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Spectral Studies of Ln(III) Complexes with Pyridine Propanamine-γ-(4-chlorophenyl)-N,N-dimethyl-2-maleate
Asian Journal of Chemistry,
Vol. 22 No. 1 (2010): Vol 22 Issue 1, 2010
Abstract
Complexes of La3+, Pr3+, Nd3+, Sm3+, Gd3+, Tb3+ and Dy3+ with pyridine
propanamine-γ-(4-chlorophenyl)-N,N-dimethyl-2-maleate have been
prepared, structures of the complexes have been established on the basis
of elemental analysis, magnetic moment, infrared, thermal analysis, X-ray
powder diffraction and electronic spectra. The ligand is bonded through
nitrogen of propanamine and nitrogen of pyridine with metal ions. The
magnetic moment studies indicate that, it is slightly participation with
4ƒ electrons in bonding. The X-ray powder diffraction studies indicate
that, the unit cell is monoclinic and space group of complexes is C2/m or
Pc/m. This ligand is anti-histaminic and active towards gram positive and
gram negative bacteria.
propanamine-γ-(4-chlorophenyl)-N,N-dimethyl-2-maleate have been
prepared, structures of the complexes have been established on the basis
of elemental analysis, magnetic moment, infrared, thermal analysis, X-ray
powder diffraction and electronic spectra. The ligand is bonded through
nitrogen of propanamine and nitrogen of pyridine with metal ions. The
magnetic moment studies indicate that, it is slightly participation with
4ƒ electrons in bonding. The X-ray powder diffraction studies indicate
that, the unit cell is monoclinic and space group of complexes is C2/m or
Pc/m. This ligand is anti-histaminic and active towards gram positive and
gram negative bacteria.
Keywords
Ln(III)
Complexes
Pyridine propanamine-g
V. LOKHANDE*, M., T. TAJANE†, S., & GEORGE A‡, K. (2024). Spectral Studies of Ln(III) Complexes with Pyridine Propanamine-γ-(4-chlorophenyl)-N,N-dimethyl-2-maleate. Asian Journal of Chemistry, 22(1), 401–407. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/16721
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