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Vol. 30 No. 6 (2018): Vol 30 Issue 6

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Complexation and Extraction of Transition Metal Cations by New Azodyes: Synthesis, Structure Elucidation and Binding Properties

https://doi.org/10.14233/ajchem.2018.20720
Olfa Naouali
Laboratory of Applied Chemistry and Natural Substances Resources and Environment, Faculty of Sciences, University of Carthage, Zarzouna, Bizerta, 7021, Tunisia
Besma Mellah
National Center of Researches in Material Sciences (CNRSM), Borj CedriaTechnopark, BP 73, 8027 Soliman, Tunisia
Riadh Ternane
Laboratory of Applied Chemistry and Natural Substances Resources and Environment, Faculty of Sciences, University of Carthage, Zarzouna, Bizerta, 7021, Tunisia
Lassaad Baklouti
Laboratory of Applied Chemistry and Natural Substances Resources and Environment, Faculty of Sciences, University of Carthage, Zarzouna, Bizerta, 7021, Tunisia; Chemistry Department, College of Science and Arts, Qassim University, Al-Rass, Kingdom of Saudi Arabia
Abdelwaheb Hamdi
Laboratory of Applied Chemistry and Natural Substances Resources and Environment, Faculty of Sciences, University of Carthage, Zarzouna, Bizerta, 7021, Tunisia; Chemistry Department, College of Science and Arts, Qassim University, Al-Rass, Kingdom of Saudi Arabia
Naceur Hamdi
Chemistry Department, College of Science and Arts, Qassim University, Al-Rass, Kingdom of Saudi Arabia; Research Laboratory of Environmental Sciences and Technologies (LR16ES09), Higher Institute of Environmental Sciences and Technology, University of Carthage, Hammam-Lif, Tunisia

Corresponding Author(s) : Naceur Hamdi

naceur.hamdi@isste.rnu.tn

Asian Journal of Chemistry, Vol. 30 No. 6 (2018): Vol 30 Issue 6

Abstract

A series of new 3-aryl(hetaryl)hydrazono-2,4-chromandiones (3a-c) were obtained in high yields, by coupling 4-hydroxycoumarin with derivatives diazonium salts, which were obtained by diazotization of aniline derivatives in presence of sodium nitrite and concentrated HCl. The azo dyes prepared may exist in four tautomeric forms. Structures of the synthesized compounds have been investigated by means of UV, IR, 1H NMR, 13C NMR and elemental analysis in order to elucidate their tautomeric and isomeric structures. The results of such spectral data indicated that compound 3 exist predominantly in hydrazo structure (D). The complexation and extraction of some transition metal cations have been followed by UV-visible spectrophotometry absorption. The conductivity studies have been used in order to confirm complex’s stoichiometries.

Keywords

Synthesis Azo-hydrazone tautomerism Coupling reaction Complexation Extraction
Naouali, O., Mellah, B., Ternane, R., Baklouti, L., Hamdi, A., & Hamdi, N. (2018). Complexation and Extraction of Transition Metal Cations by New Azodyes: Synthesis, Structure Elucidation and Binding Properties. Asian Journal of Chemistry, 30(6), 1195–1200. https://doi.org/10.14233/ajchem.2018.20720
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