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Vol. 33 No. 5 (2021): Vol 33 Issue 5, 2021

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Manganese(IV) Complexes Derived from Polyfunctional Dihydrazone: Structural, Electrochemical and Antimicrobial Studies

https://doi.org/10.14233/ajchem.2021.23162
P. Sarma
Department of Applied Sciences, Gauhati University, Guwahati-781014, India
P. Mahanta
Department of Applied Sciences, Gauhati University, Guwahati-781014, India
D. Basumatary
Department of Applied Sciences, Gauhati University, Guwahati-781014, India
C. Medhi
Department of Chemistry, Gauhati University, Guwahati-781014, India

Corresponding Author(s) : D. Basumatary

debbasumatary@gmail.com; debbasumatary@gauhati.ac.in

Asian Journal of Chemistry, Vol. 33 No. 5 (2021): Vol 33 Issue 5, 2021

Abstract

Manganese(IV) complexes viz. [MnIV(nagh)(A)2]·2H2O and [MnIV(nagh)(NN)] have been synthesized from ligand bis(2-hydroxy-1-naphthaldehyde)glutaryldihydrazone (naghH4) and auxiliary ligands, A = H2O (1)/pyridine (2)/2-picoline (3)/3-picoline (4)/4-picoline (5) or NN = 2,2′-bipyridine (6)/1,10-phenanthroline (7). The elemental analysis, mass spectral and thermal studies supported the composition of all the manganese(IV) complexes. Structural aspects were determined from magnetic susceptibility, molar conductivity and spectral studies i.e. electronic, electron spin resonance and infrared. Their non-electrolytic nature were determined from molar conductances. Results from studies of magnetic moment, electronic and ESR suggested Mn(IV) ion in six-coordinate octahedral stereochemistry. The ligand coordinated to the metal in enolic form as a tetradentate in an anti-cis configuration as was correlated from IR data. Redox activities and antimicrobial potential against few Gram-positive and Gram-negative bacteria have been investigated for the dihydrazone and some manganese(IV) complexes.

Keywords

Manganese(IV) bis(2-Hydroxy-1-napthaldehyde)glutaryldihydrazone Antimicrobial activity
Sarma, P., Mahanta, P., Basumatary, D., & Medhi, C. (2021). Manganese(IV) Complexes Derived from Polyfunctional Dihydrazone: Structural, Electrochemical and Antimicrobial Studies. Asian Journal of Chemistry, 33(5), 1144–1152. https://doi.org/10.14233/ajchem.2021.23162
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References
  1. A. Kajal, S. Bala, S. Kamboj, N. Sharma and V. Saini, J. Catal., 2013, 893512 (2013); https://doi.org/10.1155/2013/893512
  2. S. Adhikari, R.A. Lal, A. Debnath and D. Dey, J. Chem. Pharm. Res., 9, 236 (2017).
  3. M.A.-N. Mohammed, Periodica Polytechnica, 56, 83 (2012); https://doi.org/10.3311/pp.ch.2012-2.06
  4. M.K. Singh, N.K. Kar and R.A. Lal, J. Coord. Chem., 61, 3158 (2008); https://doi.org/10.1080/00958970802010583
  5. M.K. Singh, N.K. Kar and R.A. Lal, J. Coord. Chem., 62, 1677 (2009); https://doi.org/10.1080/00958970802676649
  6. M.S. Refat, S.A. El-Korashy, D.N. Kumar and S.A. Ahmed, Spectrochim. Acta A Mol. Biomol. Spectrosc., 70, 898 (2008); https://doi.org/10.1016/j.saa.2007.10.005
  7. A.H. Ahmed, A.M. Hassan, H.A. Gumaa, B.H. Mohamed and A.M. Eraky, J. Chil. Chem. Soc., 63, 4180 (2018); https://doi.org/10.4067/S0717-97072018000404180
  8. R.A. Lal, A. Kumar and M.L. Pal, J. Indian Chem. Soc., 76, 70 (1999).
  9. X.-H. Lu, Q.-H. Xia, H.-J. Zhan, H.-X. Yuan, C.-P. Ye, K.-X. Su and G. Xu, J. Mol. Catal. Chem., 250, 62 (2006); https://doi.org/10.1016/j.molcata.2006.01.055
  10. R.O. Costa, S.S. Ferreira, C.A. Pereira, J.R. Harmer, C.J. Noble, G.Schenk, R.W.A Franco, J.A.L.C Resende, P. Comba, A.E. Roberts, C.Fernandes and A. Horn Jr., Front. Chem., 6, 491 (2018); https://doi.org/10.3389/fchem.2018.00491
  11. S.-B. Yu, S.J. Lippard, I. Shweky and A. Bino, Inorg. Chem., 31, 3502 (1992); https://doi.org/10.1021/ic00043a004
  12. M. Zlatar, M. Gruden, O.Y. Vassilyeva, E.A. Buvaylo, A.N. Ponomarev, S.A. Zvyagin, J.J. Wosnitza, J. Krzystek, P. Garcia-Fernandez and C. Duboc, Inorg. Chem., 55, 1192 (2016); https://doi.org/10.1021/acs.inorgchem.5b02368
  13. R.A. Lal, D. Basumatary, O.B. Chanu, A. Lemtur, M. Asthana, A. Kumar and A.K. De, J. Coord. Chem., 64, 300 (2011); https://doi.org/10.1080/00958972.2010.542238
  14. N.K. Chaudhary and P. Mishra, Bioinorg. Chem. Appl., 2017, 6927675 (2017); https://doi.org/10.1155/2017/6927675
  15. A.I. Vogel, A Textbook of Quantitative Inorganic Analysis including Elementary Instrumentation Analysis, Longmans: London, Eds. 4 (1978).
  16. W.J. Geary, Coord. Chem. Rev., 7, 81 (1971); https://doi.org/10.1016/S0010-8545(00)80009-0
  17. D. Sadhukhan, A. Ray, G. Pilet, G.M. Rosair, E. Garribba, A. Nonat, L.J. Charbonnière and S. Mitra, Bull. Chem. Soc. Jpn., 84, 764 (2011); https://doi.org/10.1246/bcsj.20110004
  18. H. Temel and M. Sekerci, Synth. React. Inorg. Met.-Org. Chem., 31, 849 (2001); https://doi.org/10.1081/SIM-100104855
  19. N. Nishat, T. Ahamad, S. Ahmad and S. Parveen, J. Coord. Chem., 64, 2639 (2011); https://doi.org/10.1080/00958972.2011.570754
  20. L. Sacconi, A. Sabatini and P. Gans, Inorg. Chem., 3, 1772 (1964); https://doi.org/10.1021/ic50022a026
  21. C.W. Frank and L.B. Rogers, Inorg. Chem., 5, 615 (1966); https://doi.org/10.1021/ic50038a026
  22. G. Sartori, C. Furlani and A. Damiani, J. Inorg. Nucl. Chem., 8, 119 (1958); https://doi.org/10.1016/0022-1902(58)80172-4
  23. A.M. Hassan, A.H. Ahmed, H.A. Gumaa, B.H. Mohamed and A.M. Eraky, J. Chem. Pharm. Res., 7, 91 (2015).
  24. M. Tyagi, S. Chandra and P. Tyagi, Spectrochim. Acta A Mol. Biomol. Spectrosc., 117, 1 (2014); https://doi.org/10.1016/j.saa.2013.07.074
  25. B. Murukan and K. Mohanan, Transition Met. Chem., 31, 441 (2006); https://doi.org/10.1007/s11243-006-0011-7
  26. R. Mukhopadhyay, S. Bhattacharjee, C.K. Pal, S. Karmakar and R. Bhattacharyya, J. Chem. Soc., Dalton Trans., 2267 (1997); https://doi.org/10.1039/a700855d
  27. J.R. Hartman, B.M. Foxman and S.R. Cooper, Inorg. Chem., 23, 1381 (1984); https://doi.org/10.1021/ic00178a017
  28. H. Okawa, M. Nakamura and S. Kida, Bull. Chem. Soc. Jpn., 55, 466 (1982); https://doi.org/10.1246/bcsj.55.466
  29. C.P. Pradeep, P.S. Zacharias and S.K. Das, J. Chem. Sci., 118, 311 (2006); https://doi.org/10.1007/BF02708524
  30. P.J. Chirik and K. Wieghardt, Science, 327, 794 (2010); https://doi.org/10.1126/science.1183281
  31. M.D. Ward and J.A. McCleverty, J. Chem. Soc., Dalton Trans., 3, 275 (2002); https://doi.org/10.1039/b110131p
  32. R.S. Joseyphus and M.S. Nair, J. Coord. Chem., 62, 319 (2009); https://doi.org/10.1080/00958970802236048
  33. S.B. Bakare, Pol. J. Chem. Technol., 21, 26 (2019); https://doi.org/10.2478/pjct-2019-0026
  34. S.M. Abdallah, M.A. Zayed and G.G. Mohamed, Arabian. J. Chem., 3, 103 (2010); https://doi.org/10.1016/j.arabjc.2010.02.006
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