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Vol. 30 No. 6 (2018): Vol 30 Issue 6

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Transport Properties of Diethyl Malonate with Aniline and Benzaldehyde at 308.15 and 318.15 K

https://doi.org/10.14233/ajchem.2018.21233
P. Prabhu
Department of Chemistry, St. Joseph’s College, Tiruchirappalli-620 002, India
U. Revathy
Department of Chemistry, St. Joseph’s College, Tiruchirappalli-620 002, India
A. Rose Venis
Department of Chemistry, St. Joseph’s College, Tiruchirappalli-620 002, India

Corresponding Author(s) : P. Prabhu

ruban_prabhu@yahoo.com; prabhuruban51@gmail.com

Asian Journal of Chemistry, Vol. 30 No. 6 (2018): Vol 30 Issue 6

Abstract

Densities, viscosities and ultrasonic velocities of binary liquid mixtures of diethyl malonate with aniline and benzaldehyde have been measured at 308.15 and 318.15 K. From these data, excess volume (VE), deviation in isentropic compressibility (ΔKS), deviation in viscosity (Δη), deviation in intermolecular free length (ΔLf), deviation in free volume (ΔVf), deviation in internal pressure (Δπi) and deviation in acoustic impedance (ΔZ) have been calculated. These results were correlated with the Redlich and Kister type polynomial equation to derive the coefficients and standard errors. Variations in the calculated excess quantities have been studied for mixtures of diethyl malonate with component liquids. From the value of excess properties, intermolecular interactions have been studied.

Keywords

Density Viscosity Ultrasonic velocity Excess properties Binary mixture Molecular interaction
Prabhu, P., Revathy, U., & Venis, A. R. (2018). Transport Properties of Diethyl Malonate with Aniline and Benzaldehyde at 308.15 and 318.15 K. Asian Journal of Chemistry, 30(6), 1325–1330. https://doi.org/10.14233/ajchem.2018.21233
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