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Vol. 30 No. 5 (2018): Vol 30 Issue 5, 2018

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Synthesis and Characterization of Zeolite Materials from Power Plant Fly Ash

https://doi.org/10.14233/ajchem.2018.21089
Y. Prawiyanto
Graduate Department of Chemistry, Faculty Mathematic and Natural Sciences, Tanjungpura University, Jl. Prof. Hadari Nawawi, Pontianak, Indonesia
A. Shofiyani
Graduate Department of Chemistry, Faculty Mathematic and Natural Sciences, Tanjungpura University, Jl. Prof. Hadari Nawawi, Pontianak, Indonesia
T.A. Zaharah
Graduate Department of Chemistry, Faculty Mathematic and Natural Sciences, Tanjungpura University, Jl. Prof. Hadari Nawawi, Pontianak, Indonesia

Corresponding Author(s) : A. Shofiyani

anis.shofiyani@chemistry.untan.ac.id

Asian Journal of Chemistry, Vol. 30 No. 5 (2018): Vol 30 Issue 5, 2018

Abstract

The natural zeolite has been successfully synthesized from Sungai Ringin power plant fly ash. The material was then used to reduce total organic carbon (TOC) of crude palm oil (CPO) industrial waste. Results show that the synthesis process using a 2.5 M of NaOH as mineralizer produces zeolite type of analcime and cancrinite (namely Zeo 2.5); a 5.0 M generates type of cancrinite (namely Zeo 5.0) and a concentration of 7.5 M produces type of cancrinite and losod (namely Zeo 7.5) with surface area, pore volume and pore size as much as 41.405 m2/g, 0.146 cc/g and 19.198 Å; 43.499 m2/g, 0.222 cc/g and 21.554 Å; and 42.605 m2/g, 0.152 cc/g and 19.271 Å, respectively. In application, Zeo 2.5, Zeo 5.0 and Zeo 7.5 can reduce total organic carbon by 60, 72.26 and 62.60 %, respectively, of the initial concentration of 2,329 mg/L.

Keywords

Synthesis Zeolite Fly ash Reduction Total organic carbon Crude palm oil
Prawiyanto, Y., Shofiyani, A., & Zaharah, T. (2018). Synthesis and Characterization of Zeolite Materials from Power Plant Fly Ash. Asian Journal of Chemistry, 30(5), 993–997. https://doi.org/10.14233/ajchem.2018.21089
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