Alumina Supported H3PW12O40 and Ni Catalysts for Hydrocracking of n-Decane
JINGYUN SHENG
Department of Chemistry, State Key Laboratory for Physical Chemistry of the Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen-361005, P.R. China
BO QIU
Department of Chemistry, State Key Laboratory for Physical Chemistry of the Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen-361005, P.R. China
HAO JIN
Department of Chemistry, State Key Laboratory for Physical Chemistry of the Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen-361005, P.R. China
XIAODONG YI
Department of Chemistry, State Key Laboratory for Physical Chemistry of the Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen-361005, P.R. China
WEIPING FANG
Department of Chemistry, State Key Laboratory for Physical Chemistry of the Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen-361005, P.R. China
Corresponding Author(s) : XIAODONG YI
xdyi@xmu.edu.cn
Asian Journal of Chemistry,
Vol. 22 No. 6 (2010): Vol 22 Issue 6
A novel series of bifunctional Ni-H3PW12O40/Al2O3 catalysts for the hydrocracking of n-decane were designed and prepared. The evaluation results of these novel catalysts showed that they possessed extremely high catalytic activity for hydrocracking of n-decane and excellent tolerance to the sulfur and nitrogen compounds in the feedstock. In order to reveal the structure and nature of the catalysts, a number of characterizations including XRD, BET, H2-TPD, NH3-TPD and FT-IR of pyridine adsorption were carried out. The characterization results demonstrated that the high catalytic activity and high C5 + selectivity of the catalysts can be attributed to the unique structure of the H3PW12O40 and the interactions between the metal sites and the H3PW12O40.
SHENG, J., QIU, B., JIN, H., YI, X., & FANG, W. (2010). Alumina Supported H3PW12O40 and Ni Catalysts for Hydrocracking of n-Decane. Asian Journal of Chemistry, 22(6), 4439–4449. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/16752
