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Vol. 30 No. 7 (2018): Vol 30 Issue 7

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Synthesis, Characterization and Antibacterial Studies of Silver Complex of 3-Aminopropyltriethoxysilane

https://doi.org/10.14233/ajchem.2018.21177
Hayder Hamied Mihsen
Department of Chemistry, College of Science, University of Kerbala, Kerbala, Iraq
Nesser Kadham Shareef
Department of Chemistry, College of Science, University of Kerbala, Kerbala, Iraq
Wafaa Sadeq Alwazni
Department of Biology, College of Science, University of Kerbala, Kerbala, Iraq

Corresponding Author(s) : Hayder Hamied Mihsen

hayderalhmedawy@gmail.com

Asian Journal of Chemistry, Vol. 30 No. 7 (2018): Vol 30 Issue 7

Abstract

A new complex of silver, [Ag(APTES)2NO3] using 3-aminopropyltriethoxysilane (APTES) as a ligand has been symthesized. The new complex was characterized by molar conductance measurement, UV-visible, infrared, nuclear magnetic resonance, thermogravimetry and atomic absorption spectroscopy. FT-IR and 1H NMR analyses indicated that ligand APTES and NO3– ion are coordinated to the silver ion via nitrogen amino group and oxygen nitro group, respectively. Molar conductance value for the complex indicates that the complex is non-electrolyte. While TGA-DTA analysis showed that the degradation of complex occurs between 200-593 ºC. The complex assume triagonal geometry in which Ag(I) have two molecules of APTES and one molecule from ionic nitrate in the coordination sphere. The new complex of [Ag(APTES)2NO3] showed pronounced antibacterial effect against proteus (P. mirablis) bacteria isolated from patient with urinary tract infection. Also had been exhibited a clear decrease in the ability of tested bacteria to form biofilm after treating with MIC of complex.

Keywords

3-Aminopropyltriethoxysilane Silver nitrate Antibiofilm efficacy
Mihsen, H. H., Shareef, N. K., & Alwazni, W. S. (2018). Synthesis, Characterization and Antibacterial Studies of Silver Complex of 3-Aminopropyltriethoxysilane. Asian Journal of Chemistry, 30(7), 1465–1468. https://doi.org/10.14233/ajchem.2018.21177
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