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Vol. 33 No. 3 (2021): Vol 33 Issue 3

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Synthesis and Characterization of Chitosan-Polyaniline-Manganese Dioxide Nanocomposite for Removal of Methyl Orange Dye

https://doi.org/10.14233/ajchem.2021.23032
B.R.S. Rathore
Department of Chemistry, PAHER University, Udaipur-313003, India
N.P.S. Chauhan
Department of Chemistry, Faculty of Science, Bhupal Nobles’s University, Udaipur-313002, India
M.K. Rawal
Department of Chemistry, Vidya Bhawan Rural Institute, Udaipur-313002, India
S.C. Ameta
Department of Chemistry, PAHER University, Udaipur-313003, India
R. Ameta
Department of Chemistry, PAHER University, Udaipur-313003, India ; Department of Chemistry, J.R.N. Rajasthan Vidyapeeth (Deemed to be University), Udaipur-313001, India

Corresponding Author(s) : R. Ameta

rakshit_ameta@yahoo.in

Asian Journal of Chemistry, Vol. 33 No. 3 (2021): Vol 33 Issue 3

Abstract

An ecofriendly polymer composite based on chitosan, polyaniline and manganese dioxide has been prepared using batch adsorption method and analyzed by Fourier transform infrared (FTIR), UV-vis, X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). FTIR results suggested the presence of functional groups like hydroxyl and amino groups and also shown a significant shift in IR bands in CS-PANI-MnO2 composite. The surface of composite was quite rough within the folds of pleated regions as observed from the SEM and TEM morphologies. The prepared composite was also utilized as an adsorbent for the treatment of methyl orange from the aqueous solution and achieved a reasonably good adsorption capacity of 96.2%. The biochemical oxygen demand (BOD) and chemical oxygen demand (COD) tests also suggested their suitability for the adsorption of methyl orange dye.

Keywords

Polyaniline Chitosan MnO2 Nanocomposites Adsorption Dye degradation
Rathore, B., Chauhan, N., Rawal, M., Ameta, S., & Ameta, R. (2021). Synthesis and Characterization of Chitosan-Polyaniline-Manganese Dioxide Nanocomposite for Removal of Methyl Orange Dye. Asian Journal of Chemistry, 33(3), 671–676. https://doi.org/10.14233/ajchem.2021.23032
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References
  1. N. Jalali, G. Trujillo-de Santiago, M. Motevalian, M.Y. Karimi, N.P.S. Chauhan, Y. Habibi and M. Mozafari, Biomimet. Nanobiomater., 5, 74 (2016); https://doi.org/10.1680/jbibn.15.00016
  2. I. Nath, J. Chakraborty, P.M. Heynderickx and F. Verpoort, J. Appl. Catal. B, 227, 102 (2018); https://doi.org/10.1016/j.apcatb.2018.01.032
  3. H. Sani, H. Aliyu and S. Tukur, ISOR J. Appl. Chem., 8, 34 (2015); 4. M. Mozafari and N.P.S. Chauhan, Advanced Functional Polymers for Biomedical Applications, Elsevier (2019).
  4. M.J. Chatterjee, A. Ghosh, A. Mondal and D. Banerjee, RSC Adv., 7, 36403 (2017); https://doi.org/10.1039/C7RA03855K
  5. V. Janaki, B.-T. Oh, K. Shanthi, K.-J. Lee, A.K. Ramasamy and S. Kamala-Kannan, Synth. Met., 162, 974 (2012);
  6. https://doi.org/10.1016/j.synthmet.2012.04.015
  7. A.H. Gemeay, R.G. El-Sharkawy, I.A. Mansour and A.B. Zaki, Bull. Mater. Sci., 35, 585 (2012); https://doi.org/10.1007/s12034-012-0328-0
  8. D. Zhong, X. Liao, Y. Liu, N. Zhong and Y. Xu, Bioresour. Technol., 258, 125 (2018); https://doi.org/10.1016/j.biortech.2018.01.117
  9. S. Sultana, N. Ahmad, S.M. Faisal, M. Owais and S. Sabir, IET Nanobiotechnol., 11, 835 (2017); https://doi.org/10.1049/iet-nbt.2016.0215
  10. B. Mohammadi, S. Pirsa and M. Alizadeh, Polym. Polymer Compos., 27, 507 (2019); https://doi.org/10.1177/0967391119851439
  11. B. Pasela, A. Castillo, R. Simon, M. Pulido, H. Mana-ay, M. Abiquibil, R. Montecillo, K. Thumanu, D. von Tumacder and K. Taaca, Biomimetics, 4, 15 (2019); https://doi.org/10.3390/biomimetics4010015
  12. S.U. Rahman, S. Bilal and A.H.A. Shah, Polymers, 12, 2870 (2020); https://doi.org/10.3390/polym12122870
  13. M. Vellakkat and D. Hundekkal, Mater. Res. Express, 3, 015502 (2016); https://doi.org/10.1088/2053-1591/3/1/015502
  14. K. Pandiselvi and S. Thambidurai, Desalination Water Treat., 57, 8343 (2016); https://doi.org/10.1080/19443994.2015.1019365
  15. B.S. Rathore, N.P.S. Chauhan, M.K. Rawal, S.C. Ameta and R. Ameta, Polym. Bull., 77, 4833 (2019); https://doi.org/10.1007/s00289-019-02994-7
  16. A. Pawlak and M. Mucha, Thermochim. Acta, 396, 153 (2003); https://doi.org/10.1016/S0040-6031(02)00523-3
  17. T. Debnath, M.S. Islam, S. Hoque, P. Haque and M.M. Rahman, J. Polymer Eng., 40, 333 (2020); https://doi.org/10.1515/polyeng-2019-0312
  18. M. Masoumparast, M. Mokhtary and H. Kefayati, J. Polymer Eng., 40, 342 (2020); https://doi.org/10.1515/polyeng-2019-0331
  19. H. Zheng, Y.M. Du, J.H. Yu, R.H. Huang and L.N. Zhang, J. Appl. Polym. Sci., 80, 2558 (2001); https://doi.org/10.1002/app.1365
  20. V. Kumar, S. Das and T. Yokozeki, J. Polymer Eng., 38, 955 (2018); https://doi.org/10.1515/polyeng-2018-0031
  21. N.P.S. Chauhan, R. Ameta, R. Ameta and S.C. Ameta, Indian J. Chem. Technol., 18, 118 (2011).
  22. C.-C. Huang, S.-P. Rwei, Y.-S. Huang and Y.-C. Shu, J. Polymer Eng.,40, 495 (2020); https://doi.org/10.1515/polyeng-2019-0332
  23. R. Yang, Z. Wang, L. Dai and L. Chen, Mater. Chem. Phys., 93, 149 (2005); https://doi.org/10.1016/j.matchemphys.2005.03.006
  24. X.J. Yang, Y. Makita, Z. Liu, K. Sakane and K. Ooi, Chem. Mater., 16, 5581 (2004); https://doi.org/10.1021/cm049025d
  25. V. Sridevi, S. Malathi and C.S. Devi, Chem. Sci. J., 26, 1 (2011) .
  26. A. Shyaa, O.A. Hasan and A.M. Abbas, J. Saudi Chem. Soc., 19, 101 (2015); https://doi.org/10.1016/j.jscs.2012.01.001
  27. R. Karthik and S. Meenakshi, Int. J. Biol. Macromol., 67, 210 (2014); https://doi.org/10.1016/j.ijbiomac.2014.03.035
  28. G. Li, C. Zhang, H. Peng, K. Chen and Z. Zhang, Macromol. Rapid Commun., 29, 1954 (2008); https://doi.org/10.1002/marc.200800501
  29. F. Akbarzadeh, M. Motaghi, N.P.S. Chauhan and G. Sargazi, Heliyon, 6, e03231 (2020); https://doi.org/10.1016/j.heliyon.2020.e03231
  30. N.P.S. Chauhan, M. Mozafari, R. Ameta, P.B. Punjabi and S.C. Ameta, J. Phys. Chem. B, 119, 3223 (2015); https://doi.org/10.1021/jp510320g
  31. P. Kannusamy and T. Sivalingam, Colloids Surf. B Biointerfaces, 108, 229 (2013); https://doi.org/10.1016/j.colsurfb.2013.03.015
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