Copyright (c) 2019 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Production of Acetyl Cellulose from Agricultural Waste of Oil Palm Empty Fruit Bunches
Corresponding Author(s) : S.D. Yuwono
Asian Journal of Chemistry,
Vol. 31 No. 12 (2019): Vol 31 Issue 12
Abstract
In Indonesia especially in Lampung Province, there are a lot of oil palm empty fruit bunches (OPEFB) as an organic material waste. OPEFB is relatively inexpensive lignocellulose material as raw material of cellulose acetate or acetyl cellulose. In a business to bigger added value out of these natural renewable materials, the production of the acetyl cellulose was performed well by the acetylation of cellulose from OPEFB using different methods. These were extensively characterized using thermogravimetric analysis, Fourier transform infrared spectroscopy and X-ray diffraction. The results indicated that the acetyl cellulose resulted showed similar properties to cotton acetyl cellulose. Degree of substitution of the resultant acetyl cellulose from different methods was improved from 1.86 to 2.60.
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- H.N. Cheng, M.K. Dowd, G.W. Selling and A. Biswas, Carbohydr. Polym., 80, 449 (2010); https://doi.org/10.1016/j.carbpol.2009.11.048.
- J.F. Sassi and H. Chanzy, Cellulose, 2, 111 (1995); https://doi.org/10.1007/BF00816384.
- K.J. Edgar, C.M. Buchanan, J.S. Debenham, P.A. Rundquist, B.D. Seiler, M.C. Shelton and D. Tindall, Prog. Polym. Sci., 26, 1605 (2001); https://doi.org/10.1016/S0079-6700(01)00027-2.
- A. Biswas, B.C. Saha, J.W. Lawton, R.L. Shogren and J.L. Willett, Cellulose, 10, 283 (2003); https://doi.org/10.1023/A:1025117327970.
- A. Biswas, B.C. Shah, J.W. Lawton and J.L. Willett, Carbohydr. Polym., 64, 134 (2006); https://doi.org/10.1016/j.carbpol.2005.11.002.
- G. Rodrigues-Filho, D.S. Monteiro, C.S. Meireles, R.M.N. de Assunção, D.A. Cerqueira, H.S. Barud, S.J.L. Ribeiro and Y. Messadeq, Carbohydr. Polym., 73, 74 (2008); https://doi.org/10.1016/j.carbpol.2007.11.010.
- J. Wu, J. Zhang, H. Zhang, J. He, Q. Ren and M. Guo, Biomacromolecules, 5, 266 (2004); https://doi.org/10.1021/bm034398d.
- L. Yan, W. Li, Z. Qi and S. Liu, J. Polym. Res., 13, 375 (2006); https://doi.org/10.1007/s10965-006-9054-x.
- T. Heinze, T. Liebert and A. Koschella, Esterification of Polysaccharides, Springer: Berlin, pp. 41-116 (2006).
- A. Biswas, G. Selling, M. Appell, K.K. Woods, J.L. Willett and C.M. Buchanan, Carbohydr. Polym., 68, 555 (2007); https://doi.org/10.1016/j.carbpol.2006.10.018.
- Suharso and Buhani, Asian J. Chem., 23, 1112 (2011).
- B. Buhani, S. Suharso and Z. Sembiring, Orient. J. Chem., 28, 271 (2012); https://doi.org/10.13005/ojc/280133.
- F.B. Ahmad, Z. Zhang, W.O.S. Doherty and I.M. O'Hara, Biofuels, Bioprod. Bioref., 10, 378 (2016); https://doi.org/10.1002/bbb.1645.
- S.H. Chang, Biomass Bioenergy, 62, 174 (2014); https://doi.org/10.1016/j.biombioe.2014.01.002.
- B. Buhani, S. Suharso and L. Aprilia, Indo. J. Chem., 12, 94 (2012); https://doi.org/10.22146/ijc.21378.
- M.D. Fauzi, M. Asad, M.N.M. Ibrahim and W.D. Wanrosli, BioResources, 9, 4710 (2014).
- M.S. Nazir, B.A. Wahjoedi, A.W. Yussof and M.A. Abdullah, BioResources, 8, 2161 (2013); https://doi.org/10.15376/biores.8.2.2161-2172.
- H.M. Shaikh, K.V. Pandare, G. Nair and A.J. Varma, ed.: R.L. Whistler, J.W. Green, J.N. Bemiller and M.L. Wolfram, Cellulose Ester: Prepara-tion, Properties, Reaction and Analyses: Cellulose Acetate, Method In: Carbohydrate Chemistry, Academic Press: New York (2009).
- T. Ozaki, H. Ogawa and H. Sasai, Cellulose Triacetates and Methods for Producing the Cellulose Acetate, US Patent 6,683,174 (2004).
- W.D. Wanrosli, I. Mazlan, K.N. Law and R. Nasrullah, Maderas Cienc. Tecnol., 13, 193 (2011); https://doi.org/10.4067/S0718-221X2011000200007.
- R. Sun, J.M. Fang, L. Mott and J. Bolton, J. Wood Chem. Technol., 19, 167 (1999); https://doi.org/10.1080/02773819909349606.
- S.M.L. Rosa, N. Rehman, M.I.G. de Miranda, S.M.B. Nachtigall and C.I.D. Bica, Carbohydr. Polym., 87, 1131 (2012); https://doi.org/10.1016/j.carbpol.2011.08.084.
- M. Jahan, A. Saeed, Z. He and Y. Ni, Cellulose, 18, 451 (2011); https://doi.org/10.1007/s10570-010-9481-z.
- G.R. Filho, S.F. da Cruz, D. Pasquini, D.A. Cerqueira, V.S. Prado and R.M.N. de Assunção, J. Membr. Sci., 177, 225 (2000); https://doi.org/10.1016/S0376-7388(00)00469-5.
- H. Kono, Y. Numata, N. Nagai, T. Erata and T. Takai, J. Polym. Sci., Part A Polym. Chem., 37, 4100 (1999); https://doi.org/10.1002/(SICI)1099-0518(19991115)37:22<4100::AID-POLA8>3.0.CO;2-D.
- A. Alemdar and M. Sain, Bioresour. Technol., 99, 1664 (2008); https://doi.org/10.1016/j.biortech.2007.04.029.
References
H.N. Cheng, M.K. Dowd, G.W. Selling and A. Biswas, Carbohydr. Polym., 80, 449 (2010); https://doi.org/10.1016/j.carbpol.2009.11.048.
J.F. Sassi and H. Chanzy, Cellulose, 2, 111 (1995); https://doi.org/10.1007/BF00816384.
K.J. Edgar, C.M. Buchanan, J.S. Debenham, P.A. Rundquist, B.D. Seiler, M.C. Shelton and D. Tindall, Prog. Polym. Sci., 26, 1605 (2001); https://doi.org/10.1016/S0079-6700(01)00027-2.
A. Biswas, B.C. Saha, J.W. Lawton, R.L. Shogren and J.L. Willett, Cellulose, 10, 283 (2003); https://doi.org/10.1023/A:1025117327970.
A. Biswas, B.C. Shah, J.W. Lawton and J.L. Willett, Carbohydr. Polym., 64, 134 (2006); https://doi.org/10.1016/j.carbpol.2005.11.002.
G. Rodrigues-Filho, D.S. Monteiro, C.S. Meireles, R.M.N. de Assunção, D.A. Cerqueira, H.S. Barud, S.J.L. Ribeiro and Y. Messadeq, Carbohydr. Polym., 73, 74 (2008); https://doi.org/10.1016/j.carbpol.2007.11.010.
J. Wu, J. Zhang, H. Zhang, J. He, Q. Ren and M. Guo, Biomacromolecules, 5, 266 (2004); https://doi.org/10.1021/bm034398d.
L. Yan, W. Li, Z. Qi and S. Liu, J. Polym. Res., 13, 375 (2006); https://doi.org/10.1007/s10965-006-9054-x.
T. Heinze, T. Liebert and A. Koschella, Esterification of Polysaccharides, Springer: Berlin, pp. 41-116 (2006).
A. Biswas, G. Selling, M. Appell, K.K. Woods, J.L. Willett and C.M. Buchanan, Carbohydr. Polym., 68, 555 (2007); https://doi.org/10.1016/j.carbpol.2006.10.018.
Suharso and Buhani, Asian J. Chem., 23, 1112 (2011).
B. Buhani, S. Suharso and Z. Sembiring, Orient. J. Chem., 28, 271 (2012); https://doi.org/10.13005/ojc/280133.
F.B. Ahmad, Z. Zhang, W.O.S. Doherty and I.M. O'Hara, Biofuels, Bioprod. Bioref., 10, 378 (2016); https://doi.org/10.1002/bbb.1645.
S.H. Chang, Biomass Bioenergy, 62, 174 (2014); https://doi.org/10.1016/j.biombioe.2014.01.002.
B. Buhani, S. Suharso and L. Aprilia, Indo. J. Chem., 12, 94 (2012); https://doi.org/10.22146/ijc.21378.
M.D. Fauzi, M. Asad, M.N.M. Ibrahim and W.D. Wanrosli, BioResources, 9, 4710 (2014).
M.S. Nazir, B.A. Wahjoedi, A.W. Yussof and M.A. Abdullah, BioResources, 8, 2161 (2013); https://doi.org/10.15376/biores.8.2.2161-2172.
H.M. Shaikh, K.V. Pandare, G. Nair and A.J. Varma, ed.: R.L. Whistler, J.W. Green, J.N. Bemiller and M.L. Wolfram, Cellulose Ester: Prepara-tion, Properties, Reaction and Analyses: Cellulose Acetate, Method In: Carbohydrate Chemistry, Academic Press: New York (2009).
T. Ozaki, H. Ogawa and H. Sasai, Cellulose Triacetates and Methods for Producing the Cellulose Acetate, US Patent 6,683,174 (2004).
W.D. Wanrosli, I. Mazlan, K.N. Law and R. Nasrullah, Maderas Cienc. Tecnol., 13, 193 (2011); https://doi.org/10.4067/S0718-221X2011000200007.
R. Sun, J.M. Fang, L. Mott and J. Bolton, J. Wood Chem. Technol., 19, 167 (1999); https://doi.org/10.1080/02773819909349606.
S.M.L. Rosa, N. Rehman, M.I.G. de Miranda, S.M.B. Nachtigall and C.I.D. Bica, Carbohydr. Polym., 87, 1131 (2012); https://doi.org/10.1016/j.carbpol.2011.08.084.
M. Jahan, A. Saeed, Z. He and Y. Ni, Cellulose, 18, 451 (2011); https://doi.org/10.1007/s10570-010-9481-z.
G.R. Filho, S.F. da Cruz, D. Pasquini, D.A. Cerqueira, V.S. Prado and R.M.N. de Assunção, J. Membr. Sci., 177, 225 (2000); https://doi.org/10.1016/S0376-7388(00)00469-5.
H. Kono, Y. Numata, N. Nagai, T. Erata and T. Takai, J. Polym. Sci., Part A Polym. Chem., 37, 4100 (1999); https://doi.org/10.1002/(SICI)1099-0518(19991115)37:22<4100::AID-POLA8>3.0.CO;2-D.
A. Alemdar and M. Sain, Bioresour. Technol., 99, 1664 (2008); https://doi.org/10.1016/j.biortech.2007.04.029.