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Vol. 30 No. 5 (2018): Vol 30 Issue 5, 2018

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Synthesis of Zeolite Beta and Zeolite ZSM-5 from High Silica Raw Kaolinite and Their Catalytic Etherification of Ethylene Glycol

https://doi.org/10.14233/ajchem.2018.21154
Rasha S. Rawajfeh
Department of Chemistry, Faculty of Science, The University of Jordan, Amman 11942, Jordan
Hamdallah A. Hodali
Department of Chemistry, Faculty of Science, The University of Jordan, Amman 11942, Jordan

Corresponding Author(s) : Hamdallah A. Hodali

h-hodali@ju.edu.jo; hodali19@gmail.com

Asian Journal of Chemistry, Vol. 30 No. 5 (2018): Vol 30 Issue 5, 2018

Abstract

Pure phases of zeolites Beta and ZSM-5 were synthesized from high silica raw kaolinite. Both zeolites were characterized by XRD, XRF, SEM and N2 adsorption/desorption isotherms. The acid forms of zeolites (H-zeolite) were used in the catalytic etherification of ethylene glycol with benzyl alcohol and with t-butanol. In the reaction of ethylene glycol with benzyl alcohol, ethylene glycol monobenzyl ether was the only detected product over H-ZSM-5, while in case of H-zeolite Beta, ethylene glycol monobenzyl ether and ethylene glycol dibenzyl ether were detected. The highest yield of ethylene glycol monobenzyl ether (58 %) was obtained from H-ZSM-5 prepared from raw kaolinite.

Keywords

Zeolite Beta Zeolite ZSM-5 Ethylene glycol Ethylene glycol monobenzyl ether Ethylene glycol mono-t-butyl ether
Rawajfeh, R. S., & Hodali, H. A. (2018). Synthesis of Zeolite Beta and Zeolite ZSM-5 from High Silica Raw Kaolinite and Their Catalytic Etherification of Ethylene Glycol. Asian Journal of Chemistry, 30(5), 1044–1050. https://doi.org/10.14233/ajchem.2018.21154
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