Copyright (c) 2018 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Synthesis, Spectral Characterization and Biological Evaluation of Cu(II) Complexes with Schiff Bases Derived from 2-Aminobenzoic Acid
Corresponding Author(s) : S. Ahalya
Asian Journal of Chemistry,
Vol. 30 No. 4 (2018): Vol 30 Issue 4
Abstract
Schiff bases i.e., 2-[(2-hydroxy-3-methoxybenzylidene)amino]benzoic acid (L1) and 2-[(2-hydroxybenzylidene)amino]benzoic acid (L2) have been synthesized by the reaction of o-vanillin and salicylaldehyde with 2-aminobenzoic acid, respectively. These chelating agents are having oxygen and nitrogen as the chelating positions. Complexes of Cu(II) with these ligands L1 and L2 have been synthesized and characterized by colorimetry, thin-layer chromatography, molar conductance, magnetic susceptibility, IR, UV-visible, 1H NMR and CV. The metal chelates and their complexes with Cu(II) have been tested for the antimicrobial activity by disc diffusion method.
Keywords
Download Citation
Endnote/Zotero/Mendeley (RIS)BibTeX
- A.M. Abu-Diefab and I.M.A. Mohamed, Beni-Suef Univ. J. Basic Appl. Sci., 4, 119 (2015); https://doi.org/10.1016/j.bjbas.2015.05.004.
- S. Kumar, D.N. Dhar and P.N. Saxena, J. Sci. Ind. Res., 68, 181 (2009).
- N.K. Gupta, M.A. Quraishi, C. Verma and A.K. Mukherjee, RSC Adv., 6, 102076 (2016) https://doi.org/10.1039/C6RA22116E.
- T. Shamspur, I. Sheikhshoaie and M.H. Mashhadizadeh, J. Anal. At. Spectrom., 20, 476 (2005); https://doi.org/10.1039/B416097E.
- S. Di Bella, I. Fragalà, A. Guerri, P. Dapporto and K. Nakatani, Inorg. Chim. Acta, 357, 1161 (2004); https://doi.org/10.1016/j.ica.2003.09.023.
- J. Xie, J. Qiao, L. Wang, J. Xie and Y. Qiu, Inorg. Chim. Acta, 358, 4451 (2005); https://doi.org/10.1016/j.ica.2005.08.018.
- M. Sivasankaran Nair and D. Arish, J. Indian Chem. Soc., 88, 265 (2011).
- I. Rama and R. Selvameena, J. Indian Chem. Soc., 91, 1877 (2014).
- G. Valarmathy and R. Subbalakshmi, Asian J. Chem., 25, 2077 (2013); https://doi.org/10.14233/ajchem.2013.13322.
- H.N. Aliyu and I. Ado, Biokemistri, 23, 9 (2011).
- V. Gomathi and R. Selvameena, Main Group Chem., 12, 275 (2013); https://doi.org/10.3233/MGC-130107.
- V. Govindaraj and S. Ramanathan, Turk. J. Chem., 38, 521 (2014); https://doi.org/10.3906/kim-1301-83.
- V. Gomathi, R. Selvameena, R. Subbalakshmi and G. Valarmathy, Int. J. Recent. Sci. Res., 4, 80 (2013).
- B.S. Ade, M.N. Deshpande and D.G. Kolhatkar, Int. J. Pharm. Biomed. Res., 3, 449 (2012).
- K. Mounika, B. Anupama, J. Pragathi and C. Gyanakumari, J. Sci. Res., 2, 513 (2010).
- G. Matela, R. Aman, C. Sharma and S. Chaudhary, J. Indian Adv. Chem. Sci., 1, 157 (2013).
- K. Geetha and S. Santhalakshmi, Res. J. Chem. Sci., 4, 68 (2014).
References
A.M. Abu-Diefab and I.M.A. Mohamed, Beni-Suef Univ. J. Basic Appl. Sci., 4, 119 (2015); https://doi.org/10.1016/j.bjbas.2015.05.004.
S. Kumar, D.N. Dhar and P.N. Saxena, J. Sci. Ind. Res., 68, 181 (2009).
N.K. Gupta, M.A. Quraishi, C. Verma and A.K. Mukherjee, RSC Adv., 6, 102076 (2016) https://doi.org/10.1039/C6RA22116E.
T. Shamspur, I. Sheikhshoaie and M.H. Mashhadizadeh, J. Anal. At. Spectrom., 20, 476 (2005); https://doi.org/10.1039/B416097E.
S. Di Bella, I. Fragalà, A. Guerri, P. Dapporto and K. Nakatani, Inorg. Chim. Acta, 357, 1161 (2004); https://doi.org/10.1016/j.ica.2003.09.023.
J. Xie, J. Qiao, L. Wang, J. Xie and Y. Qiu, Inorg. Chim. Acta, 358, 4451 (2005); https://doi.org/10.1016/j.ica.2005.08.018.
M. Sivasankaran Nair and D. Arish, J. Indian Chem. Soc., 88, 265 (2011).
I. Rama and R. Selvameena, J. Indian Chem. Soc., 91, 1877 (2014).
G. Valarmathy and R. Subbalakshmi, Asian J. Chem., 25, 2077 (2013); https://doi.org/10.14233/ajchem.2013.13322.
H.N. Aliyu and I. Ado, Biokemistri, 23, 9 (2011).
V. Gomathi and R. Selvameena, Main Group Chem., 12, 275 (2013); https://doi.org/10.3233/MGC-130107.
V. Govindaraj and S. Ramanathan, Turk. J. Chem., 38, 521 (2014); https://doi.org/10.3906/kim-1301-83.
V. Gomathi, R. Selvameena, R. Subbalakshmi and G. Valarmathy, Int. J. Recent. Sci. Res., 4, 80 (2013).
B.S. Ade, M.N. Deshpande and D.G. Kolhatkar, Int. J. Pharm. Biomed. Res., 3, 449 (2012).
K. Mounika, B. Anupama, J. Pragathi and C. Gyanakumari, J. Sci. Res., 2, 513 (2010).
G. Matela, R. Aman, C. Sharma and S. Chaudhary, J. Indian Adv. Chem. Sci., 1, 157 (2013).
K. Geetha and S. Santhalakshmi, Res. J. Chem. Sci., 4, 68 (2014).