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Vol. 33 No. 5 (2021): Vol 33 Issue 5, 2021

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Synthesis of 5-Hydroxymethylfurfural from Cassava (Manihot utilissima pohl) Peels through Dehydration Reaction using Deep Eutectic Solvent Based on Choline Chloride/Citric Acid

https://doi.org/10.14233/ajchem.2021.22374
R. Manurung
Department of Chemical Engineering, Universitas Sumatera Utara, Medan, 20155, Indonesia
H. Silalahi
Department of Chemical Engineering, Universitas Sumatera Utara, Medan, 20155, Indonesia
O. Winda
Department of Chemical Engineering, Universitas Sumatera Utara, Medan, 20155, Indonesia
A.G. Siregar
Department of Chemical Engineering, Universitas Sumatera Utara, Medan, 20155, Indonesia

Corresponding Author(s) : R. Manurung

renita.manurung@usu.ac.id; alwigery10@gmail.com

Asian Journal of Chemistry, Vol. 33 No. 5 (2021): Vol 33 Issue 5, 2021

Abstract

The high cellulose content in cassava peel has an opportunity to produce bio-based chemical products in 5-hydroxymethylfurfural (5-HMF) form. This study aimed to determine the optimum conditions of glucose dehydration reaction as a result of hydrolysis of the best cassava peel cellulose. The variables observed in this study were H2SO4 catalyst concentrations in the hydrolysis reaction, temperature and amount of deep eutectic solvents based on choline chloride/citric acid. The optimum dehydration reaction conditions in this study was the glucose:deep eutectic solvents mass ratio of 1:6 at the reaction temperature of 80 ºC. The highest yield of 64.50% at an initial glucose concentration of 5.70% using a 1.5% H2SO4 catalyst during the hydrolysis of cassava peel cellulose. The results obtained in this study indicated that addition of choline chloride/citric acid as deep eutectic solvent can increase the yield of 5-HMF.

Keywords

Choline choride Citric acid Dehydration reaction 5-Hydroxymethylfurfural
Manurung, R., Silalahi, H., Winda, O., & Siregar, A. (2021). Synthesis of 5-Hydroxymethylfurfural from Cassava (Manihot utilissima pohl) Peels through Dehydration Reaction using Deep Eutectic Solvent Based on Choline Chloride/Citric Acid. Asian Journal of Chemistry, 33(5), 1115–1119. https://doi.org/10.14233/ajchem.2021.22374
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