Issue

Vol. 33 No. 5 (2021): Vol 33 Issue 5, 2021

Copyright (c) 2021 AJC

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Thermo-Physical Properties of Heterocyclic Compounds with Aliphatic Alcohols at T = 303.15, 308.15 and 313.15 K

https://doi.org/10.14233/ajchem.2021.22935
D. Ubagaramary
Department of Chemistry, M.V.J. College of Engineering, Bengaluru-560067, India
I.V. Muthu Vijayan Enoch
Centre for Nanoscience and Genomics, Karunya Institute of Technology & Sciences, Coimbatore-641114, India
Ajay Guttedar
Department of Chemical Engineering, M.V.J. College of Engineering, Bengaluru-560067, India
R. Lalith Kumar
Department of Chemical Engineering, M.V.J. College of Engineering, Bengaluru-560067, India
Neetun Sulebhavi
Department of Chemical Engineering, M.V.J. College of Engineering, Bengaluru-560067, India

Corresponding Author(s) : D. Ubagaramary

ubagaramary.chemistry@gmail.com

Asian Journal of Chemistry, Vol. 33 No. 5 (2021): Vol 33 Issue 5, 2021

Abstract

The densities (ρ), speeds of sound (u), and viscosities (η) have been measured for ternary liquid mixtures of tetrahydrofuran in cyclohexanone with 1-hexanol and 1-octanol at 303.15-313.15 K over the entire range of mole fractions and at atmospheric pressure 0.1 MPa. These experimental data have been used to estimate the thermophysical properties of heterocyclic compounds with aliphatic alcohols at T = 303.15, 308.15 and 313.15 K. Preliminary data was used to assess the excess free volume, internal pressure and free energy of Gibbs, which were discussed in light of the molecular interaction surviving in the mixtures. Analysis of each of the two contributions, namely interaction, free volume VE showed that the contributions are positive for all systems. The variations of these parameters with the composition and the temperature were discussed with regard to the intermolecular interactions prevailing in these mixtures. These values also indicate the formation of a hydrogen bonding (C=O......OH) between the hydrogen atom of aliphatic alcohol of 1-hexanol/1-octanol and oxygen atom of heterocyclic compounds tetrahydrofuran in cyclohexanone in the ternary liquid mixtures.

Keywords

Density Speed of sound Viscosity Tetrahydrofuran Cyclohexanone 1-Hexanol 1-Octanol.
Ubagaramary, D., Muthu Vijayan Enoch, I., Guttedar, A., Lalith Kumar, R., & Sulebhavi, N. (2021). Thermo-Physical Properties of Heterocyclic Compounds with Aliphatic Alcohols at T = 303.15, 308.15 and 313.15 K. Asian Journal of Chemistry, 33(5), 1169–1175. https://doi.org/10.14233/ajchem.2021.22935
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. V.K. Sharma, S. Solanki and S. Bhagour, J. Chem. Eng. Data, 59, 1852 (2014); https://doi.org/10.1021/je401098b
  2. Neeti, S.K. Jangra, J.S. Yadav, Dimple and V.K. Sharma, J. Mol. Liq., 163, 36 (2011); https://doi.org/10.1016/j.molliq.2011.07.008
  3. V. Pandiyan, S.L. Oswal, N.I. Malek and P. Vasantharani, Thermochim. Acta, 524, 140 (2011); https://doi.org/10.1016/j.tca.2011.07.005
  4. S. Kumar and P. Jeevanandham, J. Mol. Liq., 174, 34 (2012); https://doi.org/10.1016/j.molliq.2012.07.025
  5. O. Redlich and A.T. Kister, J. Ind. Eng. Chem., 40, 345 (1948); https://doi.org/10.1021/ie50458a036
  6. I. Prigogine, The Molecular Theory of Solution, North Holland Publ. Co., Amsterdam (1957).
  7. D.J. Cram and G.S. Hammond, Organic Chemistry, McGraw Hill Book Co., NewYork, Eds. 2 (1964).
  8. A. Heintz, B. Schmittecker, D. Wagner and R.N. Lichtenthaler, J. Chem. Eng. Data, 31, 487 (1986); https://doi.org/10.1021/je00046a030
  9. A. Valtz, M. Teodorescu, I. Wichterle and D. Richon, Fluid Phase Equilib., 215, 129 (2004); https://doi.org/10.1016/S0378-3812(03)00364-9
  10. S. Villa, N. Riesco, F.J. Carmona, I. Garcia de la Fuente, J.A. Gonzalez and J.C. Cobos, Thermochim. Acta, 362, 169 (2000); https://doi.org/10.1016/S0040-6031(00)00575-X
  11. K. Noweck and W. Grafahrend, Fatty Alcohols: Ullmann's Encyclopedia of Industrial Chemistry, Weinheim: Wiley-VCH (2006).
  12. Z. Wang, Ziegler Alcohol Synthesis (Ziegler Higher Alcohol Synthesis, Alfol Process, Ziegler-Alfol Process, Ziegler-Alfol Synthesis), In: Comprehensive Organic Name Reactions and Reagents, John Wiley & Sons, Inc. (2010).
  13. W. Kauzmann and H. Eyring, J. Am. Chem. Soc., 62, 3113 (1940); https://doi.org/10.1021/ja01868a059
  14. H. Vogel and A. Weiss, Ber. Bunsenges. Phys. Chem., 86, 193 (1982); https://doi.org/10.1002/bbpc.19820860304
  15. A. Mariano and M. Postigo, Fluid Phase Equilib., 239, 146 (2006); https://doi.org/10.1016/j.fluid.2005.11.018
  16. P. Brocos, A. Pineiro, R. Bravo and A. Amigo, Phys. Chem. Chem. Phys., 5, 550 (2003); https://doi.org/10.1039/b208765k
  17. A. Pineiro, P. Brocos, A. Amigo, M. Pintos and R. Bravo, Chem. Phys. Liq., 38, 251 (2000); https://doi.org/10.1080/00319100008030275
  18. T.M. Reed Iii. and T.E. Taylor, J. Phys. Chem., 63, 58 (1959); https://doi.org/10.1021/j150571a016
  19. B. Sathyanarayana, B. Ranjithkumar, T.S. Jyostna and N. Satyanarayana, J. Chem. Thermodyn., 39, 16 (2007); https://doi.org/10.1016/j.jct.2006.06.009
  20. K. Liu and E. Kiran, Ind. Eng. Chem. Res., 46, 5453 (2007); https://doi.org/10.1021/ie070274w
  21. H. Wang, W. Liu and J. Huang, J. Chem. Thermodyn., 36, 743 (2004); https://doi.org/10.1016/j.jct.2004.04.004
  22. S. Ottani, D. Vitalini, F. Comelli and C. Castellari, J. Chem. Eng. Data, 47, 1197 (2002); https://doi.org/10.1021/je020030c
  23. H. Wang, W. Liu and J. Huang, J. Chem. Thermodyn., 36, 743 (2004); https://doi.org/10.1016/j.jct.2004.04.004
  24. F. Kermanpour and H.Z. Niakan, J. Chem. Thermodyn., 54, 10 (2012); https://doi.org/10.1016/j.jct.2012.02.036
  25. R.L. Gardas and S. Oswal, Thermochim. Acta, 479, 17 (2008); https://doi.org/10.1016/j.tca.2008.09.006
  26. R. Balaji, M.G. Sankar, M.C. Sekhar and M.C. Shekar, Karbala Int. J. Modern Sci., 2, 10 (2016); https://doi.org/10.1016/j.kijoms.2015.12.001
  27. D. Rahul, M.G. Sankar, T.S. Krishna and D. Ramachandran, Karbala Int. J. Modern Sci., 2, 78 (2016); https://doi.org/10.1016/j.kijoms.2016.02.001
  28. J.A. Barker and F. Smith, J. Chem. Phys., 22, 375 (1954); https://doi.org/10.1063/1.1740077
  29. G. Tomas, P. Garcia-Gimenez, S.T. Blanco, L. Velasco and S. Otin, J. Chem. Eng. Data, 53, 128 (2008); https://doi.org/10.1021/je700414c
  30. Neeti, S.K. Jangra, J.S. Yadav, Dimple and V.K. Sharma, Thermochim. Acta, 524, 92 (2011); https://doi.org/10.1016/j.tca.2011.06.020
  31. S. Akhtar, A.N.M. Omar Faruk and M.A. Saleh, Phys. Chem. Liq., 39, 383 (2001); https://doi.org/10.1080/00319100108031670
  32. P. Jeevanandham, S. Kumar and P. Periyasamy, J. Mol. Liq., 188, 203 (2013); https://doi.org/10.1016/j.molliq.2013.09.035
  33. J.A. Riddick and W.B. Bunger, Techniques of Chemistry, Wiley Intersxiences: New York (1986).
  34. A. Garcia-Abuin, D. Gomez-Diaz, M.D. La Rubia and J.M. Navaza, J. Chem. Eng. Data, 56, 646 (2011); https://doi.org/10.1021/je100967k
  35. M.I. Aralaguppi, C.V. Jadar and T.M. Aminabhavi, J. Chem. Eng. Data, 44, 441 (1999); https://doi.org/10.1021/je980218p
  36. B. Hawrylak, S.E. Burke and R. Palepu, J. Solution Chem., 29, 575 (2000); https://doi.org/10.1023/A:1005198230692
  37. F. Pouryousefi and R.O. Idem, Ind. Eng. Chem. Res., 47, 1268 (2008); https://doi.org/10.1021/ie0709786
  38. J. Han, J. Jin, D.A. Eimer and M.C. Melaaen, J. Chem. Eng. Data, 57, 1095 (2012); https://doi.org/10.1021/je2010038
  39. E. Vertesi, J. Chem. Eng. Data, 25, 387 (1980); https://doi.org/10.1021/je60087a005
  40. M. Chandra Sekhar, M.G. Sankar and A. Venkatesulu, J. Mol. Liq., 209, 428 (2015); https://doi.org/10.1016/j.molliq.2015.04.034
  41. R. Balaji, M. Gowri Sankar, A. Venkatesulu and M. Chandra Shekar, J. Mol. Liq., 230, 36 (2017); https://doi.org/10.1016/j.molliq.2016.12.109
  42. G.C. Benson and O. Kiyohara, J. Chem. Thermodyn., 11, 1061 (1979); https://doi.org/10.1016/0021-9614(79)90136-8
Read More
Author biographies is not available.
Download
PDF
Statistic
Read Counter : 0 Download : 0