Spectroscopic Investigations of The Reaction Products of (NPH2)3 With Si(IV)

Abstract

Hexahydrocyclotriphosphazene, (NPH₂)₃ was used as a ligand and on refluxing 150-200 ºC in presence of benzene with SiCl₄, the two reaction products, first mass aggregated, termed as Si(A) and on concentration of filtrate, product obtained, was termed as Si(B). On the basis of their ¹H, ³¹P, NMR, UV and XRD spectral investigations, Si(A) and Si(B) have assigned the subsequently as (P₃N₃H₄)5S_i3Cl₅ and (P₃N₃H₄)₅(SiCl₂)₄.