Copyright (c) 2018 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Mitigation of Acid Corrosion on Carbon Steel by Naturally Occurring Gum Exudate
Corresponding Author(s) : Malarvizhi Manickam
Asian Journal of Chemistry,
Vol. 30 No. 9 (2018): Vol 30 Issue 9
Abstract
Gum exudates of Azadirachta indica (GAI) was tested as corrosion inhibitor for carbon steel in 1 N H2SO4 by means of different techniques viz., gravimetric experiments, electrochemical polarization and impedance studies, IR and SEM techniques. Nature of adsorption is reported and it follows Langmuir isotherm. Polarization method indicated mixed mode behaviour of the inhibitor. AC impedance studies supported mitigation effects of gum exudates of Azadirachta indica. IR and SEM studies reveal the protection of carbon steel through adsorption.
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- E.E. Ebenso, N.O. Eddy and A.O. Odiongenyi, Afr. J. Pure Appl. Chem., 2, 107 (2008).
- A. Diab and S.M. Abd El-Haleem, Orient. J. Chem., 33, 1921 (2017); https://doi.org/10.13005/ojc/330438.
- C.S.S.R. Kumar, M. Srinivas and S. Yakkundi, Phytochemistry, 43, 451 (1996); https://doi.org/10.1016/0031-9422(96)00226-9.
- A. Ahamad and M.A. Quraishi, Corros. Sci., 52, 651 (2010); https://doi.org/10.1016/j.corsci.2009.10.012.
- K. Mallaiya, R. Subramaniam, S.S. Srikandan, S. Gowri, N. Rajasekaran and A. Selvaraj, Electrochim. Acta, 56, 3857 (2011); https://doi.org/10.1016/j.electacta.2011.02.036.
- D. Kesavan, M. Gopiraman and N. Sulochana, Chem. Sci. Rev. Lett., 1, 1 (2012).
- P.C. Okafor and E.E. Ebenso, Pigm. Resin Technol., 36, 134 (2007); https://doi.org/10.1108/03699420710748992.
- P.C. Okafor, M.E. Ikpi, I.E. Uwah, E.E. Ebenso, U.J. Ekpe and S.A. Umoren, Corros. Sci., 50, 2310 (2008); https://doi.org/10.1016/j.corsci.2008.05.009.
- M. Kliskic, J. Radosevic, S. Gudic and V. Katalinic, J. Appl. Electrochem., 30, 823 (2000); https://doi.org/10.1023/A:1004041530105.
- E.E. Ebenso, U.J. Ibok, U.J. Ekpe, S. Umoren, E. Jackson, O.K. Abiola, N.C. Oforka and S. Martinez, Trans. of SAEST, 39, 117 (2004).
- G. Gunasekaran and L.R. Chauhan, Electrochim. Acta, 49, 4387 (2004); https://doi.org/10.1016/j.electacta.2004.04.030.
- E.E. Oguzie, A.I. Onuchukwu, P.C. Okafor and E.E. Ebenso, Pigm. Resin Technol., 35, 63 (2006); https://doi.org/10.1108/03699420610652340.
- A.M. Abdel-Gaber, B.A. Abd-El-Nabey, I.M. Sidahmed, A.M. ElZayady and M. Saadawy, Corros. Sci., 48, 2765 (2006); https://doi.org/10.1016/j.corsci.2005.09.017.
- A. Peter, I.B. Obot and S.K. Sharma, Int. J. Ind. Chem., 6, 153 (2015); https://doi.org/10.1007/s40090-015-0040-1.
- S.A. Umoren and U. M. Eduok, J. Carbohydr. Polym., 140, 314 (2015); https://doi.org/10.1016/j.carbpol.2015.12.038.
- M. Mobin and M. Rizvi, Carbohydr. Polym., 136, 384 (2016); https://doi.org/10.1016/j.carbpol.2015.09.027.
- S.A. Umoren, Cellulose, 15, 751 (2008); https://doi.org/10.1007/s10570-008-9226-4.
- N.O. Eddy, P. Ameh, C.E. Gimba and E.E. Ebenso, Int. J. Electrochem. Sci., 6, 815 (2011).
- A. Biswas, S. Pal and G. Udayabhanu, Appl. Surf. Sci., 353, 173 (2015); https://doi.org/10.1016/j.apsusc.2015.06.128.
- M. Mobin, M. Rizvi, L.O. Olasunkanmi and E.E. Ebenso, ACS Omega, 2, 3997 (2017); https://doi.org/10.1021/acsomega.7b00436.
- M. Abdallah, Port. Electrochim. Acta, 22, 161 (2004); https://doi.org/10.4152/pea.200402161.
- N. Patni, S. Agarwal and P. Shah, Chin. J. Eng., Article ID 784186 (2013); https://doi.org/10.1155/2013/784186.
- ASTM Practice Standard G-31 Standard Practice for Laboratory Immersion Corrosion Testing of Metals, ASTM International (2004).
- M.H. Hussin and M.J. Kassim, Mater. Chem. Phys., 125, 461 (2011); https://doi.org/10.1016/j.matchemphys.2010.10.032.
- S.S. Shivakumar, K.N. Mohana and D.M. Gurudatt, Chem. Sci. Trans., 2, 163 (2012); https://doi.org/10.7598/cst2013.302.
- S. Mukherjee and H.C. Srivastava, J. Am. Chem. Soc., 77, 422 (1955); https://doi.org/10.1021/ja01607a059.
- D.M.W. Anderson and A. Hendrie, Carbohydr. Res., 20, 259 (1971); https://doi.org/10.1016/S0008-6215(00)81379-8.
- G. Trabanelli and F. Mansfeld, Corrosion Inhibitors, Chemical Industries: Corrosion Mechanism, Chap. 3, p. 119 (1987).
- S.A. Umoren, O. Ogbobe, P.C. Okafor and E.E. Ebenso, J. Appl. Polym. Sci., 105, 3363 (2007); https://doi.org/10.1002/app.26530.
- K.O. Orubite and N.C. Oforka, Mater. Lett., 58, 1768 (2004); https://doi.org/10.1016/j.matlet.2003.11.030.
- A.Y. El-Etre, J. Appl. Surf. Sci., 252, 8521 (2006); https://doi.org/10.1016/j.apsusc.2005.11.066.
- E.E. Mola, Electrochim. Acta, 26, 1209 (1981); https://doi.org/10.1016/0013-4686(81)85101-8.
- M. Dahmani, A. Et-Touhami and A.S.S. Al-Deyab, Int. J. Electrochem. Sci., 5, 1060 (2010).
- V.R. Saliyan and A.V. Adhikari, Bull. Mater. Sci., 31, 699 (2007); https://doi.org/10.1007/s12034-008-0111-4.
- I.M. Mejeha, A.A. Uroh, K.B. Okeoma and G.A. Alozie, Afr. J. Pure Appl. Chem., 4, 158 (2010).
- C.O. Akalezi, C.K. Enenebaku, C.E. Ogukwe and E.E. Oguzie, J. Chem. Soc. Nigeria, 37, 117 (2012).
- D.K. Yadav and M.A. Quraishi, Ind. Eng. Chem. Res., 51, 14966 (2012); https://doi.org/10.1021/ie301840y.
- A.E.-A.S. Fouda, M.M. Farahat and M. Abdallah, Res. Chem. Intermed., 40, 1249 (2014); https://doi.org/10.1007/s11164-013-1036-0.
- S.A. Ali, A.M. El-Shareef, R.F. Al-Ghamdi and M.T. Saeed, Corros. Sci., 47, 2659 (2005); https://doi.org/10.1016/j.corsci.2004.11.007.
- S.A. Ali, M.T. Saeed and S.U. Rahman, Corros. Sci., 45, 253 (2003); https://doi.org/10.1016/S0010-938X(02)00099-9.
- D. Jayaperumal, Mater. Chem. Phys., 119, 478 (2010); https://doi.org/10.1016/j.matchemphys.2009.09.028.
- E.S. Ferreira, C. Giacomelli, F.C. Giacomelli and A. Spinelli, Mater. Chem. Phys., 83, 129 (2004); https://doi.org/10.1016/j.matchemphys.2003.09.020.
- N. Goudarzi, M. Peikari, M.R. Zahiri and H.R. Mousavi, Arch. Metall. Mater., 57, 845 (2012); https://doi.org/10.2478/v10172-012-0044-1.
- S.T. Arab and A.M. Al-Turkustani, Port. Electrochim. Acta, 24, 53 (2006); https://doi.org/10.4152/pea.200601053.
- I. Ahamad, R. Prasad and M.A. Quraishi, Corros. Sci., 52, 1472 (2010); https://doi.org/10.1016/j.corsci.2010.01.015.
- S.A. Barker, E.J. Bourne, M. Stacey and D.H. Whiffen, J. Chem. Soc., 171 (1954); https://doi.org/10.1039/jr9540000171.
- N.O. Eddy and E.E. Ebenso, Int. J. Electrochem. Sci., 6, 731 (2010).
- N.O. Eddy and E.E. Ebenso, Pigment Res. Technol., 39, 77 (2010); https://doi.org/10.1108/03699421011028653.
References
E.E. Ebenso, N.O. Eddy and A.O. Odiongenyi, Afr. J. Pure Appl. Chem., 2, 107 (2008).
A. Diab and S.M. Abd El-Haleem, Orient. J. Chem., 33, 1921 (2017); https://doi.org/10.13005/ojc/330438.
C.S.S.R. Kumar, M. Srinivas and S. Yakkundi, Phytochemistry, 43, 451 (1996); https://doi.org/10.1016/0031-9422(96)00226-9.
A. Ahamad and M.A. Quraishi, Corros. Sci., 52, 651 (2010); https://doi.org/10.1016/j.corsci.2009.10.012.
K. Mallaiya, R. Subramaniam, S.S. Srikandan, S. Gowri, N. Rajasekaran and A. Selvaraj, Electrochim. Acta, 56, 3857 (2011); https://doi.org/10.1016/j.electacta.2011.02.036.
D. Kesavan, M. Gopiraman and N. Sulochana, Chem. Sci. Rev. Lett., 1, 1 (2012).
P.C. Okafor and E.E. Ebenso, Pigm. Resin Technol., 36, 134 (2007); https://doi.org/10.1108/03699420710748992.
P.C. Okafor, M.E. Ikpi, I.E. Uwah, E.E. Ebenso, U.J. Ekpe and S.A. Umoren, Corros. Sci., 50, 2310 (2008); https://doi.org/10.1016/j.corsci.2008.05.009.
M. Kliskic, J. Radosevic, S. Gudic and V. Katalinic, J. Appl. Electrochem., 30, 823 (2000); https://doi.org/10.1023/A:1004041530105.
E.E. Ebenso, U.J. Ibok, U.J. Ekpe, S. Umoren, E. Jackson, O.K. Abiola, N.C. Oforka and S. Martinez, Trans. of SAEST, 39, 117 (2004).
G. Gunasekaran and L.R. Chauhan, Electrochim. Acta, 49, 4387 (2004); https://doi.org/10.1016/j.electacta.2004.04.030.
E.E. Oguzie, A.I. Onuchukwu, P.C. Okafor and E.E. Ebenso, Pigm. Resin Technol., 35, 63 (2006); https://doi.org/10.1108/03699420610652340.
A.M. Abdel-Gaber, B.A. Abd-El-Nabey, I.M. Sidahmed, A.M. ElZayady and M. Saadawy, Corros. Sci., 48, 2765 (2006); https://doi.org/10.1016/j.corsci.2005.09.017.
A. Peter, I.B. Obot and S.K. Sharma, Int. J. Ind. Chem., 6, 153 (2015); https://doi.org/10.1007/s40090-015-0040-1.
S.A. Umoren and U. M. Eduok, J. Carbohydr. Polym., 140, 314 (2015); https://doi.org/10.1016/j.carbpol.2015.12.038.
M. Mobin and M. Rizvi, Carbohydr. Polym., 136, 384 (2016); https://doi.org/10.1016/j.carbpol.2015.09.027.
S.A. Umoren, Cellulose, 15, 751 (2008); https://doi.org/10.1007/s10570-008-9226-4.
N.O. Eddy, P. Ameh, C.E. Gimba and E.E. Ebenso, Int. J. Electrochem. Sci., 6, 815 (2011).
A. Biswas, S. Pal and G. Udayabhanu, Appl. Surf. Sci., 353, 173 (2015); https://doi.org/10.1016/j.apsusc.2015.06.128.
M. Mobin, M. Rizvi, L.O. Olasunkanmi and E.E. Ebenso, ACS Omega, 2, 3997 (2017); https://doi.org/10.1021/acsomega.7b00436.
M. Abdallah, Port. Electrochim. Acta, 22, 161 (2004); https://doi.org/10.4152/pea.200402161.
N. Patni, S. Agarwal and P. Shah, Chin. J. Eng., Article ID 784186 (2013); https://doi.org/10.1155/2013/784186.
ASTM Practice Standard G-31 Standard Practice for Laboratory Immersion Corrosion Testing of Metals, ASTM International (2004).
M.H. Hussin and M.J. Kassim, Mater. Chem. Phys., 125, 461 (2011); https://doi.org/10.1016/j.matchemphys.2010.10.032.
S.S. Shivakumar, K.N. Mohana and D.M. Gurudatt, Chem. Sci. Trans., 2, 163 (2012); https://doi.org/10.7598/cst2013.302.
S. Mukherjee and H.C. Srivastava, J. Am. Chem. Soc., 77, 422 (1955); https://doi.org/10.1021/ja01607a059.
D.M.W. Anderson and A. Hendrie, Carbohydr. Res., 20, 259 (1971); https://doi.org/10.1016/S0008-6215(00)81379-8.
G. Trabanelli and F. Mansfeld, Corrosion Inhibitors, Chemical Industries: Corrosion Mechanism, Chap. 3, p. 119 (1987).
S.A. Umoren, O. Ogbobe, P.C. Okafor and E.E. Ebenso, J. Appl. Polym. Sci., 105, 3363 (2007); https://doi.org/10.1002/app.26530.
K.O. Orubite and N.C. Oforka, Mater. Lett., 58, 1768 (2004); https://doi.org/10.1016/j.matlet.2003.11.030.
A.Y. El-Etre, J. Appl. Surf. Sci., 252, 8521 (2006); https://doi.org/10.1016/j.apsusc.2005.11.066.
E.E. Mola, Electrochim. Acta, 26, 1209 (1981); https://doi.org/10.1016/0013-4686(81)85101-8.
M. Dahmani, A. Et-Touhami and A.S.S. Al-Deyab, Int. J. Electrochem. Sci., 5, 1060 (2010).
V.R. Saliyan and A.V. Adhikari, Bull. Mater. Sci., 31, 699 (2007); https://doi.org/10.1007/s12034-008-0111-4.
I.M. Mejeha, A.A. Uroh, K.B. Okeoma and G.A. Alozie, Afr. J. Pure Appl. Chem., 4, 158 (2010).
C.O. Akalezi, C.K. Enenebaku, C.E. Ogukwe and E.E. Oguzie, J. Chem. Soc. Nigeria, 37, 117 (2012).
D.K. Yadav and M.A. Quraishi, Ind. Eng. Chem. Res., 51, 14966 (2012); https://doi.org/10.1021/ie301840y.
A.E.-A.S. Fouda, M.M. Farahat and M. Abdallah, Res. Chem. Intermed., 40, 1249 (2014); https://doi.org/10.1007/s11164-013-1036-0.
S.A. Ali, A.M. El-Shareef, R.F. Al-Ghamdi and M.T. Saeed, Corros. Sci., 47, 2659 (2005); https://doi.org/10.1016/j.corsci.2004.11.007.
S.A. Ali, M.T. Saeed and S.U. Rahman, Corros. Sci., 45, 253 (2003); https://doi.org/10.1016/S0010-938X(02)00099-9.
D. Jayaperumal, Mater. Chem. Phys., 119, 478 (2010); https://doi.org/10.1016/j.matchemphys.2009.09.028.
E.S. Ferreira, C. Giacomelli, F.C. Giacomelli and A. Spinelli, Mater. Chem. Phys., 83, 129 (2004); https://doi.org/10.1016/j.matchemphys.2003.09.020.
N. Goudarzi, M. Peikari, M.R. Zahiri and H.R. Mousavi, Arch. Metall. Mater., 57, 845 (2012); https://doi.org/10.2478/v10172-012-0044-1.
S.T. Arab and A.M. Al-Turkustani, Port. Electrochim. Acta, 24, 53 (2006); https://doi.org/10.4152/pea.200601053.
I. Ahamad, R. Prasad and M.A. Quraishi, Corros. Sci., 52, 1472 (2010); https://doi.org/10.1016/j.corsci.2010.01.015.
S.A. Barker, E.J. Bourne, M. Stacey and D.H. Whiffen, J. Chem. Soc., 171 (1954); https://doi.org/10.1039/jr9540000171.
N.O. Eddy and E.E. Ebenso, Int. J. Electrochem. Sci., 6, 731 (2010).
N.O. Eddy and E.E. Ebenso, Pigment Res. Technol., 39, 77 (2010); https://doi.org/10.1108/03699421011028653.