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Synthesis and Crystal Structure of a New Mononuclear Complex: [Cd(C10H12N2O)2(NO3)2(H2O)2]
Asian Journal of Chemistry,
Vol. 22 No. 1 (2010): Vol 22 Issue 1, 2010
Abstract
A novel three-dimensional hydrogen-bonding mononuclear complex
[Cd(C10H12N2O)2(NO3)2(H2O)2], where C10H12N2O is 3-(dimethylamino)-
1-(pyridin-4-yl)prop-2-en-1-one, was synthesized and characterized by
IR spectra, elemental analysis and single-crystal X-ray. The crystal structure
analysis shows that the cadmium(II) is a six-coordinated in a slightly
distorted octahedral geometry environment. The crystal is monoclinic,
space group C2/c with unit cell parameters: a = 22.000(3)Å, b = 8.574(12)Å,
c = 14.532(2)Å, α = 90º, β = 114.643(2)º, γ = 90º, V = 2491.6(5)Å3, Z =
4, Mr = 620, Dc = 1.666 Mg/cm3, μ = 0.942 mm-1, F(000) = 1272, T =
273(2) K, R = 0.0417, wR = 0.0954 for 2184 reflections with I > 2σ(I).
[Cd(C10H12N2O)2(NO3)2(H2O)2], where C10H12N2O is 3-(dimethylamino)-
1-(pyridin-4-yl)prop-2-en-1-one, was synthesized and characterized by
IR spectra, elemental analysis and single-crystal X-ray. The crystal structure
analysis shows that the cadmium(II) is a six-coordinated in a slightly
distorted octahedral geometry environment. The crystal is monoclinic,
space group C2/c with unit cell parameters: a = 22.000(3)Å, b = 8.574(12)Å,
c = 14.532(2)Å, α = 90º, β = 114.643(2)º, γ = 90º, V = 2491.6(5)Å3, Z =
4, Mr = 620, Dc = 1.666 Mg/cm3, μ = 0.942 mm-1, F(000) = 1272, T =
273(2) K, R = 0.0417, wR = 0.0954 for 2184 reflections with I > 2σ(I).
Keywords
Crystal structure
Hydrogen bonds
Superamolecular.
CHU*, Z.-L., & DONG†, H.-Z. (2024). Synthesis and Crystal Structure of a New Mononuclear Complex: [Cd(C10H12N2O)2(NO3)2(H2O)2]. Asian Journal of Chemistry, 22(1), 629–632. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/16686
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