Synthesis and Characterization of Iron(III) and Uranyl(II) Complexes of Some Salicyloylhydrazones

B. Senthil Sivakumar; A. Manimekalai

Issue

Vol. 21 No. 7 (2009): Vol 21 Issue 7

Issue Published : May 5, 2009

Synthesis and Characterization of Iron(III) and Uranyl(II) Complexes of Some Salicyloylhydrazones

B. Senthil Sivakumar

Department of Chemistry, Annamalai University, Annamalai Nagar-608 002, India ; Present Address: Department of Applied Chemistry, Sri Venkateswara College of Engineering, Pennalur, Sriperumbudur-602 105, India

A. Manimekalai

Department of Chemistry, Annamalai University, Annamalai Nagar-608 002, India

Corresponding Author(s) : B. Senthil Sivakumar

bsenthil@svce.ac.in

Asian Journal of Chemistry, Vol. 21 No. 7 (2009): Vol 21 Issue 7
Article Published : March 30, 2010

Abstract

Iron(III) and uranyl(II) complexes of salicyloyl hydrazones derived from 2,6-diphenylpiperidin-4-one (DPSH) and 3-methyl-2,6-diphenylpiperidin- 4-one (MDPSH) were prepared and characterized by elemental analysis, conductance, magnetic, cyclic voltammetric and spectral studies. UO₂(II) complexes derived from DPSH and MDPSH have 1:1 and 2:1 metal to ligand stoichiometries, respectively. The metal ligand ratio was found to be 1:3 in Fe(III)-DPSH complex and 1:2 in Fe(III)-MDPSH complex. Based on the relevant data probable structure of the complexes were proposed.

Keywords

Iron(III) Uranyl(II) Salicyloylhydrazone complexes

Senthil Sivakumar, B., & Manimekalai, A. (2010). Synthesis and Characterization of Iron(III) and Uranyl(II) Complexes of Some Salicyloylhydrazones. Asian Journal of Chemistry, 21(7), 5228–5234. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/18297

Issue

Vol. 21 No. 7 (2009): Vol 21 Issue 7

Synthesis and Characterization of Iron(III) and Uranyl(II) Complexes of Some Salicyloylhydrazones

Corresponding Author(s) : B. Senthil Sivakumar

Abstract

Keywords

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