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Vol. 30 No. 7 (2018): Vol 30 Issue 7

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A Simple and Efficient Iodination of Aromatic Compounds Using I2/Choline Chloride/K2S2O8

https://doi.org/10.14233/ajchem.2018.21308
D. Parthiban
P.G. & Research Department of Chemistry, Arignar Anna Government Arts College, Cheyyar-604 407, India
R. Joel Karunakaran
Department of Chemistry, Madras Christian College, Tambaram, Chennai-600 059, India

Corresponding Author(s) : R. Joel Karunakaran

rjkmcc@yahoo.com

Asian Journal of Chemistry, Vol. 30 No. 7 (2018): Vol 30 Issue 7

Abstract

A simple and efficient method for the iodination of aromatic compounds has been achieved in the presence of molecular iodine, choline chloride and potassium peroxodisulfate at 65 °C in acetonitrile. The rate of conversion of aromatic compounds into iodoaromatic compounds was promoted by in situ formed choline peroxodisulfate. This protocol provides an efficient access to iodoarenes with operational simplicity, good functional group tolerance and a moderate to good product yield

Keywords

Iodination Choline chloride Potassium peroxodisulfate Choline peroxodisulfate Molecular iodine
Parthiban, D., & Karunakaran, R. J. (2018). A Simple and Efficient Iodination of Aromatic Compounds Using I2/Choline Chloride/K2S2O8. Asian Journal of Chemistry, 30(7), 1659–1663. https://doi.org/10.14233/ajchem.2018.21308
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