Issue

Vol. 30 No. 9 (2018): Vol 30 Issue 9

Copyright (c) 2018 AJC

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Inhibition Efficiency of Water Soluble Sr(ZnZr)1Fe10O19-PANI Composite against Strong Acidic Condition for Mild Steel

https://doi.org/10.14233/ajchem.2018.21402
S. Sivakumar
P.G. and Research Department of Chemistry, Government Arts College for Men (AUT), Nandanam, Chennai-600 035, India
P. Kamatchi Selvaraj
P.G. and Research Department of Chemistry, Government Arts College for Men (AUT), Nandanam, Chennai-600 035, India
S. Selvaraj
P.G. and Research Department of Chemistry, Government Arts College for Men (AUT), Nandanam, Chennai-600 035, India

Corresponding Author(s) : P. Kamatchi Selvaraj

porbal96@gmail.com

Asian Journal of Chemistry, Vol. 30 No. 9 (2018): Vol 30 Issue 9

Abstract

Polymerization of aniline along with nanoparticle size of strontium zinc zirconium ferrite (mixed metal oxide) powder using ammonium persulfate as an oxidizing agent at 0 ºC gives water soluble strontium zinc zirconium hexaferrite-polyaniline composite. Dodecylbenzene sulfonic acid was used as dopant and surfactant for the synthesis. Weight loss measurements, Tafel plot analysis and AC impedance measurement revealed that the synthesized material can act as good corrosion inhibitor in half molar and one molar acidic conditions at room temperature. Continuous measurement of open-circuit potential (OCP) also reflect the inhibition efficiency. Prepared composite acts as an effective pickling/corrosion inhibitor.

Keywords

Mild steel Corrosion Potentiodynamic polarization Electrochemical impedance spectroscopy
Sivakumar, S., Selvaraj, P. K., & Selvaraj, S. (2018). Inhibition Efficiency of Water Soluble Sr(ZnZr)1Fe10O19-PANI Composite against Strong Acidic Condition for Mild Steel. Asian Journal of Chemistry, 30(9), 2043–2048. https://doi.org/10.14233/ajchem.2018.21402
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. N. Sarkar, G. Sahoo, R. Das, G. Prusty, D. Sahu and S.K. Swain, Ind. Eng. Chem. Res., 55, 2921 (2016); https://doi.org/10.1021/acs.iecr.5b04887.
  2. T. Bellezze, G. Giuliani, A. Vicere and G. Roventi, Corros. Sci., 130, 12 (2018); https://doi.org/10.1016/j.corsci.2017.10.010.
  3. M. Finsgar and J. Jackson, Corros. Sci., 86, 17 (2014); https://doi.org/10.1016/j.corsci.2014.04.044.
  4. Y. Li, H. Zhang, X. Wang, J. Li and F. Wang, Corros. Sci., 53, 4044 (2011); https://doi.org/10.1016/j.corsci.2011.08.010.
  5. S.K. Shukla and M.A. Quraishi, Corros. Sci., 51, 1990 (2009); https://doi.org/10.1016/j.corsci.2009.05.020.
  6. M.L. Zheludkevich, S.K. Poznyak, L.M. Rodrigues, D. Raps, T. Hack, L.F. Dick, T. Nunes and M.G.S. Ferreira, Corros. Sci., 52, 602 (2010); https://doi.org/10.1016/j.corsci.2009.10.020.
  7. N. Pirhady Tavandashti, M. Ghorbani, A. Shojaei, Y. Gonzalez-Garcia, H. Terryn and J.M.C. Mol, Prog. Org. Coat., 99, 197 (2016); https://doi.org/10.1016/j.porgcoat.2016.04.046.
  8. X. Bai, T.H. Tran, D. Yu, A. Vimalanandan, X. Hu and M. Rohwerder, Corros. Sci., 95, 110 (2015); https://doi.org/10.1016/j.corsci.2015.03.003.
  9. C. Jeyaprabha, S. Sathiyanarayanan and G. Venkatachari, J. Electroanal. Chem., 583, 232 (2005); https://doi.org/10.1016/j.jelechem.2005.06.006.
  10. P. Arellanes-Lozada, O. Olivares-Xometl, D. Guzman-Lucero, N.V. Likhanova, M.A. Dominguez-Aguilar, I.V. Lijanova and E. ArceEstrada, Materials, 7, 5711 (2014); https://doi.org/10.3390/ma7085711.
  11. M.A. Quraishi and H.K. Sharma, Mater. Chem. Phys., 78, 18 (2003); https://doi.org/10.1016/S0254-0584(02)00313-9.
  12. A.A. Khadom, A.S. Yaro, A.S. AlTaie and A.A.H. Kadum, Port. Electrochim. Acta, 27, 699 (2009); https://doi.org/10.4152/pea.200906699.
  13. X. Wang, H. Yang and F. Wang, Corros. Sci., 53, 113 (2011); https://doi.org/10.1016/j.corsci.2010.09.029.
  14. F. Alvi, N. Aslam and S.F. Shaukat, Am. J. Appl. Chem., 3, 57 (2015); https://doi.org/10.11648/j.ajac.20150302.14.
  15. C. Jeyaprabha, S. Sathiyanarayanan and G. Venkatachari, J. Appl. Surface Polym. Sci., 101, 2144 (2005); https://doi.org/10.1002/app.22579.
  16. C. Jeyaprabha, S. Sathiyanarayanan, K.L.N. Phani and G. Venkatachari, J. Electroanal. Chem., 585, 250 (2005); https://doi.org/10.1016/j.jelechem.2005.08.017.
  17. Z. Grubac, I.S. Roncevic and M. Metikos-Hukovic, Corros. Sci., 102, 310 (2016); https://doi.org/10.1016/j.corsci.2015.10.022.
  18. B.N. Grgur, N.V. Krstajic, M.V. Vojnovic, È. Laènjevac and L. Gajic-Krstajic, Prog. Org. Coat., 33, 1 (1998); https://doi.org/10.1016/S0300-9440(97)00112-4.
  19. Y. Yi, G. Liu, Z. Jin and D. Feng, Int. J. Electrochem. Sci., 8, 3540 (2013).
  20. H. Gomez, M.K. Ram, F. Alvi, E. Stefanakos and A. Kumar, J. Phys. Chem. C, 114, 18797 (2010); https://doi.org/10.1021/jp106379e.
  21. C.-W. Peng, K.-C. Chang, C.-J. Weng, M.-C. Lai, C.-H. Hsu, S.-C. Hsu, Y.-Y. Hsu, W.-I. Hung, Y. Wei and J.-M. Yeh, Electrochim. Acta, 95, 192 (2013); https://doi.org/10.1016/j.electacta.2013.02.016.
  22. C.L. Yuan, Y.U. Hong and C.H. Lin, J. Magn. Magn. Mater., 323, 1851 (2011); https://doi.org/10.1016/j.jmmm.2011.02.015.
  23. P.J. Kinlen, Y. Ding and D.C. Silverman, Corrosion, 58, 490 (2002); https://doi.org/10.5006/1.3277639.
  24. S. Kalyane and U.V. Khadke, Int. J. Pure Appl. Phys., 13, 201 (2017).
  25. A.K. Singh and M.A. Quraishi, Corros. Sci., 52, 1373 (2010); https://doi.org/10.1016/j.corsci.2010.01.007.
  26. S. Sathiyanarayanan, S.S. Azim and G. Venkatachari, Electrochim. Acta, 52, 2068 (2007); https://doi.org/10.1016/j.electacta.2006.08.022.
  27. S.N. Victoria, R. Prasad and R. Manivannan, Int. J. Electrochem. Sci., 10, 2220 (2015).
  28. A.Y. Musa, A.A.H. Kadhum, A.B. Mohamad, A.R. Daud, M.S. Takriff and S.K. Kamarudin, Corros. Sci., 51, 2393 (2009); https://doi.org/10.1016/j.corsci.2009.06.024.
  29. F. Mansfeld, M.W. Kendig and S. Tsai, Corrosion, 38, 570 (1982); https://doi.org/10.5006/1.3577304.
  30. Y. Qiang, S. Zhang, S. Xu and W. Li, J. Colloid Interface Sci., 472, 52 (2016); https://doi.org/10.1016/j.jcis.2016.03.023.
  31. L.O. Olasunkanmi, I.B. Obot, M.M. Kabanda and E.E. Ebenso, J. Phys. Chem. C, 119, 16004 (2015); https://doi.org/10.1021/acs.jpcc.5b03285.
Read More
Author biographies is not available.
Download
PDF
Statistic
Read Counter : 0 Download : 0