV s-1 and 1450 F g-1 at a current density of 0.75 A g-1 were accomplished in aqueous solution of 1 M H2SO4 with good cycle stability.

Keywords

Polyaniline Voltammetry Composites Charge-discharge Impedance
Chaudhary, G., Sharma, A. K., Kaushal, I., & Saharan, P. (2018). Spinel Organic-Framework Wrapped Polymer Electrodes for Super Capacitors. Asian Journal of Chemistry, 30(9), 2151–2158. https://doi.org/10.14233/ajchem.2018.21500
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