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Synthesis of Molecularly Imprinted Polymers using Methacrylic Acid and Ethylene Glycol Dimethacrylate by Precipitation Polymerization Method
Corresponding Author(s) : St. Fauziah
Asian Journal of Chemistry,
Vol. 33 No. 4 (2021): Vol 33 Issue 4
Abstract
The synthesis of molecularly imprinted polymers (MIPs) was carried out by using methacrylic acid as a monomer, ethylene glycol dimethacrylate as a crosslink and dibutyl phthalate as a mold through the precipitation polymerization method. The MIP was characterized with FTIR, surface area analyzer, SEM-EDS and ultraviolet-visible spectrophotometer. The MIP adsorption ability test variables for dibutyl phthalate were time and concentration. The FTIR indicates that the functional groups –OH, –C=O and –C=C contribute to the formation of MIP and the SEM-EDS analysis showed that the prepared MIP resembles as beads. The MIP’s ability to adsorb dibutyl phthalate is better than NIP and the optimum time to adsorb dibutyl phthalate is 60 min.
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- M.C. Hennion, J. Chromatogr. A, 856, 3 (1999); https://doi.org/10.1016/S0021-9673(99)00832-8
- Y. Yang, J. Yu, J. Yin, B. Shao and J. Zhang, J. Agric. Food Chem., 62, 11130 (2014); https://doi.org/10.1021/jf5037933
- G. Vasapollo, R.D. Sole, L. Mergola, M.R. Lazzoi, A. Scardino, S.Scorrano and G. Mele, Int. J. Mol. Sci., 12, 5908 (2011); https://doi.org/10.3390/ijms12095908
- H. Yan and K.H. Row, Int. J. Mol. Sci., 7, 155 (2006); https://doi.org/10.3390/i7050155
- H. Surikumaran, S. Mohamad and N. Sarih, Int. J. Mol. Sci., 15, 6111 (2014); https://doi.org/10.3390/ijms15046111
- A. Beltran, F. Borrull, R.M. Marcé and P.A.G. Cormack, Trends Analyt. Chem., 29, 1363 (2010); https://doi.org/10.1016/j.trac.2010.07.020
- S. Pardeshi and S.K. Singh, RSC Adv., 6, 23525 (2016); https://doi.org/10.1039/C6RA02784A
- M.S. Tabarestani, K. Rahnama, M. Jahanshahi, S. Nasrollanejad and M.S. Fatemi, J. Nanostruct., 6, 245 (2016).
- Z. Yang, F. Chen, Y. Tang and S. Li, J. Chem. Soc. Pak., 37, 939 (2015).
- N.A. Yusof, M.D. Appribeyan and J. Harson, Sains Malays., 39, 829 (2010).
- P.A.G. Cormack and A.Z. Elorza, J. Chromatogr. B Analyt. Technol. Biomed. Life Sci., 804, 173 (2004); https://doi.org/10.1016/j.jchromb.2004.02.013
- Y.F. Jin, Y.J. Zhang, Y.P. Zhang, J. Chen, X.M. Zhou and L.Y. Bai, J. Chem., 2013, 903210 (2013); https://doi.org/10.1155/2013/903210
- H. Shaikh, N. Memon, H. Khan, M.I. Bhanger and S.M. Nizamani, J. Chromatogr. A, 1247, 125 (2012); https://doi.org/10.1016/j.chroma.2012.05.056
References
M.C. Hennion, J. Chromatogr. A, 856, 3 (1999); https://doi.org/10.1016/S0021-9673(99)00832-8
Y. Yang, J. Yu, J. Yin, B. Shao and J. Zhang, J. Agric. Food Chem., 62, 11130 (2014); https://doi.org/10.1021/jf5037933
G. Vasapollo, R.D. Sole, L. Mergola, M.R. Lazzoi, A. Scardino, S.Scorrano and G. Mele, Int. J. Mol. Sci., 12, 5908 (2011); https://doi.org/10.3390/ijms12095908
H. Yan and K.H. Row, Int. J. Mol. Sci., 7, 155 (2006); https://doi.org/10.3390/i7050155
H. Surikumaran, S. Mohamad and N. Sarih, Int. J. Mol. Sci., 15, 6111 (2014); https://doi.org/10.3390/ijms15046111
A. Beltran, F. Borrull, R.M. Marcé and P.A.G. Cormack, Trends Analyt. Chem., 29, 1363 (2010); https://doi.org/10.1016/j.trac.2010.07.020
S. Pardeshi and S.K. Singh, RSC Adv., 6, 23525 (2016); https://doi.org/10.1039/C6RA02784A
M.S. Tabarestani, K. Rahnama, M. Jahanshahi, S. Nasrollanejad and M.S. Fatemi, J. Nanostruct., 6, 245 (2016).
Z. Yang, F. Chen, Y. Tang and S. Li, J. Chem. Soc. Pak., 37, 939 (2015).
N.A. Yusof, M.D. Appribeyan and J. Harson, Sains Malays., 39, 829 (2010).
P.A.G. Cormack and A.Z. Elorza, J. Chromatogr. B Analyt. Technol. Biomed. Life Sci., 804, 173 (2004); https://doi.org/10.1016/j.jchromb.2004.02.013
Y.F. Jin, Y.J. Zhang, Y.P. Zhang, J. Chen, X.M. Zhou and L.Y. Bai, J. Chem., 2013, 903210 (2013); https://doi.org/10.1155/2013/903210
H. Shaikh, N. Memon, H. Khan, M.I. Bhanger and S.M. Nizamani, J. Chromatogr. A, 1247, 125 (2012); https://doi.org/10.1016/j.chroma.2012.05.056